Ypsiyunnosides A-E, Five New Cholestanol Glycosides from Ypsilandrayunnanensis

Supplementary Data for

Ypsiyunnosides A-E, Five New Cholestanol Glycosides from Ypsilandrayunnanensis

Yu Chena, b,1,Yong-Ai Si a, b,1, Wei Nia, Huan Yana, Xu-Jie Qina, Chang-Xiang Chena, Hai-YangLiu*, a

a State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming 650201, China

b University of ChineseAcademy of Sciences, Beijing 100039, China

*Corresponding author.

Tel/Fax: +86-871-65223246.

E-mail address: (H.-Y. Liu).

1 These authors contributed equally to this work.

Table of contents

Figure 1S. 1H NMR spectrum of compound 1 (pyridine-d5, 400 MHz).

Figure 2S.13C NMR spectrum of compound 1 (pyridine-d5, 100 MHz).

Figure 3S. HSQC spectrum of compound 1 (pyridine-d5, 500 MHz).

Figure 4S.HMBC spectrum of compound 1 (pyridine-d5, 500 MHz).

Figure 5S.1H-1H COSY spectrum of compound 1 (pyridine-d5, 500 MHz).

Figure 6S. ROESY spectrum of compound 1 (pyridine-d5, 500 MHz).

Figure 7S.1H NMR spectrum of compound 2 (pyridine-d5, 600 MHz).

Figure 8S.13C NMR spectrum of compound 2 (pyridine-d5, 150 MHz).

Figure 9S. HSQC spectrum of compound 2 (pyridine-d5, 600 MHz).

Figure 10S. HMBC spectrum of compound 2 (pyridine-d5, 600 MHz).

Figure 11S.1H-1H COSY spectrum of compound 2 (pyridine-d5, 600 MHz).

Figure 12S. 1H NMR spectrum of compound 3 (pyridine-d5, 600 MHz).

Figure 13S.13C NMR spectrum of compound 3 (pyridine-d5, 150 MHz).

Figure 14S. HSQC spectrum of compound 3 (pyridine-d5, 600 MHz).

Figure 15S. HMBC spectrum of compound 3 (pyridine-d5, 600 MHz).

Figure 16S. 1H-1H COSY spectrum of compound 3 (pyridine-d5, 600 MHz).

Figure 17S. 1H NMR spectrum of compound 4 (pyridine-d5, 600 MHz).

Figure 18S.13C NMR spectrum of compound 4 (pyridine-d5, 150 MHz).

Figure 19S. HSQC spectrum of compound 4 (pyridine-d5, 600 MHz).

Figure 20S. HMBC spectrum of compound 4 (pyridine-d5, 600 MHz).

Figure 21S. 1H NMR spectrum of compound 5 (pyridine-d5, 600 MHz).

Figure 22S.13C NMR spectrum of compound 5 (pyridine-d5, 150 MHz).

Figure 23S. HSQC spectrum of compound 5 (pyridine-d5, 600 MHz).

Figure 24S. HMBC spectrum of compound 5 (pyridine-d5, 600 MHz).

Figure 1S.1H NMR spectrum of compound 1 (pyridine-d5, 400 MHz).

Figure 2S.13C NMR spectrum of compound 1 (pyridine-d5, 100MHz).