Supporting Information

1.Supplementary Tables

Table S1 Major chemical characteristics of the mine spoil used for the experiment

Parameter / Mine spoil / Method
Organic matter content (%) / 0.54 / Walkley–Black method
Mineral composition / Jarosite (28%), gypsum (27%), quartz (25%), feldspar (6%), elemental S (4%), anglesite (4%) / XRD
MgO(%) / 0.65 / XRF
Al2O3(%) / 6.96
SiO2(%) / 33.3
SO3(%) / 27.8
K2O(%) / 2.86
CaO(%) / 8.70
PbO(%) / 3.41
MnO(%) / 0.02
Fe2O3(%) / 14.7
CuO(%) / 0.31
ZnO(%) / 0.25
Water-extractable K (mg/kg) / 2.03 / 1:5 water extract,measured by AAS
Water-extractable Na (mg/kg) / 9.02
Water-extractable Ca (mg/kg) / 2846
Water-extractable Mg (mg/kg) / 28.1
Water-extractable Fe (mg/kg) / 35.7
Water-extractable Mn (mg/kg) / 5.12
Water-extractable Cu (mg/kg) / 9.99
Water-extractable Zn (mg/kg) / 26.9
Water-extractable Pb (mg/kg) / 18.2
Water-extractable Cd (mg/kg) / 0.45
Water-extractable Cr (mg/kg) / 0.04
NH4Cl-extractable K (mg/kg) / 5.97 / 1:5 NH4Cl extract,measured by AAS
NH4Cl-extractable Na (mg/kg) / 10.5
NH4Cl-extractable Ca (mg/kg) / 8574
NH4Cl-extractable Mg (mg/kg) / 23.6
NH4Cl-extractable Fe (mg/kg) / 71.8
NH4Cl-extractable Mn (mg/kg) / 4.98
NH4Cl-extractable Cu (mg/kg) / 13.7
NH4Cl-extractable Zn (mg/kg) / 30.4
NH4Cl-extractable Pb (mg/kg) / 869
NH4Cl-extractable Cd (mg/kg) / 0.77
NH4Cl-extractable Cr (mg/kg) / 0.06

Table S2 Some elements contained in the straw clippings used for the incubation experiment

Element / Average / SD (n=3)
Zn (mg kg-1) / 43.8 / 0.23
Cd (mg kg-1) / 0.41 / 0.10
Cu (mg kg-1) / 10.3 / 0.44
Pb (mg kg-1) / 1.25 / 0.17
P (g kg-1) / 0.71 / 0.03
N (g kg-1) / 30.5 / 2.81
K (g kg-1) / 33.6 / 0.03

2.Supplementary Figure

The Control (C)

Treatment 1 (T1)

Treatment 2 (T2)

Figure S1 Schematic diagram showing the experimental apparatus for the incubation experiment