Section1.Identificationofthesubstanceorthemixtureandofthesupplier
1.1ProductIdentifier
Productidentifier:
FRESH ORANGE PN792840 (Contains:Citral, Geraniol, alpha-Terpineol,d-Limonene)
Otheridentifiers:None
1.2RelevantidentifiedusesofthesubstanceofmixtureandusesadvisedagainstProductuses:Fragrance
1.3Details of the supplier of the safety datasheet
Companyname:Sensory Perfection
Companyaddress:
135 Hughenden Road, Hastings, East Sussex, TN34 4TF, UK
Contact:Jo Cateley
E-Mailaddress:
Companyphone:
+44 1424 532737
1.4Emergency telephonenumberEmergencyphone:+44 1424 532737
Section2.Hazardsidentification
2.1Classification of the substance ormixture
Classification under Regulation (EC) No1272/2008
Classandcategoryofdanger:
Hazardsymbols:
Skin Corrosion / Irritation Category2 Eye Damage / Irritation Category2 Sensitization - Skin Category1 Aspiration Hazard Category1
Hazardous to the Aquatic Environment - Acute Hazard Category1 Hazardous to the Aquatic Environment - Long-term Hazard Category1 H304, May be fatal if swallowed and entersairways.
H315, Causes skinirritation.
H317, May cause an allergic skinreaction.H319, Causes serious eyeirritation.
H410, Very toxic to aquatic life with long lastingeffects.ClassificationunderDirective1999/45/EC
Xn,Harmful.
N, Dangerous for theenvironment.
Riskphrases:
2.2Labelelements
R38, Irritating to theskin.
R43, May cause sensitisation by skincontact.R65, May cause lung damage ifswallowed.
R50/53, Very toxic to aquatic organisms, may cause long-term adverse effects in theaquaticenvironment.
Signalword:
Danger
Hazardstatements:H304, May be fatal if swallowed and entersairways.
H315, Causes skinirritation.
H317, May cause an allergic skinreaction.H319, Causes serious eyeirritation.
H410, Very toxic to aquatic life with long lastingeffects.
SupplementalInformation:
Precautionarystatements:
Pictograms:
Otherhazards:
EUH208, Contains p-Mentha-6,8-dien-2-one, Geranyl acetate, Nerol, Citronellol,dl-Limonene (racemic). May produce an allergicreaction.
P261, Avoid breathing vapour ordust.
P264, Wash hands and other contacted skin thoroughly afterhandling.
P272, Contaminated work clothing should not be allowed out of theworkplace.P273, Avoid release to theenvironment.
P280, Wear protective gloves/eye protection/faceprotection.
P301/310, IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physician.P302/352, IF ON SKIN: Wash with plenty of soap andwater.
P305/351/338, IF IN EYES: Rinse cautiously with water for several minutes. Removecontactlenses, if present and easy to do. Continuerinsing.
P331, Do not inducevomiting.
P333/313, If skin irritation or rash occurs: Get medicaladvice/attention.P337/313, If eye irritation persists: Get medicaladvice/attention.
P362, Take off contaminated clothing and wash beforereuse.P391, Collectspillage.
P405, Store lockedup.
P501, Dispose of contents/container to approved disposal site, in accordance withlocal regulations.
None
Section3.Composition/informationoningredients
3.2MixturesContains:
d-Limonene / 5989-27-5 / 227-813-5 / 27.62% / Xn-N ;R10-R38-R43-R65- R50/53 / FL 3-SCI 2-SS 1-SS1B-AH1-EH A1-EHC1;H226-H304-H315-H317-H410,-
alpha-Terpineol / 98-55-5 / 202-680-6 / 2.00% / Xi ;R36/38 / SCI 2-EDI2;H315-H319,-
Linalool / 78-70-6 / 201-134-4 / 1.75% / Xi ;R38 / SCI 2-EDI2;H315-H319,-
Decanal / 112-31-2 / 203-957-4 / 1.65% / N ;R51/53 / SCI 2-EHC3;H315-H319-
H412,-
Citral / 5392-40-5 / 226-394-6 / 1.56% / Xi ;R38-R43 / SCI 2-EDI 2-SS1B;H315-
H317-H319,-
Myrcene / 123-35-3 / 204-622-5 / 0.67% / Xn ;R10-R38-R65 / FL 3-SCI 2-EDI 2-AH1;
H226-H304-H315-H319,-
Citronellol / 106-22-9 / 203-375-0 / 0.65% / Xi-N ;R38-R43-R51/53 / SCI 2-EDI 2-SS1B;H315-
H317-H319,-
Geraniol / 106-24-1 / 203-377-1 / 0.45% / Xi ;R38-R41-R43 / SCI 2-EDI 1-SS1;H315-
H317-H318,-
Nerol / 106-25-2 / 203-378-7 / 0.36% / Xi ;R43-R36/38 / SCI 2-EDI 2-SS1B;H315-
H317-H319,-
n-Octanal / 124-13-0 / 204-683-8 / 01-2119638274-38 / 0.36% / Xi-N ;R10-R36/38-R51/53 / FL 3-SCI 2-EDI 2-EHC2;
H226-H315-H319-H411,-
Terpinylacetate
(Isomermixture) / 8007-35-0 / 232-357-5 / 0.34% / Xi-N ;R38-R51/53 / EHC2;H411,-
p-Mentha-6,8-dien-2-
one / 6485-40-1 / 229-352-5 / 0.32% / Xi ;R43 / SS1B;H317,-
dl-Limonene(racemic) / 138-86-3 / 205-341-0 / 0.30% / Xn-N ;R10-R38-R43-R65- R50/53 / FL 3-SCI 2-SS 1-SS1B-AH
1-EH A1-EHC1;H226-H304-H315-H317-H410,-
Citronellylacetate / 150-84-5 / 205-775-0 / 0.24% / Xi-N ;R38-R51/53 / SCI 2-EHC2;H315-H411,-
Geranylacetate / 105-87-3 / 203-341-5 / 0.21% / Xi-N ;R38-R43-R51/53 / SCI 2-SS 1-EHC3;H315-
H317-H412,-
Ethylacetate / 141-78-6 / 205-500-4 / 0.18% / F-Xi ;R11-R36-R66-R67 / FL 2-EDI 2-STO-SE3(NE);
H225-H319-H336,-
p-Cymene / 99-87-6 / 202-796-7 / 0.15% / Xn-N ;R10-R65-R51/53 / FL 3-AH 1-EHC2;H226-
H304-H411,-
Octanal / 124-13-0 / 204-683-8 / 0.12% / Xi-N ;R10-R36/38-R51/53 / FL 3-SCI 2-EDI 2-EHC2;
H226-H315-H319-H411,-
Valencene / 4630-07-3 / 225-047-6 / 0.12% / Xn ;R10-R65 / AH1;H304,-
Nonanal / 124-19-6 / 204-688-5 / 0.10% / Xi-N ;R38-R51/53 / SCI 2-EHC3;H315-H319-
H412,-
beta-Caryophyllene / 87-44-5 / 201-746-1 / 0.05% / Xn ;R65 / AH1;H304,-
Tridecene-2-nitrile / 22629-49-8 / 245-142-6 / 0.04% / N ;R50/53 / EH A1-EHC1;H410,-
p-Mentha-1,4-diene / 99-85-4 / 202-794-6 / 0.03% / Xn ;R10-R65 / FL 3-AH1;H226-H304,-
alpha-Pinene / 80-56-8 / 201-291-9 / 0.01% / Xn ;R10-R38-R43-R65 / FL 3-SCI 2-SS 1B-AH1;
H226-H304-H315-H317,-
d-.alpha.-Pinene / 7785-70-8 / 232-087-8 / 0.008% / Xn-N ;R10-R38-R43-R65- R50/53 / FL 3-SCI 2-SS 1B-AH1-EH
A1-EHC1;H226-H304-H315-H317-H410,-
1,3,5-Undecatriene / 16356-11-9 / 240-416-1 / 0.006% / Xn-N ;R38-R65-R50/53 / SCI 2-AH 1-EH A1-EHC1;
H304-H315-H410,-
delta-3-Carene / 13466-78-9 / 236-719-3 / 0.006% / Xn-Xi ;R10-R38-R43-R65 / FL 3-SCI 2-SS 1B-AH1;
H226-H304-H315-H317,-
Terpinolene / 586-62-9 / 209-578-0 / 0.005% / Xn-N ;R43-R65-R50/53 / SS 1B-AH 1-EH A1-EHC1;
H304-H317-H410,-
cis-beta-Ocimene / 3338-55-4 / 222-081-3 / 0.004% / Xn ;R10-R65 / FL 3-AH1;H226-H304,-
beta-Pinene / 127-91-3 / 204-872-5 / 0.004% / Xn ;R10-R38-R43-R65 / FL 3-SCI 2-SS 1B-AH1;
H226-H304-H315-H317,-
SubstanceswithCommunityworkplaceexposurelimits,notlistedabove:
Name / CAS / EC / %1-Methoxypropan-2-ol / 107-98-2 / 203-539-1 / <0.001%
Dipropylene glycol monomethylether / 34590-94-8 / 0.006%
Ethylacetate / 141-78-6 / 205-500-4 / 0.18%
Propyleneglycol / 57-55-6 / 200-338-0 / <0.001%
Substancesthatarepersistent,bioaccumulativeandtoxicorverypersistentandverybioaccumulative,greaterthan0.1%:NotApplicable
Section4.First-aidmeasures
4.1Description of first aidmeasures
IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physician.IF ON SKIN: Wash with plenty of soap andwater.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continuerinsing.
4.2Mostimportantsymptomsandeffects,bothacuteanddelayed
May be fatal if swallowed and entersairways.Causes skinirritation.
May cause an allergic skinreaction.Causes serious eyeirritation.
4.3Indicationofanyimmediatemedicalattentionandspecialtreatmentneeded None expected, see Section 4.1 for furtherinformation.
SECTION 5: Firefightingmeasures
5.1Extinguishingmedia
Suitablemedia:Carbon dioxide, Dry chemical,Foam.
5.2Special hazards arising from the substance ormixture
In case of fire, may beliberated:Carbon monoxide, Unidentified organiccompounds.
5.3Advice for firefighters:
In case of insufficient ventilation, wear suitable respiratoryequipment.
Section6.Accidentalreleasemeasures
6.1Personalprecautions,protectiveequipmentandemergencyprocedures:
Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and8.
6.2Environmentalprecautions:
Keep away from drains, surface and ground water, andsoil.
6.3Methods and material for containment and cleaningup:
Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours. Containspillage immediately by use of sand or inert powder. Dispose of according to localregulations.
6.4Referencetoothersections:Also refer to sections 8 and13.
Section7.Handlingandstorage
7.1Precautions for safehandling:
Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipmentas required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas withadequateventilation Do not eat, drink or smoke when using thisproduct.
7.2Conditions for safe storage, including anyincompatibilities:
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container andreceiving equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools.Takeprecautionary measures against staticdischarge.
7.3Specific enduse(s):
Use in accordance with good manufacturing and industrial hygienepractices.
Section 8. Exposure controls/personal protection
8.1ControlparametersWorkplace exposurelimits:
Ingredient / CAS / EC / Description / Reference1-Methoxypropan-2-ol / 107-98-2 / 203-539-
1 / Long-term exposure limit(8-hour TWA referenceperiod) / 100 / 375 / UK EH40Oct2007
Short-term exposure limit(15- minute referenceperiod) / 150 / 560 / UK EH40Oct2007
Dipropyleneglycolmonomethylether / 34590-
94-8 / Long-term exposure limit(8-hour TWA referenceperiod) / 50 / 308 / UK EH40Oct2007
Short-term exposure limit(15- minute referenceperiod) / - / - / UK EH40Oct2007
Ethylacetate / 141-78-6 / 205-500-
4 / Long-term exposure limit(8-hour TWA referenceperiod) / 200 / - / UK EH40Oct2007
Short-term exposure limit(15- minute referenceperiod) / 400 / - / UK EH40Oct2007
Propyleneglycol / 57-55-6 / 200-338-
0 / Long-term exposure limit(8-hour TWA referenceperiod) / 150 / 474 / UK EH40Oct2007
Short-term exposure limit(15- minute referenceperiod) / - / - / UK EH40Oct2007
8.2ExposureControls
Eye / SkinProtection
Wear protective gloves/eye protection/faceprotectionRespiratoryProtection
Ensure adequate and ongoing ventilation is maintained in order to prevent build up of excessive vapour and toensure occupational exposure limits are adhered to. If appropriate, and depending on your patterns and volumes of use,thefollowing engineering controls may be required as additional protective measures: a) Isolate mixing rooms andotherareas where this material is used or openly handled. Maintain these areas under negative air pressure relative totherest of the plant. b) Employ the use of Personal protective equipment - an approved, properly fitted respiratorwithorganic vapour cartridges or canisters and particulate filters. c) Use local exhaust ventilation around open tanksand other open sources of potential exposures in order to avoid excessive inhalation, including places where this materialis openly weighed or measured. In addition, use general dilution ventilation of the work area to eliminate orreduce possible worker exposures. d) Use closed systems for transferring and processing thismaterial.
Also refer to Sections 2 and7.
Section9.Physicalandchemicalproperties
9.1Information on basic physical and chemicalproperties
Appearance:
Very Pale Yellow toYellow
Odour:Notdetermined
pH:Notdetermined
Initialboilingpoint/range:
Notdetermined
Flashpoint:> 61°C
Vapourpressure:
Notdetermined
Relativedensity:0.9400 -0.9600
Solubility(ies):Notdetermined
9.2Otherinformation:Noneavailable
Section10.Stabilityandreactivity
10.1Reactivity:
Presents no significant reactivity hazard, by itself or in contact withwater.
10.2Chemicalstability:
Good stability under normal storageconditions.
10.3Possibility of hazardousreactions:
Not expected under normal conditions ofuse.
10.4Conditions toavoid: Avoid extremeheat.
10.5Incompatiblematerials:
Avoid contact with strong acids, alkalis or oxidisingagents.
10.6Hazardous decompositionproducts:Notexpected.
Section 11.Toxicological information
11.1Informationontoxicologicaleffects
This mixture has not been tested as a whole for health effects. The health effects have been calculated usingthemethods outlined in Regulation (EC) No 1272/2008(CLP).
May be fatal if swallowed and entersairways.Causes skinirritation.
May cause an allergic skinreaction.Causes serious eyeirritation.
AssumedToxicityValue(LD50orATE)forAcuteOralToxicity:>5000AssumedToxicityValue(LD50orATE)forAcuteDermalToxicity: >5000AssumedToxicityValue(LC50orATE)forAcuteInhalationToxicity: NotAvailable
InhalationRoute:
InformationabouthazardousingredientsinthemixtureNotApplicable
Refer to Sections 2 and 3 for additionalinformation.
NotAvailable
Section12.Ecologicalinformation
12.1Toxicity:
Very toxic to aquatic life with long lastingeffects.
12.2Persistence anddegradability:
Notavailable
12.3Bioaccumulativepotential:Notavailable
12.4Mobility insoil:Notavailable
12.5Results of PBT and vPvBassessment:
This substance does not meet the PBT/vPvB criteria of REACH, annexXIII.
12.6Other adverseeffects:Notavailable
Section13.Disposalconsiderations
13.1 Waste treatmentmethods:
Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment.Emptycontainers should be taken to an approved waste handling site for recycling ordisposal.
Section14.Transportinformation
14.1UNnumber:UN3082
14.2UN Proper ShippingName:ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.(d-
Limonene,Tridecene-2-nitrile)
14.3Transporthazardclass(es):9
SubRisk:-
14.4. PackingGroup:III
14.5Environmental hazards:This is an environmentally hazardoussubstance.
14.6Specialprecautionsforuser:Noneadditional
14.7TransportinbulkaccordingtoAnnexIIofMARPOL73/78andtheIBCCode:Notapplicable
Section15.Regulatoryinformation
15.1Safety,healthandenvironmentalregulations/legislationspecificforthesubstanceormixture
Noneadditional
15.2Chemical SafetyAssessment
A Chemical Safety Assessment has not been carried out for thisproduct.
Section16.Otherinformation
Concentration %Limits:EH A1=88.26% EH C1=88.26% EH C2=8.83% EH C3=0.88210666%EH
C4=5.11% SCI 2=28.92% EDI 2=86.95% EDI 2A=86.95% SS 1=3.62%AH1=34.49%
TotalFractionalValues:EH A1=1.13 EH C1=1.13 EH C2=11.33 EH C3=113.36 EH C4=19.58SCI
2=3.46 EDI 2=1.15 EDI 2A=1.15 SS 1=27.62 AH1=2.90
Keytorevisions:
Notapplicable
Keytoabbreviations:
Abbreviation / MeaningAH1 / Aspiration Hazard Category1
EDI1 / Eye Damage / Irritation Category1
EDI2 / Eye Damage / Irritation Category2
EHA1 / Hazardous to the Aquatic Environment - Acute Hazard Category1
EHC1 / Hazardous to the Aquatic Environment - Long-term Hazard Category1
EHC2 / Hazardous to the Aquatic Environment - Long-term Hazard Category2
EHC3 / Hazardous to the Aquatic Environment - Long-term Hazard Category3
FL2 / Flammable Liquid, Hazard Category2
FL3 / Flammable Liquid, Hazard Category3
H225 / Highly flammable liquid andvapour.
H226 / Flammable liquid andvapour.
H304 / May be fatal if swallowed and entersairways.
H315 / Causes skinirritation.
H317 / May cause an allergic skinreaction.
H318 / Causes serious eyedamage.
H319 / Causes serious eyeirritation.
H336 / May cause drowsiness ordizziness.
H410 / Very toxic to aquatic life with long lastingeffects.
H411 / Toxic to aquatic life with long lastingeffects.
H412 / Harmful to aquatic life with long lastingeffects.
P210 / Keep away from heat, sparks, open flames and hot surfaces. - Nosmoking.
P233 / Keep container tightlyclosed.
P240 / Ground/bond container and receivingequipment.
P241 / Use explosion-proof electrical, ventilating and lightingequipment.
P242 / Use only non-sparkingtools.
P243 / Take precautionary measures against staticdischarge.
P261 / Avoid breathing vapour ordust.
P264 / Wash hands and other contacted skin thoroughly afterhandling.
P271 / Use only outdoors or in a well-ventilatedarea.
P272 / Contaminated work clothing should not be allowed out of theworkplace.
P273 / Avoid release to theenvironment.
P280 / Wear protective gloves/eye protection/faceprotection.
P301/310 / IF SWALLOWED: Immediately call a POISON CENTER ordoctor/physician.
P302/352 / IF ON SKIN: Wash with plenty of soap andwater.
P303/361/353 / IF ON SKIN (or hair): Remove/take off immediately all contaminated clothing. Rinse skinwith
water/shower.
P304/340 / IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable forbreathing.
P305/351/338 / IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy
to do. Continuerinsing.
P310 / Immediately call a POISON CENTER ordoctor/physician.
P312 / Call a POISON CENTRE or doctor/physician if you feelunwell.
P331 / Do not inducevomiting.
P332/313 / If skin irritation occurs: Get medicaladvice/attention.
P333/313 / If skin irritation or rash occurs: Get medicaladvice/attention.
P337/313 / If eye irritation persists: Get medicaladvice/attention.
P362 / Take off contaminated clothing and wash beforereuse.
P363 / Wash contaminated clothing beforereuse.
P370/378 / In case of fire: Use carbon dioxide, dry chemical, foam forextinction.
P391 / Collectspillage.
P403/233/235 / Store in a well-ventilated place. Keep container tightly closed. Keepcool.
P403/235 / Store in a well-ventilated place. Keepcool.
P405 / Store lockedup.
P501 / Dispose of contents/container to approved disposal site, in accordance with localregulations.
SCI2 / Skin Corrosion / Irritation Category2
SS1 / Sensitization - Skin Category1
SS1B / Sensitization - Skin Category1B
STO-SE3(NE) / Specific Target Organ Toxicity (Single Exposure) Category3
The information in this safety data sheet is to the best of our knowledge true and accurate but all data,instructions,recommendations and/or suggestions are made withoutguarantee.