Supplemental Material for Accurate Gaseous Ion Mobility Measurements by L. A. Viehland

Supplemental Material for “Accurate Gaseous Ion Mobility Measurements” by L. A. Viehland (Chatham University; ), A. Lutfullaeva, J. Dashdorj and R. Johnsen

Zero-field standard mobilities (K0(0) in cm2/Vs) and standard mobilities (K0 in cm2/Vs) at the limiting value of the reduced field strength (E/N in Td) given by Eq. (5) of the text, for state-specific atomic ions in naturally-occurring rare gases and 222Rn. The theoretical references are cited by numbers; experimental values are given only if the claimed accuracy is ±2% or better and E/N is below the tabulated value, and they are referencedby letters. The semi-classicalvalues for He+ in He at 300.00 K are corrected to the quantum values, as discussed in the text; the values at 400.00 K are not corrected.

300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
107Ag-(1S0) / He / 13.600 / 1.42 / 1.0002 / 12.842 / [34]
Ne / 6.8652 / 2.63 / 1.0009 / 6.4906 / [34]
Ar / 2.8469 / 5.90 / 0.9984 / 2.9932 / [34]
107Ag+(1S0) / He / 17.516 / 17.2 / 1.10 / 0.9998 / 18.510 / [13] / [H]
Ne / 5.5425 / 3.26 / 0.9996 / 5.7359 / [13]
Ar / 2.0399 / 8.25 / 1.0004 / 2.0158 / [13]
Kr / 1.3132 / 11.3 / 1.0006 / 1.2973 / [13]
Xe / 0.9322 / 14.2 / 1.0009 / 0.9212 / [13]
Rn / 0.7598 / 14.8 / 1.0010 / 0.7520 / [13]
107Ag+(3S1) / He / 24.248 / 0.80 / 1.0000 / 23.849 / [34]
Ne / 6.4863 / 2.78 / 0.9985 / 6.8756 / [34]
Ar / 1.9773 / 8.50 / 1.0005 / 1.9443 / [34]
27Al+(1S0) / He / 21.882 / 1.67 / 1.0003 / 21.221 / [26]
Ne / 8.4904 / 3.49 / 0.9978 / 8.7832 / [26]
Ar / 2.7581 / 9.03 / 0.9985 / 2.8287 / [26]
Kr / 2.0370 / 9.47 / 1.0012 / 2.0258 / [26]
Xe / 1.5455 / 10.5 / 1.0022 / 1.5202 / [26]
Rn / 1.3319 / 9.68 / 1.0019 / 1.3139 / [26]
27Al3+(1S0) / He / 16.873 / 2.16 / 1.0001 / 16.813 / [3]
Ne / 6.9598 / 4.26 / 1.0006 / 6.8591 / [19]
40Ar+(2P3/2) / He / 20.603 / 1.49 / 0.9999 / 20.626 / [22]
Ne / 6.8179 / 3.85 / 0.9985 / 7.0757 / [24]
40Ar+(2P1/2) / He / 20.979 / 1.49 / 0.9999 / 21.355 / [22]
Ne / 7.0710 / 3.71 / 0.9985 / 7.3172 / [24]
40Ar+(2P) / He / 20.850 / 1.47 / 0.9998 / 21.105 / [22]
Ne / 6.9030 / 3.80 / 0.9985 / 7.1556 / [24]
197Au-(1S0) / He / 15.597 / 0.92 / 1.0001 / 14.560 / [34]
Ne / 6.5527 / 2.11 / 1.0003 / 6.2584 / [34]
Ar / 2.2617 / 5.85 / 0.9989 / 2.4119 / [34]
197Au+(1S0) / He / 17.182 / 0.84 / 0.9999 / 18.267 / [13]
Ne / 5.1946 / 2.66 / 0.9998 / 5.3691 / [13]
Ar / 1.8796 / 7.05 / 1.0003 / 1.8474 / [13]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
Kr / 1.1694 / 10.4 / 1.0005 / 1.1512 / [13]
Xe / 0.8108 / 13.9 / 1.0006 / 0.7994 / [13]
Rn / 0.6372 / 15.6 / 1.0009 / 0.6295 / [13]
197Au+(3S1) / He / 20.360 / 0.71 / 1.0000 / 20.991 / [34]
Ne / 5.1887 / 2.66 / 0.9996 / 5.4565 / [34]
Ar / 1.7976 / 7.36 / 1.0002 / 1.7726 / [34]
11B+(1S0) / He / 25.746 / 2.04 / 0.9990 / 26.364 / [31]
Ne / 10.135 / 3.60 / 0.9934 / 10.829 / [31]
Ar / 3.6828 / 7.74 / 1.0009 / 3.6612 / [31]
Kr / 2.8387 / 7.37 / 1.0012 / 2.8131 / [31]
Xe / 2.2156 / 7.68 / 1.0014 / 2.1937 / [31]
Rn / 1.9783 / 6.74 / 1.0012 / 1.9593 / [31]
138Ba+(2S1/2) / He / 16.976 / 1.01 / 1.0001 / 16.320 / [20]
Ne / 8.3917 / 1.93 / 1.0003 / 8.0850 / [20]
Ar / 1.8895 / 8.12 / 0.9987 / 2.0091 / [20]
Kr / 1.1184 / 12.2 / 0.9995 / 1.1416 / [20]
Xe / 0.7888 / 15.8 / 1.0007 / 0.7831 / [20]
Rn / 0.6371 / 16.8 / 1.0015 / 0.6288 / [20]
138Ba2+(1S0) / He / 18.055 / 0.95 / 0.9999 / 18.953 / [20]
Ne / 5.7154 / 2.84 / 0.9998 / 5.8208 / [20]
Ar / 2.0664 / 7.40 / 1.0000 / 2.0670 / [20]
Kr / 1.2922 / 10.5 / 1.0000 / 1.2908 / [20]
Xe / 0.8990 / 14.3 / 0.9995 / 0.8959 / [20]
Rn / 0.7152 / 15.7 / 0.9993 / 0.7134 / [20]
9Be+(2S1/2) / He / 31.664 / 1.78 / 0.9984 / 32.833 / [25]
Ne / 12.762 / 2.95 / 0.9853 / 14.500 / [25]
Ar / 3.8642 / 7.53 / 1.0017 / 3.8143 / [25]
Kr / 3.0505 / 6.93 / 1.0017 / 3.0107 / [25]
Xe / 2.4093 / 7.23 / 1.0013 / 2.3786 / [25]
Rn / 2.1594 / 6.20 / 1.0015 / 2.1331 / [25]
9Be2+(1S0) / He / 18.577 / 3.04 / 1.0002 / 18.469 / [25]
Ne / 9.0247 / 4.18 / 1.0005 / 8.9829 / [25]
Ar / 4.1482 / 7.02 / 1.0005 / 4.1231 / [25]
79Br-(1S0) / He / 17.741 / 1.26 / 1.0003 / 16.545 / [16]
Ne / 6.9157 / 2.96 / 1.0005 / 6.6971 / [16]
Ar / 2.3673 / 2.32 / 7.88 / 0.9978 / 2.5001 / [16] / [C]
Kr / 1.4552 / 1.47 / 11.0 / 0.9970 / 1.5238 / [16] / [C]
Xe / 1.0039 / 0.99 / 14.0 / 0.9983 / 1.0286 / [16] / [C]
Rn / 0.8263 / 14.2 / 0.9990 / 0.8363 / [16]
79Br+(3P0) / He / 19.510 / 1.15 / 1.0001 / 19.107 / [21]
Ne / 6.8397 / 2.99 / 0.9996 / 6.8924 / [21]
Ar / 2.3365 / 8.02 / 0.9988 / 2.4133 / [21]
79Br+(3P1) / He / 19.416 / 1.15 / 1.0000 / 19.082 / [21]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
Ne / 6.3898 / 3.20 / 0.9994 / 6.5415 / [21]
Ar / 2.2037 / 8.48 / 0.9998 / 2.2226 / [21]
79Br+(3P2) / He / 19.631 / 1.14 / 1.0001 / 19.391 / [21]
Ne / 6.3638 / 3.22 / 0.9992 / 6.5683 / [21]
Ar / 2.1110 / 8.87 / 1.0003 / 2.1048 / [21]
12C+(2P3/2) / He / 22.903 / 2.22 / 0.9990 / 23.726 / [33]
Ne / 9.2613 / 3.87 / 0.9976 / 9.5103 / [33]
Ar / 3.7621 / 7.58 / 0.9989 / 3.8065 / [33]
Kr / 2.8239 / 7.37 / 1.0000 / 2.8269 / [33]
Xe / 2.1741 / 7.82 / 1.0012 / 2.1531 / [33]
12C+(2P1/2) / He / 21.410 / 2.38 / 0.9980 / 23.060 / [33]
Ne / 8.1715 / 4.39 / 0.9989 / 8.3261 / [33]
Ar / 3.6060 / 7.84 / 1.0016 / 3.5571 / [33]
Kr / 2.8012 / 7.43 / 1.0015 / 2.7669 / [33]
Xe / 2.1942 / 7.75 / 1.0014 / 2.1679 / [33]
12C+(2P) / He / 22.382 / 2.27 / 0.9986 / 23.498 / [33]
Ne / 8.8681 / 4.05 / 0.9980 / 9.0813 / [33]
Ar / 3.7076 / 7.67 / 0.9999 / 3.7178 / [33]
Kr / 2.8161 / 7.39 / 1.0005 / 2.8064 / [33]
Xe / 2.1808 / 7.80 / 1.0012 / 2.1578 / [33]
12C+(4P5/2) / He / 26.593 / 1.91 / 0.9992 / 27.155 / [33]
12C+(4P3/2) / He / 20.042 / 2.54 / 1.0003 / 19.724 / [33]
12C+(4P1/2) / He / 16.381 / 3.11 / 1.0010 / 15.777 / [33]
12C+(4P) / He / 21.924 / 2.32 / 1.0000 / 21.796 / [33]
40Ca+(2S1/2) / He / 20.022 / 1.53 / 1.0004 / 19.117 / [23]
Ne / 9.5161 / 2.76 / 0.9995 / 9.5336 / [23]
Ar / 2.4467 / 9.32 / 0.9962 / 2.5996 / [23]
Kr / 1.6272 / 11.3 / 0.9991 / 1.6540 / [23]
Xe / 1.2123 / 12.8 / 1.0012 / 1.2039 / [23]
Rn / 1.0660 / 11.8 / 1.0020 / 1.0518 / [23]
40Ca2+(1S0) / He / 18.824 / 1.63 / 0.9998 / 19.458 / [23]
Ne / 6.4154 / 4.09 / 0.9999 / 6.4366 / [23]
Ar / 2.7591 / 8.26 / 1.0009 / 2.7244 / [23]
Kr / 1.7792 / 10.3 / 0.9999 / 1.7770 / [23]
Xe / 1.3190 / 11.8 / 0.9996 / 1.3212 / [23]
Rn / 1.1207 / 11.2 / 0.9999 / 1.1205 / [23]
114Cd+(2S1/2) / He / 21.614 / 21.6 / 0.87 / 1.0000 / 21.242 / [8] / [H]
Ne / 6.5105 / 2.70 / 0.9992 / 6.8022 / [8]
Ar / 1.9701 / 8.35 / 1.0001 / 1.9724 / [8]
Kr / 1.2578 / 11.5 / 1.0006 / 1.2451 / [8]
Xe / 0.8931 / 14.6 / 1.0009 / 0.8828 / [8]
Rn / 0.7244 / 15.3 / 1.0011 / 0.7162 / [8]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
35Cl-(1S0) / He / 20.001 / 1.63 / 1.0005 / 18.750 / [27]
Ne / 8.1570 / 8.20 / 3.36 / 1.0005 / 7.9895 / [27] / [B]
Ar / 2.8194 / 2.81 / 8.30 / 0.9958 / 2.9870 / [27] / [B]
Kr / 1.8676 / 1.86 / 10.0 / 0.9950 / 1.9536 / [27] / [B]
Xe / 1.3446 / 1.34 / 11.7 / 0.9982 / 1.3727 / [27] / [B]
Rn / 1.1509 / 11.0 / 0.9994 / 1.1618 / [27]
133Cs+(1S0) / He / 18.202 / 0.96 / 1.0001 / 17.539 / [5]
Ne / 6.1066 / 6.00 / 2.70 / 0.9998 / 6.1443 / [5] / [B]
Ar / 2.1318 / 2.11 / 7.27 / 0.9994 / 2.1956 / [5] / [B]
Kr / 1.3053 / 1.30 / 10.6 / 0.9991 / 1.3378 / [5] / [B]
Xe / 0.9018 / 0.89 / 14.0 / 1.0000 / 0.9008 / [5] / [B]
Rn / 0.7182 / 15.2 / 0.9995 / 0.7240 / [5]
63Cu-(1S0) / He / 14.186 / 1.75 / 1.0003 / 13.423 / [34]
Ne / 7.4986 / 2.98 / 1.0014 / 7.0872 / [34]
Ar / 3.2650 / 6.15 / 0.9971 / 3.4301 / [34]
63Cu+(1S0) / He / 16.094 / 1.55 / 0.9998 / 16.893 / [13]
Ne / 5.7854 / 3.86 / 0.9994 / 5.9534 / [13]
Ar / 2.2300 / 9.01 / 1.0005 / 2.2044 / [13]
Kr / 1.5021 / 11.2 / 1.0009 / 1.4857 / [13]
Xe / 1.0987 / 13.3 / 1.0012 / 1.0855 / [13]
Rn / 0.9243 / 13.2 / 1.0014 / 0.9140 / [13]
63Cu+(3S1) / He / 25.578 / 0.97 / 0.9999 / 25.569 / [34]
Ne / 6.8093 / 3.28 / 0.9981 / 7.2865 / [34]
Ar / 2.1765 / 9.22 / 1.0007 / 2.1490 / [34]
153Eu+(9S0) / He / 18.238 / 18.4 / 0.89 / 1.0001 / 17.410 / [32] / [J]
Ne / 7.9596 / 1.94 / 0.9999 / 7.8975 / [32]
Ar / 1.8745 / 1.84 / 7.82 / 0.9990 / 1.9865 / [32] / [J]
Kr / 1.1162 / 11.9 / 0.9998 / 1.1338 / [32]
Xe / 0.7818 / 15.4 / 1.0007 / 0.7754 / [32]
153Eu2+(8S7/2) / He / 17.443 / 0.93 / 0.9999 / 18.157 / [29]
Ne / 5.6179 / 2.75 / 0.9999 / 5.6786 / [29]
Ar / 2.0285 / 7.23 / 1.0000 / 2.0295 / [29]
Kr / 1.2519 / 10.6 / 1.0000 / 1.2522 / [29]
Xe / 0.8591 / 14.1 / 1.0000 / 0.8588 / [29]
153Eu3+(7F0) / He / 16.496 / 0.99 / 1.0000 / 16.534 / [29]
Ne / 5.5468 / 2.79 / 1.0000 / 5.5463 / [29]
Ar / 2.0148 / 7.00 / 1.0002 / 2.0153 / [29]
19F-(1S0) / He / 27.636 / 1.54 / 1.0005 / 26.692 / [10]
Ne / 10.486 / 3.10 / 0.9976 / 10.757 / [10]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
Ar / 3.2605 / 8.14 / 0.9948 / 3.4447 / [10]
Kr / 2.3003 / 2.30 / 8.74 / 0.9977 / 2.3577 / [10] / [B]
Xe / 1.7202 / 9.67 / 1.0000 / 1.7235 / [10]
Rn / 1.5051 / 8.72 / 1.0002 / 1.5036 / [10]
223Fr+(1S0) / He / 17.512 / 0.77 / 1.0001 / 16.771 / [5]
Ne / 5.8257 / 2.24 / 0.9999 / 5.8314 / [5]
Ar / 1.9904 / 6.31 / 0.9996 / 2.0538 / [5]
Kr / 1.1875 / 9.79 / 0.9995 / 1.2158 / [5]
Xe / 0.7961 / 13.6 / 0.9997 / 0.8066 / [5]
Rn / 0.6123 / 15.8 / 0.9997 / 0.6177 / [5]
69Ga+(1S0) / He / 21.122 / 1.13 / 1.0000 / 20.719 / [28]
Ne / 6.9553 / 3.10 / 0.9989 / 7.2343 / [28]
Ar / 2.2138 / 8.83 / 0.9995 / 2.2568 / [28]
Kr / 1.4493 / 11.4 / 1.0003 / 1.4488 / [28]
Xe / 1.0495 / 13.8 / 1.0008 / 1.0406 / [28]
Rn / 0.8786 / 13.6 / 1.0011 / 0.8703 / [28]
4He+(2S1/2) / He / 10.398 / 10.3 / 10.4 / 1.0028 / 10.136 / [35] / [A]
Ne / 16.608 / 16.7 / 16.6 / 0.9931 / 17.559 / [18] / [D]
Ar / 5.4691 / 5.49 / 0.9980 / 5.6345 / [29]
202Hg+(2S1/2) / He / 20.009 / 0.71 / 1.0000 / 19.938 / [8]
Ne / 5.7430 / 2.38 / 0.9997 / 5.9819 / [8]
Ar / 1.8510 / 7.08 / 1.0002 / 1.8374 / [8]
Kr / 1.2003 / 10.0 / 1.0008 / 1.1731 / [8]
Xe / 0.8475 / 13.2 / 1.0011 / 0.8285 / [8]
Rn / 0.6203 / 15.9 / 1.0008 / 0.6131 / [8]
127I-(1S0) / He / 16.562 / 1.16 / 1.0002 / 15.341 / [6]
Ne / 7.1506 / 2.75 / 1.0005 / 6.7021 / [6]
Ar / 2.9352 / 7.27 / 0.9985 / 3.0249 / [6]
127I+(3P2) / He / 17.887 / 0.99 / 1.0001 / 17.211 / [6]
Ne / 6.0561 / 2.77 / 0.9998 / 6.0989 / [6]
Ar / 2.0363 / 7.74 / 0.9995 / 2.0829 / [6]
115In+(1S0) / He / 19.584 / 0.95 / 1.0001 / 18.948 / [28]
Ne / 6.4519 / 2.72 / 0.9995 / 6.6194 / [28]
Ar / 2.0405 / 8.03 / 0.9995 / 2.0911 / [28]
Kr / 1.2733 / 11.3 / 1.0000 / 1.2796 / [28]
Xe / 0.8989 / 14.5 / 1.0006 / 0.8918 / [28]
Rn / 0.7314 / 15.2 / 1.0011 / 0.7238 / [28]
39K+(1S0) / He / 21.261 / 21.2 / 1.46 / 0.9998 / 21.388 / [4] / [F]
Ne / 7.3518 / 7.45 / 3.60 / 0.9984 / 7.6306 / [4] / [A]
Ar / 2.6777 / 2.66 / 8.58 / 0.9980 / 2.7682 / [4] / [E]
Kr / 1.8251 / 1.83 / 10.2 / 0.9979 / 1.8638 / [4] / [B]
Xe / 1.3489 / 1.35 / 11.7 / 0.9993 / 1.3598 / [4] / [B]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
Rn / 1.1429 / 11.2 / 0.9981 / 1.1467 / [4]
84Kr+(2P3/2) / He / 19.493 / 1.11 / 1.0000 / 19.334 / [22]
Ne / 6.3333 / 3.25 / 0.9993 / 6.5109 / [24]
84Kr+(2P1/2) / He / 19.496 / 1.11 / 1.0000 / 19.201 / [22]
Ne / 6.3805 / 3.13 / 0.9994 / 6.5451 / [24]
84Kr+(2P) / He / 19.492 / 1.11 / 1.0000 / 19.287 / [22]
Ne / 6.3487 / 3.21 / 0.9993 / 6.5215 / [24]
7Li+(1S0) / He / 22.816 / 23.1 / 2.69 / 0.9969 / 24.561 / [1] / [A]
Ne / 10.566 / 10.7 / 3.70 / 0.9955 / 11.045 / [1] / [A]
Ar / 4.6177 / 4.62 / 6.44 / 1.0001 / 4.6201 / [1] / [A]
Kr / 3.5696 / 6.01 / 1.0002 / 3.5629 / [1]
Xe / 2.7826 / 6.27 / 1.0000 / 2.7697 / [1]
Rn / 2.4521 / 5.55 / 1.0004 / 2.4378 / [1]
175Lu+(1S0) / He / 16.577 / 16.7 / 0.92 / 1.0001 / 15.617 / [32] / [I]
Ne / 6.5253 / 2.37 / 0.9999 / 6.5008 / [32]
Ar / 1.9866 / 6.99 / 0.9990 / 2.1113 / [32]
Kr / 1.1149 / 11.4 / 0.9995 / 1.1426 / [32]
Xe / 0.7595 / 15.3 / 1.0008 / 0.7535 / [32]
24Mg+(2S1/2) / He / 24.587 / 1.57 / 1.0003 / 23.865 / [37]
Ne / 10.166 / 3.04 / 0.9961 / 10.708 / [25]
Ar / 2.7372 / 9.63 / 0.9981 / 2.7864 / [25]
Kr / 2.0111 / 10.2 / 0.9998 / 1.9970 / [25]
Xe / 1.5121 / 11.4 / 0.9988 / 1.5036 / [25]
Rn / 1.2289 / 10.6 / 0.9982 / 1.2427 / [25]
24Mg2+(1S0) / He / 17.271 / 2.23 / 1.0000 / 17.272 / [25]
Ne / 6.9726 / 4.39 / 1.0000 / 6.9668 / [25]
Ar / 2.8338 / 8.99 / 0.9995 / 2.8455 / [25]
Kr / 2.2075 / 8.89 / 0.9998 / 2.2071 / [25]
Xe / 1.6441 / 9.15 / 1.0010 / 1.6372 / [25]
Rn / 1.5755 / 8.24 / 0.9996 / 1.5740 / [25]
23Na+(1S0) / He / 22.364 / 22.8 / 1.75 / 0.9991 / 23.673 / [2] / [A]
Ne / 8.0882 / 8.25 / 3.83 / 0.9963 / 8.5929 / [2] / [A]
Ar / 3.0443 / 3.08 / 8.43 / 0.9988 / 3.0981 / [2] / [A]
Kr / 2.1861 / 2.20 / 9.05 / 0.9995 / 2.2011 / [2] / [C]
Xe / 1.6495 / 10.0 / 1.0000 / 1.6495 / [2]
Rn / 1.3990 / 9.30 / 1.0000 / 1.4010 / [2]
20Ne+(2P3/2) / He / 19.786 / 2.11 / 0.9997 / 20.011 / [18]
20Ne+(2P1/2) / He / 21.321 / 1.95 / 0.9991 / 22.399 / [18]
20Ne+(2P) / He / 20.273 / 20.3 / 2.06 / 0.9996 / 20.749 / [18] / [B]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
16O-(2P3/2) / He / 28.004 / 1.63 / 1.0010 / 26.645 / [7]
16O-(2P1/2) / He / 25.099 / 1.81 / 1.0012 / 22.613 / [7]
16O-(2P) / He / 26.963 / 1.69 / 1.0010 / 25.551 / [7]
16O+(4S3/2) / He / 22.825 / 2.00 / 0.9987 / 24.173 / [9]
Ne / 8.3462 / 4.06 / 0.9958 / 8.8227 / [14]
Ar / 3.3455 / 3.35 / 8.19 / 1.0005 / 3.3244 / [17] / [G]
226Ra+(2S1/2) / He / 15.806 / 0.85 / 1.0001 / 14.926 / [23]
Ne / 7.0425 / 1.84 / 1.0002 / 6.7965 / [23]
Ar / 1.9604 / 6.40 / 0.9992 / 2.0923 / [23]
Kr / 1.0876 / 10.7 / 0.9991 / 1.1275 / [23]
Xe / 0.7311 / 14.9 / 1.0000 / 0.7338 / [23]
Rn / 0.5711 / 17.2 / 1.0008 / 0.5658 / [23]
226Ra2+(1S0) / He / 18.240 / 0.74 / 0.9999 / 19.195 / [23]
Ne / 5.6012 / 2.32 / 0.9999 / 5.7252 / [23]
Ar / 1.9818 / 6.32 / 1.0000 / 1.9813 / [23]
Kr / 1.1947 / 9.83 / 1.0000 / 1.1934 / [23]
Xe / 0.8077 / 13.5 / 0.9999 / 0.8058 / [23]
Rn / 0.6219 / 16.0 / 1.0000 / 0.6211 / [23]
85Rb+(1S0) / He / 19.756 / 1.98 / 1.0001 / 19.437 / [5]
Ne / 6.5450 / 6.50 / 4.73 / 0.9986 / 6.6943 / [5] / [A]
Ar / 2.3145 / 2.26 / 11.4 / 0.9976 / 2.3736 / [5] / [A]
Kr / 1.4559 / 1.45 / 13.6 / 0.9979 / 1.4915 / [5] / [B]
Xe / 1.0257 / 1.02 / 16.1 / 0.9992 / 1.0382 / [5] / [B]
Rn / 0.8337 / 15.6 / 0.9988 / 0.841 / [5]
222Rn+(2P3/2) / He / 17.373 / 0.78 / 1.0001 / 16.622 / [22]
Ne / 5.7231 / 2.28 / 0.9999 / 5.7422 / [24]
Ar / 1.9438 / 6.50 / 0.9998 / 1.9777 / [24]
Kr / 1.1709 / 10.0 / 0.9999 / 1.1768 / [24]
Xe / 0.8038 / 13.6 / 0.9996 / 0.8033 / [24]
222Rn+(2P1/2) / He / 17.304 / 0.78 / 1.0002 / 16.610 / [22]
Ne / 5.7758 / 2.28 / 0.9999 / 5.7906 / [24]
Ar / 1.9400 / 6.50 / 0.9997 / 1.9887 / [24]
Kr / 1.1490 / 10.0 / 0.9999 / 1.1567 / [24]
Xe / 0.7867 / 13.6 / 0.9996 / 0.7786 / [24]
222Rn+(2P) / He / 17.324 / 0.78 / 1.0000 / 16.612 / [22]
Ne / 5.7404 / 2.28 / 0.9999 / 5.7579 / [24]
Ar / 1.9423 / 6.49 / 0.9998 / 1.9813 / [24]
Kr / 1.1636 / 10.0 / 0.9999 / 1.1701 / [24]
Xe / 0.7986 / 13.8 / 0.9997 / 0.7955 / [24]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
32S-(2P3/2) / He / 19.468 / 2.34 / 1.0013 / 18.163 / [12]
32S-(2P1/2) / He / 17.433 / 2.61 / 1.0013 / 16.222 / [12]
32S-(2P) / He / 18.738 / 2.43 / 1.0013 / 17.466 / [12]
28Si+(2P3/2) / He / 19.613 / 2.60 / 1.0002 / 19.353 / [36]
Ne / 7.3849 / 4.86 / 0.9985 / 7.5112 / [36]
Ar / 2.8412 / 9.94 / 0.9984 / 2.8795 / [36]
28Si+(2P1/2) / He / 22.904 / 2.22 / 0.9987 / 23.363 / [36]
Ne / 7.1405 / 5.03 / 0.9952 / 7.5524 / [36]
Ar / 2.6272 / 10.8 / 1.0017 / 2.5913 / [36]
28Si+(2P) / He / 20.601 / 2.47 / 0.9999 / 20.527 / [36]
Ne / 7.3017 / 4.92 / 0.9975 / 7.5255 / [36]
Ar / 2.7655 / 10.2 / 0.9995 / 2.7758 / [36]
88Sr+(2S1/2) / He / 18.123 / 1.17 / 1.0002 / 17.273 / [23]
Ne / 8.4432 / 2.32 / 1.0000 / 8.3325 / [23]
Ar / 2.0950 / 8.60 / 0.9978 / 2.2415 / [23]
Kr / 1.2733 / 9.25 / 0.9957 / 1.3061 / [23]
Xe / 0.9200 / 15.1 / 1.0007 / 0.9144 / [23]
Rn / 0.7780 / 15.2 / 1.0011 / 0.7662 / [23]
88Sr2+(1S0) / He / 17.439 / 1.22 / 0.9999 / 18.087 / [23]
Ne / 5.8473 / 3.35 / 0.9999 / 5.8946 / [23]
Ar / 2.1933 / 8.22 / 1.0000 / 2.1912 / [23]
Kr / 1.4111 / 11.0 / 1.0000 / 1.4095 / [23]
Xe / 1.0043 / 13.8 / 1.0000 / 1.0020 / [23]
Rn / 0.8248 / 14.0 / 1.0000 / 0.8249 / [23]
205Tl+(1S0) / He / 18.991 / 0.74 / 1.0000 / 18.516 / [11]
Ne / 5.9262 / 2.29 / 0.9997 / 6.0862 / [11]
Ar / 1.9175 / 6.81 / 0.9998 / 1.9526 / [11]
Kr / 1.1599 / 10.4 / 1.0000 / 1.1622 / [11]
Xe / 0.8081 / 14.2 / 1.0003 / 0.7983 / [11]
238U+(4I9/2) / He / 14.671 / 0.96 / 1.0001 / 13.735 / [30]
Ne / 6.1562 / 2.20 / 1.0001 / 6.0066 / [30]
Ar / 2.0334 / 6.40 / 0.9990 / 2.1787 / [30]
Kr / 1.0819 / 11.1 / 0.9989 / 1.1310 / [30]
Xe / 0.7015 / 15.8 / 1.0002 / 0.7045 / [30]
132Xe+(2P3/2) / He / 17.961 / 0.97 / 1.0000 / 17.366 / [24]
Ne / 5.9721 / 2.76 / 0.9998 / 6.0313 / [24]
Ar / 2.0462 / 7.59 / 0.9997 / 2.0736 / [24]
Kr / 1.2852 / 10.8 / 0.9998 / 1.2925 / [24]
132Xe+(2P1/2) / He / 18.000 / 0.97 / 1.0001 / 17.334 / [24]
Ne / 6.0184 / 2.74 / 0.9998 / 6.0683 / [24]
Ar / 2.0448 / 7.60 / 0.9996 / 2.0902 / [24]
Kr / 1.2670 / 10.9 / 1.0001 / 1.2679 / [24]
300.00 K / 400.00 K
Ion / Gas / K0(0) / E/N / Ratio / K0(0) / References
Theory / Expt. / K0(0)/K0 / Theory / Theory / Expt.
132Xe+(2P) / He / 17.974 / 0.97 / 1.0003 / 17.354 / [24]
Ne / 5.9870 / 2.76 / 0.9998 / 6.0434 / [24]
Ar / 2.0471 / 2.07 / 7.59 / 0.9997 / 2.0806 / [24] / [E]
Kr / 1.2812 / 10.8 / 1.0000 / 1.2896 / [24]
174Yb+(2S1/2) / He / 19.108 / 19.4 / 2.05 / 1.0007 / 18.237 / [32] / [I]
Ne / 7.8609 / 3.94 / 0.9993 / 7.8933 / [32]
Ar / 1.8625 / 1.84 / 13.8 / 0.9972 / 1.9625 / [32] / [J]
Kr / 1.1072 / 17.8 / 0.9998 / 1.1194 / [32]
Xe / 0.7701 / 21.3 / 1.0013 / 0.7629 / [32]
64Zn+(2S1/2) / He / 23.818 / 1.04 / 0.9999 / 23.860 / [15]
Ne / 7.1036 / 3.14 / 0.9982 / 7.5705 / [15]
Ar / 2.1619 / 9.27 / 1.0004 / 2.1478 / [15]
Kr / 1.4691 / 11.4 / 1.0010 / 1.4525 / [15]
Xe / 1.0806 / 13.4 / 1.0011 / 1.0680 / [15]

References

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5. Hickling HL, Viehland LA, Shepherd DT, Soldan P, Lee EPF, Wright TG (2004) Spectroscopy of M+∙Rg and transport coefficients of M+ in Rg (M=Rb-Fr, Rg=He-Rn). Phys. Chem. Chem. Phys. 6:4233-4239
6. Buchachenko AA, Tscherbul TV, Klos J, Szczesniak MM, Chalasinski G, Webb R, Viehland LA (2005) Interaction potentials of the Rg-I anions, neutrals, and cations (Rg=He, Ne, Ar). J. Chem. Phys. 122:194311
7. Viehland LA, Webb R, Lee EPF, Wright TG (2005), Accurate potential energy curves of HeO-, NeO-, and ArO-: spectroscopy and transport coefficients J. Chem. Phys. 122:114302
8. Qing E, Viehland LA, Lee EPF, Wright TG (2006) Interaction potentials and spectroscopy of Hg+Rg and Cd+Rg and transport coefficients for Hg+ and Cd+ in Rg (Rg=He-Rn). J. Chem. Phys. 124:044316
9. Danailov DM, Brothers R, Viehland LA, Johnsen R, Wright TG, Lee EPF (2006) Mobility of O+ ions in He and interaction potential of HeO+. J. Chem. Phys. 125:084309
10. Gray BR, Wright TG, Wood EL, Viehland LA (2006) Accurate potential energy curves for F--Rg (Rg=He-Rn): Spectroscopy and transport coefficients. Phys. Chem. Chem. Phys. 8:4752-4757
11. Gray BR, Lee EPF, Yousef A, Shrestha S, Viehland LA, Wright TG (2006) Accurate potential energy curves for Tl+-Rg (Rg=He-Rn): Spectroscopy and transport coefficients. Mol. Phys. 104:3237-3244
12. Wright TG, Viehland LA (2006)Accurate potential energy curves for HeS-: spectroscopy and transport coefficients, Chem. Phys. Lett. 420:24-28.
13. Yousef A, Shrestha S, Viehland LA, Lee EPF, Gray BR, Ayles VL, Wright TG, Breckenridge WH (2007) Interaction potentials and transport properties of coinage metal cations in rare gases. J. Chem. Phys. 127:154309
14. Danailov DM, Viehland LA, Johnsen R, Wright TG, Dickinson AS (2007) Interaction potential and transport properties of NeO+. J. Chem. Phys. 127:084303
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19. Wright TG, Lee EPF, Viehland LA (2008) Interaction potential of Al3+-Ne and the mobility of Al3+ in He and Ne. Chem. Phys. Lett. 467:66-69
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6. Skullerud HR, Elford MT, Roeggen I (1996) The mobility of potassium ions in helium. J. Phys. B 29:1925-1939. The values reported at 295 K have been corrected to 300 K based on the ratio of the theoretical mobilities at these two temperature.
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8. Manard MJ, Kemper PR (2016) Characterizing the electronic states of the second-row transition metal cations using high-resolution ion mobility mass spectrometry. Int. J. Mass Spectrom. 407:69-76. The values reported at 295 K have been corrected to 300 K based on the ratio of the theoretical mobilities at these two temperature.
9. Manard MJ, Kemper PR (2016) Reduced mobilities of lanthanide cations measured using high-resolution ion mobility mass spectrometry with comparisons between experiment and theory. Int. J. Mass Spectrom. 412:14-19. The values reported at 295 K have been corrected to 300 K based on the ratio of the theoretical mobilities at these two temperature. The experimenters did not indicate which isotope they used, so it is assumed to be the one whose theoretical mobility lies closest to the reported value.
10. Laatiaoui M, Backe H, Habs D, Kunz P, Sewtz M (2014) Low-field mobilities of rare-earth metals. Eur. Phys. J. D 66:232

1