Supplementary material to “Elemental and cooperative diffusion in a liquid, supercooled liquid and glass resolved”

Daniel R. Cassar1*, Ricardo F. Lancelotti1, Rafael Nuernberg1, Marcio L. F. Nascimento2, Alisson M. Rodrigues1, Luiza T. Diz1, Edgar D. Zanotto1*

1CeRTEV — Center for Research, Technology and Education in Vitreous Materials, Department of Materials Engineering, Federal University of São Carlos, 13565 - 905 São Carlos, SP, Brazil: www.certev.ufscar.br

2PROTEC / PEI — Graduate Program in Industrial Engineering, Department of Chemical Engineering, Polytechnic School, Federal University of Bahia, Rua Aristides Novis 2, Federação, 40210 - 630 Salvador, BA, Brazil: www.protec.ufba.br

* Corresponding authors: ,

Supplementary material

Tables S.1, S.2, and S.3 show all the experimental data obtained from this study.

Table S.1: Experimental crystal growth rates, U, obtained from this study. These are raw data, not corrected with the Herron & Bergeron expression (Eq. 15 from the manuscript).

Batch / T (K) / U (m/s)
Batch 1 / 688 / 1.0(1)×10–12
Batch 1 / 700 / 4.0(1)×10–12
Batch 1 / 710 / 1.6(2)×10–11
Batch 1 / 725 / 8.4(4)×10–11
Batch 1 / 739 / 2.26(9)×10–10
Batch 1 / 748 / 4.60(7)×10–10
Batch 1 / 787 / 4.4(1)×10–09
Batch 1 / 798 / 5.2(1)×10–09
Batch 2 / 753 / 7.70×10–10
Batch 2 / 775 / 2.03×10–09
Batch 2 / 838 / 4.26×10–08
Batch 2 / 703 / 6.70×10–12
Batch 2 / 713 / 5.55×10–11
Batch 2 / 733 / 2.50×10–10
Batch 2 / 796 / 6.46×10–09
Batch 2 / 811 / 1.83×10–08
Batch 2 / 825 / 2.52×10–08
Batch 2 / 849 / 3.79×10–08
Batch 2 / 853 / 6.79×10–08

Table S.2: Experimental viscosity data obtained from this study for a sample of Batch 1.

T (K) / log10(h) (h in Pa·s) / T (K) / log10(h) (h in Pa·s) / T (K) / log10(h) (h in Pa·s)
694 / 11.00 / 711 / 9.72 / 727 / 8.76
694 / 10.95 / 711 / 9.73 / 727 / 8.82
695 / 10.87 / 712 / 9.67 / 727 / 8.74
696 / 10.85 / 712 / 9.66 / 728 / 8.76
696 / 10.80 / 713 / 9.65 / 728 / 8.68
697 / 10.76 / 713 / 9.60 / 729 / 8.67
697 / 10.74 / 713 / 9.60 / 729 / 8.61
698 / 10.65 / 714 / 9.56 / 729 / 8.70
699 / 10.59 / 714 / 9.57 / 730 / 8.66
700 / 10.57 / 714 / 9.55 / 730 / 8.56
700 / 10.51 / 715 / 9.51 / 730 / 8.54
701 / 10.46 / 715 / 9.49 / 730 / 8.65
701 / 10.44 / 716 / 9.46 / 731 / 8.49
702 / 10.38 / 716 / 9.44 / 731 / 8.59
702 / 10.45 / 716 / 9.45 / 732 / 8.56
703 / 10.36 / 717 / 9.39 / 732 / 8.54
703 / 10.37 / 717 / 9.39 / 733 / 8.51
703 / 10.31 / 718 / 9.36 / 734 / 8.45
704 / 10.27 / 718 / 9.35 / 735 / 8.40
704 / 10.29 / 718 / 9.32 / 736 / 8.36
704 / 10.24 / 718 / 9.33 / 736 / 8.34
704 / 10.23 / 719 / 9.29 / 738 / 8.29
705 / 10.16 / 719 / 9.26 / 738 / 8.27
705 / 10.16 / 720 / 9.27 / 738 / 8.24
705 / 10.13 / 720 / 9.20 / 739 / 8.18
705 / 10.14 / 720 / 9.23 / 740 / 8.16
706 / 10.06 / 721 / 9.16 / 740 / 8.12
706 / 10.07 / 721 / 9.12 / 741 / 8.05
706 / 10.03 / 721 / 9.16 / 742 / 8.01
707 / 9.97 / 722 / 9.12 / 743 / 7.97
707 / 10.00 / 722 / 9.05 / 743 / 7.95
708 / 9.96 / 723 / 9.07 / 744 / 7.89
708 / 9.89 / 723 / 9.05 / 745 / 7.85
708 / 9.91 / 723 / 8.99 / 745 / 7.84
709 / 9.86 / 724 / 8.97 / 746 / 7.79
709 / 9.87 / 724 / 8.98 / 747 / 7.75
709 / 9.82 / 724 / 8.91 / 747 / 7.74
709 / 9.85 / 725 / 8.96 / 748 / 7.71
710 / 9.77 / 725 / 8.85 / 749 / 7.66
711 / 9.76 / 725 / 8.92 / 750 / 7.61
711 / 9.79 / 726 / 8.79 / 751 / 7.56
711 / 9.77 / 726 / 8.86 / 752 / 7.54

Table S.3: DPb obtained via impedance spectroscopy from a sample of Batch 1.

T (K) / DPb (m2/s) using Hr=0.1 / DPb (m2/s) using Hr=0.3 / DPb (m2/s) using Hr=0.5
473 / 7.0×10–22 / 2.1×10–21 / 3.5×10–21
493 / 2.2×10–21 / 6.6×10–21 / 1.1×10–20
513 / 6.1×10–21 / 1.8×10–20 / 3.1×10–20
533 / 1.8×10–20 / 5.2×10–20 / 8.8×10–20
553 / 4.9×10–20 / 1.5×10–19 / 2.5×10–19
573 / 1.3×10–19 / 3.8×10–19 / 6.3×10–19
593 / 3.0×10–19 / 8.9×10–19 / 1.5×10–18
613 / 6.4×10–19 / 1.9×10–18 / 3.2×10–18
633 / 1.3×10–18 / 3.9×10–18 / 6.5×10–18
653 / 2.4×10–18 / 7.2×10–18 / 1.2×10–17
673 / 4.4×10–18 / 1.3×10–17 / 2.2×10–17

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