SAFETY DATA SHEET
1. Identification
Product identifier FAS-MARK Cover Paint
Other means of identification FM150, FM15Y, FM15BR, FM15R, FM15G, FM15BL, FM15P. FM15W, FM15B, FM 15BRZ
Company name FEDERAL PROCESS CORPORATION
ADDRESS
Emergency phone number
4520 Richmond Road
Cleveland, Ohio 44128
Chemtrec Phone
800-424-9300
2. Hazard(s) identification
Physical hazards Health hazards
Environmental hazards
OSHA defined hazards Label elements
Flammable aerosols Gases under pressure
Serious eye damage/eye irritation Carcinogenicity
Reproductive toxicity
Specific target organ toxicity, single exposure
Specific target organ toxicity, repeated exposure
Hazardous to the aquatic environment, acute hazard
Hazardous to the aquatic environment, long-term hazard
Not classified.
Category 1 Liquefied gas Category 2A Category 1A Category 2
Category 3 narcotic effects Category 1
Category 2
Category 3
Signal word Danger
Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. May cause drowsiness or dizziness. May cause cancer. Suspected of damaging fertility or the unborn child. Causes damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Harmful to aquatic life with long lasting effects.
Precautionary statement
Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection.
Response If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention.
Material name: FAS-MARK Cover Paint
Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from sunlight. Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
Hazard(s) not otherwise classified (HNOC)
None known.
Supplemental information 55.82% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 55.82% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment.
3. Composition/information on ingredients
Mixtures
Chemical name
Common name and synonyms
CAS number %
ACETONE N-BUTANE PROPANE
BARIUM SULFATE TITANIUM DIOXIDE 2-PENTANONE
PROPYLENE GLYCOL METHYL ETHER ACETATE
TALC XYLENE
ETHYLBENZENE
SILICA, CRYSTALLINE QUARTZ
67-64-1
106-97-8
74-98-6
7727-43-7
13463-67-7
107-87-9
108-65-6
14807-96-6
1330-20-7
100-41-4
14808-60-7
30 to <40
10 to <20
10 to <20
5 to <10
5 to <10
1 to <5
1 to <5
1 to <5
1 to <5
0.1 to <1
0.1 to <1
Other components below reportable levels 10 to <20
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell.
Skin contact No adverse effects due to skin contact are expected. Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. No specific first aid measures noted.
Ingestion Not likely, due to the form of the product. In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.
Most important symptoms/effects, acute and delayed
Indication of immediate medical attention and special treatment needed
May cause drowsiness and dizziness. Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Prolonged exposure may cause chronic effects.
Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed.
General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance.
5. Fire-fighting measures
Suitable extinguishing media Alcohol resistant foam. Water fog. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing media
Specific hazards arising from the chemical
Special protective equipment and precautions for firefighters
Do not use water jet as an extinguisher, as this will spread the fire.
Contents under pressure. Pressurized container may explode when exposed to heat or flame. During fire, gases hazardous to health may be formed.
Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.
Fire fighting equipment/instructions
In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed to heat. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes.
General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may explode when exposed to heat or flame.
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Methods and materials for containment and cleaning up
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS.
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has dispersed. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth and place into containers. Prevent product from entering drains. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases.
7. Handling and storage
Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment used when handling the product must be grounded. Do not re-use empty containers. Do not breathe mist or vapor. Avoid contact with eyes. Avoid prolonged exposure. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment.
Observe good industrial hygiene practices.
Conditions for safe storage, including any incompatibilities
Level 2 Aerosol.
Store locked up. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Secure cylinders in an upright position at all times, close all valves when not in use. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components
Type
Value
Form
2-PENTANONE (CAS
107-87-9)
ACETONE (CAS 67-64-1)
BARIUM SULFATE (CAS 7727-43-7)
PEL 700 mg/m3
200 ppm
PEL 2400 mg/m3
1000 ppm
PEL 5 mg/m3 Respirable fraction.
15 mg/m3 Total dust.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
Components / Type / Value / FormETHYLBENZENE (CAS 100-41-4) / PEL / 435 mg/m3
100 ppm
PROPANE (CAS 74-98-6) / PEL / 1800 mg/m3
1000 ppm
TITANIUM DIOXIDE (CAS 13463-67-7) / PEL / 15 mg/m3 / Total dust.
XYLENE (CAS 1330-20-7) / PEL / 435 mg/m3
100 ppm
US. OSHA Table Z-3 (29 CFR 1910.1000)
Components / Type / Value / Form
SILICA, CRYSTALLINE QUARTZ (CAS 14808-60-7) / TWA / 0.3 mg/m3 / Total dust.
0.1 mg/m3 / Respirable.
2.4 mppcf / Respirable.
TALC (CAS 14807-96-6) / TWA / 0.3 mg/m3 / Total dust.
0.1 mg/m3 / Respirable.
20 mppcf
2.4 mppcf / Respirable.
US. ACGIH Threshold Limit Values
Components / Type / Value / Form
2-PENTANONE (CAS
107-87-9) / STEL / 150 ppm
ACETONE (CAS 67-64-1) / STEL / 750 ppm
TWA / 500 ppm
BARIUM SULFATE (CAS 7727-43-7) / TWA / 5 mg/m3 / Inhalable fraction.
ETHYLBENZENE (CAS 100-41-4) / TWA / 20 ppm
N-BUTANE (CAS 106-97-8) / STEL / 1000 ppm
SILICA, CRYSTALLINE QUARTZ (CAS 14808-60-7) / TWA / 0.025 mg/m3 / Respirable fraction.
TALC (CAS 14807-96-6) / TWA / 2 mg/m3 / Respirable fraction.
TITANIUM DIOXIDE (CAS 13463-67-7) / TWA / 10 mg/m3
XYLENE (CAS 1330-20-7) / STEL / 150 ppm
TWA / 100 ppm
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
Form
2-PENTANONE (CAS
107-87-9)
ACETONE (CAS 67-64-1)
BARIUM SULFATE (CAS 7727-43-7)
ETHYLBENZENE (CAS 100-41-4)
N-BUTANE (CAS 106-97-8)
PROPANE (CAS 74-98-6)
TWA 530 mg/m3
150 ppm
TWA 590 mg/m3
250 ppm
TWA 5 mg/m3 Respirable.
10 mg/m3 Total
STEL 545 mg/m3
125 ppm
TWA 435 mg/m3
100 ppm
TWA 1900 mg/m3
800 ppm
TWA 1800 mg/m3
US. NIOSH: Pocket Guide to Chemical Hazards
Components
Type
Value
1000 ppm
Form
SILICA, CRYSTALLINE QUARTZ (CAS 14808-60-7)
TALC (CAS 14807-96-6)
TWA 0.05 mg/m3 Respirable dust.
TWA 2 mg/m3 Respirable.
US. Workplace Environmental Exposure Level (WEEL) Guides Components Type
Value
PROPYLENE GLYCOL METHYL ETHER ACETATE (CAS 108-65-6)
Biological limit values
ACGIH Biological Exposure Indices
TWA 50 ppm
ACETONE (CAS 67-64-1) / 50 mg/l / Acetone / Urine / *
ETHYLBENZENE (CAS 100-41-4) / 0.15 g/g / Sum of mandelic acid / Creatinine in urine / *
and
phenylglyoxylic
acid
XYLENE (CAS 1330-20-7) / 1.5 g/g / Methylhippuric acids / Creatinine in urine / *
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
PROPYLENE GLYCOL METHYL ETHER ACETATE (CAS 108-65-6)
Can be absorbed through the skin.
Appropriate engineering controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station.
Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles).
Skin protection
Hand protection For prolonged or repeated skin contact use suitable protective gloves.
Other Wear suitable protective clothing.
Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an air-supplied respirator.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene considerations
When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance
Physical state Liquid.
Form Aerosol. Liquefied gas.
Color Not available.
Odor Not available.
Odor threshold Not available.
pH Not available.
Melting point/freezing point -305.68 °F (-187.6 °C) estimated
Initial boiling point and boiling range
-43.78 °F (-42.1 °C) estimated