List of Publications-Sun CQ
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Updated 10/24/2018 4:19 AM
IMonographs, treatises, book chapters, patents
1.1Monographs (3 Springer and 2 High-education)
1.2Treatises (20)
1.3Book chapters (4)
1.4Patents (4)
1.5Editorial/Commentary (8)
IIH2O and Aqueous Solutions: O:H-O bond cooperativity
2.1Water and ice: O:H-O bond cooperativity(17)
2.2Solvation Dynamics: Solute Capabilties and Molecular interactions (10)
IIIMultifield spectrometrics: bond-electron-phonon
3.1ZPS of under-coordinated adatoms, edges, defects, cavities, etc (26)
3.2ZPS of hetero-coordinated impurities, interfaces, and alloys (8)
3.3Multifield phonon spectrometrics (17)
3.4Multifield photon spectrometrics (4)
3.5Multifield solid mechanics (4)
3.62D substance: Quantum entrapment and polarization (16)
3.7Dielectric impedance: suppression, relaxation & transition (12; section 4.7)
3.8VLEED Spectrometrics (8; section 5.3)
IVUnder-coordination Physics: defects, skins, nanocrystals
4.1BOLS-NEP theory (4)
4.2Mechanical strength: extensibility, modulus, & hardness (15)
4.3Thermal stability: superheating & undercooling (12)
4.4EG and electron-hole interaction: photon emission & absorption: (13)
4.5Electrons: work function & affinity (18)
4.6Magnetism: size & thermal effect (3)
4.7Dielectrics: suppression, relaxation & transition (12)
4.8Transport dynamics: electron, phonon & photon (13)
VHetero-coordination Chemistry: Chemisorption, compounds, interfaces
5.1Bond-band-barrier correlation notation (6)
5.2Valence DOS & nonbonding electron interactions (2)
5.3VLEED quantification: O-Cu(001) 3B making dynamics (8)
5.4STM & PES verification: bonding kinetics & dynamics (12)
5.5Skin passivation (5)
VIApplications: designer materials
6.1Catalysis, desalination, solar cells (22)
6.2Photoluminescence, electron emission, photonic crystal (38)
6.3Elasticity, work function & magnetism modulation (19)
6.4Diamond thinn films and carbon allotrope (18)
6.5Thermal stability, phase transition, & expansion (3)
6.6Sensors, superconductors, and thin film technologies (22)
VIIOther publications
7.1Education (1)
VIIINews Gallary (links)
1
Outline: Extaordinary Bond Engineering
Education Experience / Professional educator since 1982 received 5 awards from Ministry of Education, Tianjin Municipality, and Tianjin University (3)Research Inspiration /
- Bond formation and relaxation and the associated energetics, localization, entrapment, and polarization of electrons mediate the macroscopic performance of substance accordingly.
- O:H-O bond segmental disparity and O-O repulsivity form the soul dictating the extraordinary adaptivity, cooperativity, recoverability, and sensitivity of water and ice.
Led area / Coordination Bond and Electronic Engineering
Original
Theory / Bond-band-barrier (3B) notation for chemisorption
Bond order-length-strength (BOLS) notation for under- and heterocoordinated systems
H-bond cooperativityfor H2O anomalies and acid-base-salt hydration-network switchers
Rules for superhydrophobicity, fluidity, lubricity, solidity, elasticity, plasticity, and rigidity
Numerical Algorithm / Local bond averaging (LBA)
BOLS-TB algorithm
Lagrangian oscillating mechanics
Fourier thermo-fluid skin dynamics
Invention / Multifield phonon spectrometrics
Coordination-resolved electronic spectrometrics
Discovery / 4-stage Cu3O2 bonding dynamics
Quantum entrapment and polarization of irregularly coordinated atoms
Catalytic nature of the least- and hetero-coordinated metals
Resolution of most documented anomalies of water and ice
Regulation of solvation bonding dynamics
News gallery / 2015 / Why is ice slippery? / New Scientist 3037, Sept 05, 2015 (UK)
2013 / Mpemba paradox resolved / Times, Telegraph, DalyMail, Phys Today, IOP News, Chem World, Chem Views, Nat Chem, Sing Chow Daily, China News, ANI News, etc.
2012 / Unlocking the mysteries of ice / Chem World, Chem Views, Madrid Times, Dallas Morning, etc.
25th KIA award / SNIC News; Press TV
Monograph / 2022: Nonbonding Electronics (incubation)
2018: Atomistic Spectrometrics:Bond-Electron-Phonon Cooperativity(2018)
- 2016: The Attribute of Water: Single Notion, Multiple Myths. Springer494 pp, ISBN: 978-981-10-0180-2
2018:《水规则六十条》(Chinese high education press)
2017: 《化学键的弛豫》(Chinese high education press, Beijing)
Treatises
(18) /
Friction / 2015 / 3, 294-319 / Ice quantum friction: Electronic repulsivity and phononic elasticity
Coord Chem Rev / 2015 / 285, 109–165 / Resolving mysteries of water and ice
Chem Rev
Chem Rev / 2015 / 115,6746–810 / Coordination-resolved electron spectrometrics
2012 / 112, 2833-52 / ZnO multifield physics and chemistry
Prog Mater Sci
Prog Mater Sci / 2009 / 54, 179-307 / Multifield solid mechanics
2003 / 48, 521-685 / Oxidation electronics
Prog Solid S Chem
Prog Solid S Chem
Prog Solid S Chem / 2015 / 43,71-81 / Water phase diagram: H-bonding dynamics
2007 / 35, 1-159 / Nanostructure size dependency
2006 / 34, 1-20 / Nitridation electronics & applications
Surf Rev Lett
Surf Rev Lett
Surf Rev Lett / 2001 / 8, 367-402 / O-Cu(001): I. STM, LEED, PES correlation
2001 / 8, 703-734 / O-Cu(001): II. Four-stage Cu3O2 bonding kinetics
2000 / 7, 347-363 / C-, N-, O-fcc(100) bonding kinetics
Surf Sci Rep / 2013 / 68, 418-445 / Nanostructured Si: bond-electron-phonon-dielectrics
Sci China / 2012 / 55, 963–979 / Nanoscopic super-plasticity, elasticity, & rigidity
Energy Environ Sci / 2011 / 4, 627-55 / CNT & Graphene
Nanoscale / 2010 / 2, 1930-1361 / Nonbonding electron polarization
JPCC / 2009 / 113, 20009-19 / Super-hydrophobicity, fluidity, lubricity, and solidity
J Raman Spec / 2008 / 38, 780-788 / Multifield Raman spectrometrics
Credentials /
- 47(57) PI-H-index; 8200 (11,050) citations
- 3 monographs, 357 journal articles; ~110 invited talks; 4 book chapters; 4 patents
- 5 journal editorials
- FRSC (2006), FinstP (2005), SNIC Council Member
- 1st place of the 25th Khwarizmi Sci Award (KIA) 2012 (out of 162 nominees from 46 countries)
- Inaugural Nanyang Award of Research 2005 (sole awardee)
- Finalist of Presidential/National Science Award, Singapore, 2012 & 2003
- 5 Education Awards in earlier career age
- Gorden Research Conference: 2016, 2017 (Water and liquid physics)
Current focus / Atomicstic spectroscopy (electron, phonon, photon, dielectric, etc.); Interface quantum entrapment and polarization; Lagrangian H-bond ultra-short-range interactions; H-bond & phonon asymmetric relaxation dynamics H2O anomalies; H-bond in cells and drugs; Metallic H2; He supersolidity; new catalysts; 4S; CF4, NO, & nanomedicine; Si-based thin film solar cells; Plasmonics; photonic crystals; hydration theory, nanobubbles, energetic crystals, etc.
IMonographs, treatises, book chapters, patents
1.1Monographs (3 Springer and 2 High-education)
04Sun CQ
Spectrometrics: Bond-Electron-Phonon Cooperativity (2018)
Complementing scanning tunneling micro/spectroscopy, phonon electron spectroscopy, and phonon spectroscopy, strategies probe atomic scale, local, dynamic, and quantitative information of bond-electron-phonon pertaining to particularly point defects, terrace edges, monolayer skin, dopants, impurities, interfaces, nanostructures, etc.
04Sun CQ and Sun Yi
The Attribute of Water: Single Notion, Multiple Myths (494 pages)
Springer Series in Chemical Physics 113; 2016; ISBN:978-981-10-0180-2
O:H-O bond segmental disparity and O-O Coulomb repulsion dictate its adaptivity, cooperativity, memory-ability, recoverability and sensitivity, which stems anomalies of water and ice
04Sun CQ
Relaxation of the Chemical Bond(807pages)
(SkinChemisorptionSize MatterPTZ MechanicsH2O Myths)
Springer Series in Chemical Physics 108; 2014, ISBN:978-981-4585-20-0
Bond formation and relaxation and the associated energetics, localization, entrapment, and polarization of electrons mediate the macroscopic performance of substance accordingly.
02孙长庆黄勇力张希
水规则六十条
高等教育出版社
北京
2018
01孙长庆黄勇力王艳
化学键的弛豫（国家科委出版基金资助）
高等教育出版社
北京
2017/08
DOI: 978-7-04-047750-4
1.2Treatises (20)
21Multifield solid phonon spectrometrics (Incubation)
21Aaqueous Solvation: Solute-Solvent Interactions (communicated)
20Zhang Xi, Huang Yongli, Ma Zengsheng, Niu Lengyuan, Sun CQ
From Ice Superlubricity to Quantum Friction: Electronic Repulsivity and Phononic Elasticity
Friction3(4): 294-319 (2015)
Molecular undercoordination induced H-O contraction and O:H elongation and the associated dual polarization turns out a supersolid phase. Share the same H-O phonn frequency at 3450 cm-1the supersolid skin of water ans ice is responsioble form the less frictionless of ice and the hydrophobicity and elasticity ofwater skin
19Liu X,Zhang X, Bo M, Li L, Tian H, Nie Y, Sun Y, Xu S, Wang Y, Zheng WT, Sun CQ
Coordination-resolved electron spectrometrics
Chem Rev115, 6746-6810 (2015)
Incorporating the theoretical approaches of BOLS, NEP, and LBA into the tight-binding premise and the experimental databases of STM/S, UPS, XPS, and AES has resulted in coordination-resolved, quantitative information regarding bond relaxation in length and energy and the associated dynamics of electron densification, entrapment, localization, and polarization at sites surrounding under- and hetero-coordinated atoms.
18X Zhang, P Sun, T Yan, Y Huang, Z Ma, B Zou, W Zheng, J Zhou, CQ Sun
Water’s phase diagram: from the notion of thermodynamics to hydrogen-bond cooperativity
Prog Solid State Chem43, 871-81 (2005)
TC(P)diagram of water and ice shows four-type phase boundaries according to their slopes; Raman mapping of three constant pressures and three constant temperatures reveal that the O:H-O bond relaxation in angle and segmental lengths take respective responsibilities in all phases and cross boundaries.
17Huang Y,Zhang X,Ma Z,Zhou Y,Zheng W,Zhou J,SunCQ
Hydrogen–bond relaxation dynamics: Resolving mysteries of water ice
Coord Chem Rev285, 109-165 (2015)
Unification of the length scale, geometry, and mass density of water ice
O:H-O bond cooperative relaxation stems the anomalies of water ice
Water prefers the 4-coordinated mono-phase with a supersolid skin unless at the nanoscale; O:H-O bond memory and skin supersolidity resolve Mpemba paradox – hotter water freezes quicker
16Pan L, Xu S, Liu X, Qin W, Sun Z, Zheng W, Sun CQ
Skin dominance of the dielectric-electronic-phononic-photonic attribute of nanosolid silicon
Surf Sci Rep68, 418–45 (2013)
The dielectric, electronic, photonic and phononic properties of siliconcan be predicatively engineered by bond relaxation and reformation based on the consistent understanding the fundamental nature of the unusual properties and their correlations. Bond relaxation is controlled by solid size reduction to induce under-coordination-induced local bond contraction and quantum entrapment. Bond reformation is realized by surface passivation and metallization.
15Li JW, Ma SZ, Liu XJ, Zhou ZF, Sun CQ
ZnO meso-mechano-thermo physical chemistry
Chem Rev112, 2833-52 (2012)
An original set of theoretical, numerical, and experimental premises has enabled clarification of the nature difference between nanostructures and bulk solids, and unification of the size trends and the emerging anomalies of ZnO nanomaterials and their pressure and temperature dependence.
14Ma ZS, Zhou ZF, Huang YL, Zhou YC, Sun CQ
Mesoscopic superplasticity, superelasticity, and superrigidity
Sci China-Phys Mech Astronomies55: 963–79 (2012)
Atomic-undercoordination-induced local bond contraction, bond strength gain, and the associated temperature (T)-dependent atomic-cohesive-energy and binding-energy-density are shown to originate intrinsically the exotic paradox of superplasticity, superelasticity, and superrigidity demonstrated by solid sizing from monatomic chain to mesoscopic grain.
13Zheng WT and Sun CQ
Underneath the fascinations of carbon nanotubes and graphene ribbons (Perspective)
Energy Environ Sci4, 627-55 (2011)
The C-C bond-length, energy, elasticity, chemical and thermal stability, C 1s core-level shift, Raman phonon relaxation, and Dirac-Fermion polarons generation and annihilation of CNTs/GNRs are consistently formulated, correlated, clarified and quantified from the perspectives of BOLS, LBA, BOLS-TB, and NEP.
12Sun CQ
Dominance of broken bonds and nonbonding electronics at the Nanoscale (Feature article)
Nanoscale2, 1930-61 (2010)
Nonbonding electron polarization (NEP) and localization by the undercoordination-induced quantum entrapment amplifies the “Strong Localization” theory of Anderson (1979), which originates the unexpected anomalies such as dilute magnetism, conducting-insulating transition, efficient catalysis, and toxic attribute of undercoordinated systems.
11Sun CQ
Thermo-mechanical behavior of low-dimensional systems: The local bond average approach
Prog Mater Sci54, 179-307 (2009)
Complementing quantum and continuum approaches, the meso-mechano-thermodynamics formulates the mechanically elastic and plastic properties of atomic chains, nanowires, nanotubes, nanograins, nanocavities, and nanocomposites under various stimuli in terms of the local bond averaging (LBA) approach.
10Sun CQ
Size dependence of nanostructures: impact of bond order deficiency
Prog Solid State Chem 35, 1-159 (2007)
BOLS theory not only clarifies the nature difference between undercoordinated defects, surfaces, and nanocrystals and the fully-coordinated bulk solid but also formulates and unifies the size dependency of nanostructures in mechanical strength, chemical and thermal stability, lattice dynamics, optics, electronic, dielectric, and magnetic properties.
09Zheng WT, Sun CQ
Electronic process of nitridation: mechanism and applications
Prog Solid State Chem 34, 1-20 (2006)
Nitrogen-modulated band-gap, workfunction, mechanical strength, elasticity, chemical inertness, photon and electron emissibility, and magnetism and their practical applications are correlated and clarified based on the NH3 like tetrahedron and the 3B correlation, guiding surface engineering for functionalities devises.
08Sun CQ
Oxidation electronics: bond-band-barrier correlation and its applications
Prog Mater Sci 48, 521-685 (2003){Movie:STM/VLLED quantified 4-stage Cu3O2 bonding kinetics}
Replacing H with metals and O with C and N in the Ice Rule (Pauling, 1935), the bond-band-barrier (3B) correlation clarifies, unifies, and formulates O-, C-, and N-chemisorption 3B forming dynamics with discoveries of surface bond contraction, 4-stage Cu3O2 bonding kinetics, and a unification of more than 50 phases and measurements of O, N, and C adsorption in terms of 3B dynamics.
07Sun CQ
O-Cu (001): I. Binding the signatures of LEED, STM and PES in a bond-forming way
Surf Rev Lett 8, 367-402 (2001)
Formulation in terms of bond making and its consequence on the behavior of atoms and valence electrons, and the corresponding parameterization, are demonstrated being able to correctly reflect the real process of reaction, as well as morphology, crystallography, and electronic spectroscopy. VLEED collects information of bond geometry, potential barrier, and electronic energy from the outermost two atomic layers of the skin.
06Sun CQ
O-Cu (001): II. VLEED quantification of the four-stage Cu3O2 bonding kinetics
Surf Rev Lett8, 703-34 (2001)
STM/VLEED quantified 4-stgage Cu3O2 bonding kinetics (Movie link)with clarification of individual atomic valences in the surface skin and quantification of the tetrahedral bond geometry under exposure, aging, annealing, azimuth angle variation conditions.
05Sun CQ
The sp3 hybrid bonding of C, N and O to the fcc (001) surface of nickel and rhodium
Surf Rev Lett 7, 347-63 (2000)
(O2--Rh)/(N3-,C4-)-Ni-fcc(001)-4(22)R45surface reconstruction share the similar morphology and the “diamond-chain” along the <11> direction but different nature. N3- induces tensile bond stress while C4-induces compressive, which enabled TiCN buffer layer for diamond –metal adhesion.
04Sun CQ
Electronic process of Cu (Ag, V, Rh) (001) surface oxidation: atomic valence alteration and bonding kinetics
Appl Surf Sci246, 6-13 (2005)
Disregarding the morphology difference, O adsorption induces the same atomic valence and electronic valence density-of-states. Ag and Cu show the same phase structures at different orders. Bonding dynamic difference arises from the crystal geometry and the electronegativity difference between O and the metal surfaces.
03Sun CQ and Bai CL
The bonding between oxygen and metal surfaces
Chem Hong Kong1, 59-63 (1998)
Metal surface O adsorption may differentiates morphology but the bond nature and the valance DOS and the 4-stage bonding dynamics.
02Gu MX, Pan LK, Tay BK, Sun CQ
Atomistic origin and temperature dependence of Raman optical redshift in nanostructures: a broken bond rule
J Raman Spec 38, 780-8 (2007)
01Sun CQ
断键与非键电子学的理论及应用研究初探
湘潭大学学报(自然科学版, 50周年校庆特集) 2008,3, 36-45.
J Xiangtan University, Special issue for the 50th anniversary, No. 3, 36-45 (2008）
1.3Book chapters (4)
04Pan LK, Gu MX, Ouyang G, Sun CQ
Behind the quantum and size effect: broken-bond-induced local strain and skin-depth charge and energy quantum trapping, in the themed issue of Size Effects in Metals, Alloys and Inorganic Compounds: From Basics to Applications, eds. Gregory Guisbiers and Dibyendu Ganguli, Key Engineering Materials 444, 17-45, 2010. TransTechPub, Switzerland.
03Sun CQ, Theory of size, confinement, and oxidation effects (Chapter 1)Cover and comments
In the Synthesis, properties, and applications of oxide nanoparticles, Eds Jose A. Rodríguez and Marcos. Fernandez-Garcia, 2007, 9-47; ISBN 978-0-471-72405-6, John Wiley & Sons.
02Jennings PJ and Sun CQ
Low energy electron diffraction
In the Surface Analysis Methods in Materials Science, Eds O'Connor DJ, Sexton BA and Smart RC, Berlin Springer-Verlag, New York, 2003
01Thurgate SM, Sun CQ and Hitchen G
Surface structural determination by VLEED analysis
In the Surface Science: Principles and Applications, Eds MacDonald RJ, Taglauer EC and Wandelt KR, Springer-Verlag, pp29-37 (1996)
1.4Patents (4)
04Sun CQ
Atomic-scaled photoelectron spectroscopy purification
(National Phase Entry from PCT Application No: PCT/SG2010/000230)
- US Application No. : 13/704,923
- Filing Date: 17 December 2012
- International Filing Date: 18 June 2010
- Granted: 18/04/2017: No. 9,625,397B2
03Li CMand Sun CQ
Addressable Transistor Chip for conducting Assays (US 8,138,496 B2, 20/03, 2012)
02Li CM and Sun CQ
Addressable organic transistor-based biochip (USA: No 60/558, 117)
01Jiang EY, Sun CQ, Liu YG, and Zhang XX
FTS-II facing-target PVD sputtering system for multilayers (Chinese: No 90242431)
1.5Editorial/Commentary (8)
08Sun CQ
Discovery: Behind the Mpemba Paradox (Open access)
Temperature, in press
07Sun CQ
非键电子在功能材料中的作用, 功能材料信息（特约高层论坛）5(3): 14-20 (2008)
Functions of broken bonds and nonbonding states in functional materials (Chinese)
Published under invitation in the <Specialist Forum>5(3): 14-20 (2008)
06Sun CQ
Nanostructures: strained shells are stiffer but melt easier
Nano Affairs 4, (2008)
05Sun CQ
Local bond average: An approach crossing the boundaries of classical and quantum approximations
Nano Affairs 3, (2007)
04Sun CQ
Size enabled elucidation of the core-electron energy and the dimer-vibration frequency
Nano Affairs 2, (2007)
03Sun CQ
Broken bonds: the key to the size dependency of nanostructures
Nano Affairs 1, 5 (2007)
02Sun CQ, Li S, and Tay BK
Laser-like mechanoluminescence in ZnMnTe-diluted magnetic semiconductor [Appl Phys Lett 81, 460 (2002)]
Appl Phys Lett 82, 3568-9 (2003)
01Sun CQ
The lattice contraction of nanometer-sized Sn and Bi particles
J Phys-Condens Matt 11, 4801-3 (1999)
IIH2O and Aqueous Solutions: O:H-O bond cooperativity
2.1Water and ice: O:H-O bond cooperativity(17)
17王彦超, 孙长庆,吴光恒
受限水的超流特性.
科学通报, 62 (11): 62, 1111-1117 (2017)
16X. Zhang, Y. Huang, S. Wang, L. Li, and C.Q. Sun,
Supersolid Skin Mechanics of Water and Ice
Procedia IUTAM, 21: 102-110, (2017)
15B Wang, W Jiang, Y Gao, Z Zhang, C Sun, F Liu, Z Wang
Energetics competition in centrally four-coordinated water clusters and Raman spectroscopic signature for hydrogen bonding
RSC Advances 7, 11680-11683 (2017)
14XZhang, X Liu, Y Zhong, Z Zhou, Y Huang, CQ Sun
Nanobubble Skin Supersolidity
Langmiure, 32(43): 11321-11327, (2016)
13Y. Zhou, Y. Zhong, Y. Huang, Y.Y. Gong, Y. Huang, Z. Ma, and C.Q. Sun
Unprecedented high thermal stability of water supersolid skin
J MolLiq 220: 865-869 (2016)
12Y.L. Huang, X. Zhang, Z.S. Ma, G.H. Zhou, Y.Y. Gong, and C.Q. Sun
Potential Paths for the Hydrogen-Bond Relaxing with (H2O)N Cluster Size
J Phys Chem C 119(29): 16962-16971 (2015)
11X. Zhang, Y. Huang, P. Sun, X. Liu, Z. Ma, Y. Zhou, J. Zhou, W. Zheng, and C.Q. Sun
Ice Regelation: Hydrogen-bond extraordinary recoverability and water quasisolid-phase-boundary dispersivity.
Sci Rep 5: 13655 (2015)
10CQ Sun
Behind the Mpemba paradox
Temperature 2, 38-39 (2015)
09X Zhang, P Sun, YL Huang, Z Ma, X Liu, J Zhou, W Zheng, CQ Sun
Water nanodroplet thermodynamics: quasi-solid phase-boundary dispersivity
J Phys Chem B 119 (16), 5265-5269 (2015)
08Zhang X, Yan TT, Huang YL, Ma ZS, Zou B, Sun CQ
Mediating relaxation and polarization of hydrogen-bonds in water by NaCl salting and heating
PCCP 16, 24666-71(2014)
07Zhang X, Huang YL, Ma ZS, Zhou YC, Zheng WT, Jiang Q, Zhou J, Sun CQ
Hydrogen-bond memory and water-skin supersolidity resolving Mpemba paradox
PCCP16, 22995-3002 (2014)
Featured by multiple News Media
06Zhang X, Huang YL, Ma ZS, Zhou YC, Zheng WT, Zhou J, Sun CQ
A common supersolid skin covering both water and ice
PCCP 16: 22987-94 (2014)
05Huang YL, Zhang X, Ma ZS, Zhou YC, Sun CQ
Size, separation, structural order and mass density of molecules packing in water and ice
Sci Rep 3, 3005 (2013)
04Huang YL, Ma ZS, Zhang X, Zhou GH, Zhou YC, Sun CQ
Hydrogen-bond asymmetric local potential in compressed ice
J Phys Chem B 117, 13639–45 (2013)
03Sun CQ, Zhang X, Fu XJ, Zheng WT, Kuo JL, Zhou YC, Shen ZX,Zhou J
Density and phonon-stiffness anomalies of water and ice in the full temperature range
J Phys Chem Lett 4, 3238-44 (2013)
ACSLiveSlidesTM
02Sun CQ, Zhang X, Zhou J, Huang YL, Zhou YC, Zheng WT