Last update September2018
Luca GonsalviItalian citizen, male, married
/ Address: ICCOM-CNR
Area di Ricerca di Firenze, room C163
Via Madonna del Piano 10
50019 Sesto Fiorentino (FI), Italy(EU)
Email:
Phone: +39 055 5225251
Fax: +39 055 5225203
Keywords: sustainable chemistry by catalysis (homogeneous catalysis: hydrogenation, oxidation, carbonylation, hydroformylation; heterogenised catalysts); synthesis and mechanisms (catalytic mechanisms; organometallic chemistry in water; white phosphorus coordination); catalysis for hydrogen production and storage (formic acid dehydrogenation; carbon dioxide hydrogenation).
Education and Research
Researcher (2001-2009), Senior Researcher (since 2010)andGroup Leader (since 2009)
Istituto di Chimica dei Composti Organometallici, Area di Ricerca CNR di Firenze (ICCOM-CNR), Sesto Fiorentino, Firenze, Italy, 2001-present
Research Lines: (a) Hydrogen production and storage by HCOOH/CO2catalyticdehydrogenation / hydrogenation cycle; (b) Synthesis of novel water soluble transition metal cyclopentadienyl complexes [(C5R5)MX(PTA)2] (R = H, Me; M = Ru, Re, Rh, Ir; X = H, halogen, solvent; PTA = 1,3,5-triaza-7-phosphaadamantane) and use as regioselective catalysts for hydrogenation of unsaturated substrates in aqueous biphasic conditions; (c) P4 chemical activation via mono- and bimetallic complexes; (d) water soluble organometallics as antimetastatic drugs.
Postdoctoral Research Fellow(Supervisors Prof. Dr. Roger A. Sheldon, Prof. Dr. Isabel W. C. E. Arends)
DelftUniversity of Technology (TUD) and IOP Catalysis, The Netherlands, 1999-2001
Research Project: Catalytic oxidation of ethers and acetals to esters. Development and optimisation of highly selective oxidation protocols for the catalytic conversion of ethers and acetals to esters with high atom efficiency and low E-factor, using oxygen/air, hydrogen peroxide and other cheap oxidants (i.e. hypochlorite), under homogeneous, heterogeneous, biphasic conditions.
Doctor of Philosophy – Organometallic Chemistry and Catalysis (Supervisors Dr. Anthony Haynes, Prof. Peter M. Maitlis FRS)University of Sheffield and BP Chemicals, United Kingdom, 1996-1999.
Research Project: “Ligand Effects on Homogeneous Methanol Carbonylation”. Synthesis of chelated complexes [M(CO)I(LL)] (M = Rh, Ir; LL = PS, PP, PO, NN bidentate ligands) and kinetic studies of oxidative addition and migratory insertion in the reaction with MeI as models for stereoelectronic ligand effects in methanol carbonylation.
Postgraduate Grant Holder (Supervisors Prof. Giovanni Predieri, Prof. Mirco Costa)
Department of General and Inorganic Chemistry, University of Parma, Italy, 1994.
Research Project: Study of catalytic properties of xerogel-bonded ruthenium clusters. Synthesis of organically-modified materials by sol-gel process; binding of ruthenium clusters and application in alkyne hydrogenation and olefin hydroformylation processes.
Laurea in Chimica (Supervisors Prof. Giovanni Predieri, Prof. Antonio Tiripicchio)
University of Parma, Italy (M. Sc. Hons Chemistry, 5 years course, 12 months research project), 1987-1993.
Research Project: “New hybrid inorganic-organic materials from sol-gel process. Applications in catalysis and precious metals recovery”. Synthesis of thiourea-modified silica by sol-gel process, binding of Rh(I) and Pd(II) and application in alkyne hydrogenation and olefin hydroformylation. Use of the materials as stationary phase for selective extraction of Pd(II), Rh(I), Ru(III), Ag(I), Pt(IV) from acidic aqueous solutions.
Technical Skills
Schlenk, vacuum and inert-atmosphere manipulation of moderate air, moisture sensitive organometallic and organic compounds. Liquid phase NMR including multi-nuclear, variable temperature, sapphire tube HP-NMR. Fischer-Porter apparatus and Parr autoclaves. Synthesis of heterogenised catalysts via LDH and modified silica. Fully conversed in GC, GC-MS, HPLC techniques and HP-IR, IR, UV-vis spectroscopy. Non-standard analytical techniques (SEM, XRF).Solvent and reagent purification, product isolation using vacuum distillation, crystallization or sublimation. Graphic design, molecular visualization (Chemdraw, Chem3D, ISIS Draw) Detailed knowledge and use of MS Office and other packages (PC and Macintosh). On-line multimedia presentations for progress report and meetings.
Bibliometric Data
-(WoS, 25/09/2018): results: 103; sum of times cited: 3183; citing articles: 2104; average citation per item: 30.9; h-index: 31.Researcher ID: D-8393-2011; ORCID ID: 0000-0002-5996-6307.Research Gate: Luca Gonsalvi’s profile; Publons: 1219067
Teaching and Supervisor Activity
Tutor of more than 30 young researchers, postdoctoral, doctoral, visiting and graduate students, since 1999, including: Scientific supervision of 3 doctoral and 3 postdoctoral projects, ICCOM-CNR (2008-present); Scientific supervision of 2 postdoctoral projects (FP6 MC-RTN Aquachem), ICCOM-CNR, 2004-2007; Scientific supervision of 3 postdoctoral projects (FP5 MC-RTN Hydrochem), ICCOM-CNR, May 2003-2005; Full supervision of a IAESTE 3-months stage undergraduate project, TUD, 2001; Co-supervision of a 3rd year undergraduate project, University of Sheffield, 1999; Three years demonstrating in inorganic chemistry undergraduate teaching laboratories, University of Sheffield, 1996-1999; Tutorship for General and Inorganic Chemistry undergraduate Chemistry students, University of Parma, 1992-1994. Co-supervision of undergraduate final year projects in Inorganic Chemistry, University of Parma, 1994; Demonstrating in inorganic and analytical chemistry undergraduate teaching laboratories, University of Parma, 1992-1994.Lecture course on Homogeneous Catalysis (postgraduate level), University of Florence, 2013.
Management Activities
-Principal Investigator (PI) in WG2 of COST Action CA15106“CHAOS – C-H Activation in Organic Synthesis” (2016-2020); Principal Investigator (PI) in WG2 of COST Action CM1205 “CARISMA - Catalytic Routines for Small Molecules Activation” (2013-2017).
-National Coordinator forWP2 of CNR project EFOR“Progetti CNR per il Mezzogiorno” (2011-2015)
-ICCOM Group Leader: Chemical Hydrogen Storage and Production by Organic Hydrides (Formic acid and CO2 catalyzed activations)
-ICCOM Group Leader: Homogeneous Catalysis in Water and Biphasic Systems (Water-soluble ligands, organometallic complexes and application in catalytic hydrogenation and hydroformylation)
-ManagerofStrategic CNR Activity Module PM03.005.001 (Hydrogen production and Storage) and Curiosity-Driven CNR Activity DG.RSTL.020.004 (Valorisation of Inorganic Feedstocks)
-Project Writing and Partecipation to International (FP6 and FP7 MC Actions, COST, INTAS, EERA), National (PRIN), CNR (Premiale, Cluster, Mezzogiorno), Ministry for Environment (PIRODE), ECRF Foundation (Hydrolab, Hydrolab2, Hydrolab-2.0, Energylab) and Region Tuscany (EBH2, Vecoprebio) Projects (2004-present).
-Principal Investigator for bilateral CNR-CNRS Project (Italy-France) 2010-2012
-Principal Investigator for Joint Mobility Project Italy-USA 2008-2010 (joint reviewed), Ministry for Foreign Affairs.
-Scientific Secretary of ICOMC-2018, 28th International Conference of Organometallic Chemistry, Florence 15-20/7/2018; COGICO-9, 9th Interdivisional Congress of Organometallic Chemistry, Florence 8-11/6/2010; EWPC-6, 6th European Workshop on Phosphorus Chemistry, Florence 26-27/3/2009.
-Network Manager of Project AQUACHEM, Transition Metal Chemistry and Catalysis in Aqueous Media (FP6 RTN project n° MRTN-CT-2003-503864) 2004-2008.
Other Activities
-National Habilitation (ASN 2016) as Full Professor in Inorganic Chemistry, peer-reviewed national habilitation procedure, validity: 12/04/2017 - 12/04/2023. National Habilitation as Associate Professor in Inorganic Chemistry (ASN 2013).
-Member elected of Scientific Committee of ICCOM (2009-present).
-Peer-reviewer for scientific journals including Angew. Chem Int. Ed.,Chem. Eur. J.,ChemSusChem, Eur. J. Inorg. Chem., Beilstein J. Org. Chem. (Wiley);J. Am. Chem Soc., Chem. Rev., Organometallics, Inorg. Chem., ACS Catal., ACS Appl. Mat. & Interfaces (ACS);Coord. Chem. Rev., J. Organomet. Chem., Appl. Catal. A Gen.,Appl. Catal. B Environm., Inorg. Chim. Acta, Inorg. Chem. Commun., Catal. Commun., J. Catal., Catal. Today, J. CO2 Utilization (Elsevier);Chem. Commun., Catal. Sci. Tech., Green Chem., New J. Chem. (RSC); Inorganics, Molecules (MDPI). See review activity on Publons.
-Visiting Scientist: UNAM (Mexico), 2004; INEOS-RAS (Russia), 2006; CNRS-Université d’Artois (France), 2010-2011; LIKAT Rostock (Germany), 2011; EPFL Lausanne (Switzerland), 2013.
-Italian National Service, 12 months, 1995
-Languages: English (fluent), Spanish (advanced), Dutch (basic), French (basic), Italian (native).
Awards and Memberships
Awards, Fellowships
-CNR Career Development Prize 2005
-University of Sheffield Turner Prize for best Chemistry PhD Thesis, 2000.
Professional Affiliations
-Member, Royal Society of Chemistry (MRSC),1997-2005; CO2Chem Network, 2013-2016; EERA and EEC, since 2013.
References
Em. Prof. Dr. Roger A. SheldonDr. Anthony Haynes and Em. Prof. Peter M. Maitlis FRS
DelftUniversity of Technology, Delft (NL)Department of Chemistry,University of Sheffield, Sheffield (UK)
Email: -mail: ;
Publications – JCR Articles
1.Armstrong, D.; Kirk, S. M.; Murphy, C.; Guerriero, A.; Peruzzini,M.; Gonsalvi,L.; Phillips, A. D.
Water-soluble Silver(I) Complexes Featuring the Hemi-labile 3,7-dimethyl-1,3,5-triaza-7-phosphabicyclo[3.3.1]nonane Ligand: Synthesis, Characterization and Antimicrobial Activity
Inorg. Chem.2018, 57, 6309-6323[article]
2.Guerriero, A.; Peruzzini, M.; Gonsalvi, L.
Ruthenium(II)-Arene Complexes of the Water-Soluble Ligand CAP as Catalysts for Homogeneous Transfer Hydrogenations in Aqueous Phase
Catalysts2018, 8, 88 [article] – Special Issue Homogeneous Catalysis and Mechanisms in Water and Biphasic Media
3.Marcos, R.; Bertini, F.; Rinkevicius, Z.; Peruzzini, M.; Gonsalvi, L.; Ahlquist, M. S. G.
Mechanistic studies on NaHCO3 hydrogenation and HCOOH dehydrogenation reactions catalysed by a Fe(II) linear tetraphosphine complex
Chem. Eur. J. 2018, 24, 5366-5372 [article]
4.Guerriero, A.; Peruzzini, M.; Gonsalvi, L.
Coordination chemistry of 1,3,5-triaza-7-phosphatricyclo[3.3.1.1]decane (PTA) and derivatives. Part III. Variations on a theme: novel architectures, materials and applications
Coord. Chem. Rev.2018, 355,328–361 [article] – Highly Cited Paper (top 1%) May/June 2018
5.Bertini, F.; Glatz, M.; Gorgas, N.; Stöger, B.; Peruzzini, M.; Veiros, L. F.; Kirchner, K.; Gonsalvi, L.
Carbon Dioxide Hydrogenation Catalysed by Well-defined Mn(I) PNP Pincer Hydride Complexes
Chem. Sci.2017, 8, 5024-5029 [article] – Highly Cited Paper (top 1%) May/June 2018
6.Guerriero, A.; Oberhauser, W.; Riedel, T.; Peruzzini, M.; Dyson, P. J.; Gonsalvi, L.
New Class of Half-Sandwich Ruthenium(II) Arene Complexes Bearing the Water-Soluble CAP Ligand as an in Vitro Anticancer Agent
Inorg. Chem. 2017, 56, 5514–5518 [article]
7.Nicolas, E.; Guerriero, A.; Lyaskovskyy, V.; Peruzzini, M.; Lammertsma, K.; Gonsalvi, L.; Slootweg, J.C.
Metal-Free Reduction of Phosphine Oxides Using Polymethylhydrosiloxane
Inorganics 2016, 4, 34−41[article] upon invitation for Special Issue Organophosphorus 2016
8.Mellone, I; Gorgas, N.; Bertini, F.; Peruzzini, M.; Kirchner, K.; Gonsalvi, L.
Selective Formic Acid Dehydrogenation Catalyzed by Fe-PNP Pincer Complexes Based on the 2,6-Diaminopyridine Scaffold
Organometallics 2016, 35, 3344−3349 [article]
9.Mellone, I.; Bertini, F.; Peruzzini, M.; Gonsalvi, L.
An active, stable and recyclable Ru(II) tetraphosphine-based catalytic system for hydrogen production by selective formic acid dehydrogenation
Catal. Sci. & Technol. 2016, 6, 6504-6512 [article]
10.Bertini, F.; Gorgas, N.; Stöger, B.; Peruzzini, M.; Veiros, L. F.; Kirchner, K.; Gonsalvi, L.
Efficient and Mild Carbon Dioxide Hydrogenation to Formate Catalyzed by Fe(II)-Hydridocarbonyl Complexes bearing 2,6-(diaminopyridyl)diphosphine Pincer Ligands
ACS Catal. 2016, 6, 2889−2893 [article] – Highly Cited Paper (top 1%) September/October 2016
11.Kalsin, A.M.; Peganova, T. A.; Novikov, V. V.; Peruzzini, M.; Gonsalvi, L.
Cooperative effects of ruthenium micellar catalysts and added surfactants in transfer hydrogenation of ketones in water
Catal. Sci. & Technol. 2015,5, 4458 – 4465.[article]
12.Mellone, I.; Bertini, F.;Gonsalvi, L.; Guerriero, A.; Peruzzini, M.
New wind in old sails: Novel Applications of Triphos-based Transition Metal Complexes as Homogeneous Catalysts for Small Molecules and Renewables Activation
Chimia2015, 69, 331-338. [article]
13.Sordakis, K.; Guerriero, A.; Bricout, H.; Peruzzini, M.; Dyson, P. J.; Monflier, E. Hapiot, F.; Gonsalvi, L.; Laurenczy, G.
Homogenous catalytic hydrogenation of bicarbonate with water soluble biaryl phosphine ligands
Inorg. Chim. Acta2015, 431, 132-138. [article]
14.Jumde, V. R.; Gonsalvi, L.; Guerriero, A.; Peruzzini, M.; Taddei, M.
A Ruthenium-Based Catalytic System for a Mild Borrowing-Hydrogen Process
Eur. J. Org. Chem. 2015, 1829-1833[article]
15.Bertini, F.; Mellone, I.; Ienco, A.; Peruzzini, M.; Gonsalvi, L.
Iron(II) Complexes of the Linear rac-Tetraphos-1 Ligand as Efficient Homogeneous Catalysts for Sodium Bicarbonate Hydrogenation and Formic Acid Dehydrogenation
ACS Catal. 2015, 5, 1254−1265[article]
16.Potier, J.; Guerriero,A.; Menuel, S.; Monflier, E.; Peruzzini, M.; Hapiot, F.; Gonsalvi, L.
Cyclodextrins as first and second sphere ligands for Rh(I) complexes of lower-rim PTA derivatives for use as catalysts in aqueous phase hydrogenation
Catal. Commun.2015, 63, 74-78 [article]
17.Talavera,M.; Bravo, J.; Gonsalvi, L.; Peruzzini,M.; Zuccaccia, C.; Bolaño, S.
[IrCp*(NCMe)2(PPh2Me)][PF6]2 as Catalyst for the Meyer–Schuster Rearrangement of Aryl Propargylic Alcohols under Mild Conditions
Eur. J. Inorg. Chem. 2014, 6268–6274[article]
18.Guerriero, A.; Bricout, H.; Sordakis, K.; Peruzzini, M.; Monflier, E. Hapiot, F.; Laurenczy, G.; Gonsalvi, L.
Hydrogen Production by Selective Dehydrogenation of HCOOH Catalyzed by Ru-biaryl Sulfonated Phosphines in Aqueous Solution
ACS Catal.2014, 4, 3002-3012 [article].
19.Caporali, M.; Gonsalvi, L.; Mirabello, V.; Ienco, A.; Manca, G.; Zanobini, F.; Peruzzini, M.
The bimetallic activation of white phosphorus by trans-[RhCl(CO)(dppm)]2 results in a tetrahedro-Rh2P2 moiety
Eur. J.Inorg. Chem. 2014, 1652–1659[article]
20.Kalsin, A.M.; Peganova, T. A.; Novikov, V. V.; Zhamoityna, A. I.; Gonsalvi, L.; Peruzzini, M.
Transfer hydrogenation of ketones catalyzed by surface active ruthenium and rhodium complexes in water
Chem. Eur. J.2014, 20, 846 – 854 [article]
21.Tristany, M.; Laurent, R.; Dib, H.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.
Bifunctional metallodendrimers based on AB5 derivatives of cyclotriphosphazene as core and P,N ligands as terminal functions
Inorg. Chim. Acta 2014, 409,121–126 [article]
22.Manca, G.; Mellone, I.; Bertini, F.; Rosi, L.; Peruzzini, M.; Mellman, D.; Junge, H.; Beller, M.; Ienco, A.; Gonsalvi, L.
Inner vs Outer-sphere Ru-catalyzed Formic Acid Dehydrogenation: A Computational Study
Organometallics 2013, 32, 7053−7064[article]
23.Mirabello, V.; Caporali, M.; Gonsalvi, L.; Manca, G.; Ienco, A.; Peruzzini, M.
Stabilization of the triphosphallyl ligand 3-P3{P(O)H} at iridium via alkaline activation of P4
Chem. Asian J. 20138, 3177-3184 [article]
24.Caporali, M.; Guerriero, A.; Ienco, A.; Caporali, S.; Peruzzini, M.; Gonsalvi, L.
Water-soluble palladium nanoparticles stabilized by PTA and their application in biphasic catalytic hydrogenations at room temperature
Chem. Cat. Chem. 2013, 5, 2517-2526[article]
25.Gonsalvi, L.; Guerriero, A.; Hapiot, F.; Krogstad, D. A.; Monflier, E.; Reginato, G.; Peruzzini, M.
Lower and Upper Rim-Modified PTA Derivatives: Coordination Chemistry and Applications in Catalytic Reactions in Water
Pure Appl. Chem.2013, 85, 385–396 [article]
26.Mellone, I.; Peruzzini, M.; Rosi, L.; Mellman, D.; Junge, H.; Beller, M.; Gonsalvi, L.
Formic Acid Dehydrogenation Catalysed by Ruthenium Complexes bearing the Tripodal Ligands Triphos and NP3
Dalton Trans. 2013, 42, 2495-2501[article]
27.Alidori, S.; Heift, D.; Santiso-Quinones, G.; Benkö, Z.; Grützmacher, H.; Caporali,M.; Gonsalvi,L.; Rossin, A.; Peruzzini, M.
Synthesis and Characterisation of terminal [Re(XCO)(CO)2(triphos)] (X = N, P):Isocyanate versus Phosphaethynolate Complexes
Chem. Eur. J. 2012, 18, 14805 – 14811[article]
28.Barbaro, P.; Gonsalvi, L.;Guerriero, A.; Liguori, F.
Facile heterogeneous catalytic hydrogenations of C=N and C=O bonds in neat water: anchoring of water-soluble metal complexes onto ion-exchange resins
Green Chem.2012, 14, 3211 - 3219[article]
29.Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Gudat, D.; Frey, W.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M.
Solution and Solid State Dynamics of Metal-Coordinated White Phosphorus
Chem. Eur. J. 2012, 18, 11238–11250 [article] (issue 36 cover article)
30.Gonsalvi, L.; Peruzzini, M.
Novel Synthetic Pathways for Bis(acyl)phosphine Oxide Photoinitiators
Angew. Chem. Int. Ed.(Highlights) 2012, 51, 7895 – 7897[article]
31.Servin, P.; Laurent, R.; Dib, H.; Gonsalvi, L.; Peruzzini, M.; Majoral,J.-P.; Caminade, A.-M.
Number of terminal groups versus generation of the dendrimer, which criteria influence the catalytic properties?
Tetrahedron Lett.2012,53, 3876–3879 [article]
32.Caporali, M.; Gonsalvi, L.; Kagirov, R.; Mirabello, V.; Peruzzini, M.; Sinyashin, O.; Stoppioni, P.; Yakhvarov, D.
The first water-soluble tetraphosphorus ruthenium complex. Synthesis, characterization and kinetic study of its hydrolysis
J. Organomet.Chem. 2012, 714, 67-73 [article]
33.Coletti, C.; Gonsalvi, L.; Guerriero, A.; Marvelli, L.; Peruzzini, M.; Reginato, G., Re, N.
Electron-Poor Rhenium Allenylidenes and Their Reactivity toward Phosphines: A Combined Experimental and Theoretical Study
Organometallics 2012, 31, 57-69 [article]
34.Krogstad, D. A.; Guerriero, A.; Ienco, A.; Manca, G.; Peruzzini, M.; Reginato, G.; Gonsalvi, L.
Imidazolyl PTA Derivatives as Water Soluble (P,N) Ligands for Ru-catalysed Hydrogenations
Organometallics 2011, 30, 6292–6302 [article]
35.Mirabello, V.; Caporali, M.; Gallo, V.; Gonsalvi, L.; Ienco, A.; Latronico, M.; Mastrorilli, P.; Peruzzini, M.
Dynamic Behaviour of Ru and Ru-Pt complexes containing tetrahedron-P4 Ligand
Dalton Trans 2011, 40, 9668–9671[article]
36.Six, N.; Guerriero, A.; Landy, D.; Peruzzini, M.; Gonsalvi, L.; Hapiot, F.; Monflier, E.
Supramolecularly controlled surface activity of an amphiphilic ligand. Application to biphasic hydroformylation of higher olefins
Catal. Sci. Technol. 2011, 1, 1347-1353 [article] (issue 8 cover article)
37.Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A.
Design And Synthesis Of Thiazole And Thiazolidine Metallosupramolecular Networks
Phosphorus Sulfur Sil. Rel. El. 2011,186, 1312-1315 [article]
38.Yakhvarov, D.; Caporali, M.; Gonsalvi, L.; Latypov, S.; Mirabello, V.; Rizvanov, I.; Sinyashin, O.; Stoppioni, P.; Peruzzini, M.
Experimental evidence of phosphine oxide generation in solution and its trapping by ruthenium complexes
Angew. Chem. Int. Ed. 2011, 50, 5370–5373[article]
39.Guerriero, A.; Erlandsson, M.; Ienco, A.; Krogstad, D. A.; Peruzzini, M.; Reginato, G.; Gonsalvi, L.
Iridium(I) Complexes of Upper Rim Functionalized PTA Derivatives. Synthesis, Characterization and Usein Catalytic Hydrogenations (PTA = 1,3,5-triaza-7-phosphaadamantane)
Organometallics 2011, 30, 1874–1884[article]
40.Levina, V. A.; Rossin, A.; Belkova, N. V.; Chierotti, M.; Epstein, L. M.; Filippov, O. A.; Gobetto, R.; Gonsalvi, L.; Lledos, A.; Shubina, E. S.; Zanobini, F.; Peruzzini, M.
Acid–Base Interaction between Transition-Metal Hydrides: Dihydrogen Bonding and Dihydrogen Evolution
Angew. Chem. Int. Ed. 2011, 50, 1367–1370 [article]
41.Rossin, A.; Di Credico, B.; Giambastiani, G.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.
Coordination Chemistry of Thiazole-Based Ligands: New Complexes Generating 3D Hydrogen-Bonded Architectures
Eur. J. Inorg. Chem. 2011, 539-548 [article]
42.Reginato, G.; Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Rossin, A.
Selective Synthesis of 2-Substituted 4-Carboxy Oxazoles, Thiazoles and Thiazolidines from Serine or Cysteine Amino Acids
Tetrahedron 2011, 67, 267-274[article]
43.Coletti, C.; Gonsalvi, L.; Guerriero, A.; Marvelli, L.; Peruzzini, M.; Reginato, G., Re, N.
Reactivity of Rhenium Allenylidenes towards phosphines: a theoretical study
Organometallics 2010, 29, 5982–5993[article]
44.Kovacs, G.; Rossin,A.; Gonsalvi,L.; Lledos, A.; Peruzzini, M.
Comparative DFT analysis of ligand and solvent effects on the mechanism of H2 activation in water mediated by half-sandwich complexes [Cp’Ru(PTA)2Cl](Cp’ = C5H5, C5Me5; PTA = 1,3,5-triaza-7-phosphaadamantane)
Organometallics 2010, 29, 5121–5131[article]
45.Casini, A.; Edafe, F.; Erlandsson, M.; Gonsalvi, L.; Marrone, A.; Ciancetta, A.; Re, N.; Ienco, A.; Messori, L.; Peruzzini,M.; Dyson, P. J.
Rationalization of the inhibition activity of structurally related organometallic compounds against drug target cathepsin B by DFT analysis
Dalton Trans. 2010, 39, 5556–5563 [article] - selected as Hot Article May 2010
46.Rossin,A.; Gutsul,E. I.; Belkova,N. V.; Epstein,L. M.; Gonsalvi,L.; Lledós,A.; Lyssenko, K. A.; Peruzzini,M.; Shubina, E. S.; Zanobini, F.
Mechanistic study of the protonation of [(k3-P,P,P-NP3)Ir(H)3] [NP3 = N(CH2CH2PPh2)3] by HBF4 and fluorinated alcohols through combined NMR, IR and DFT techniques
Inorg. Chem. 2010, 49, 4343 - 4354[article]
47.Caporali, M.; Gonsalvi, L.; Rossin, A.; Peruzzini, M.
P4 activation by Late Transition Metal Complexes
Chem. Rev. 2010, 110, 4178–4235[article]
48.Ciancaleoni, G.; Bolaño, S.; Bravo, J.; Peruzzini, M.; Gonsalvi, L.; Macchioni, A.
Counterion-dependent deuteration of pentamethylcyclopentadiene in water-soluble cationic Rh(III) complexes assisted by PTA
Dalton Trans. 2010, 39, 3366 - 3368[article]
49.Bolaño, S.; Plaza, M.; Bravo, J.; Castro, J.; Peruzzini, M.; Gonsalvi, L.; Ciancaleoni, G.; Macchioni, A.
New Highly Water-Soluble Rhodium Complexes Bearing 1,3,5-Triaza-7-phosphaadamantane (PTA) and/or Tris(hydroxymethyl) phosphine (THP)
Inorg. Chim. Acta 2010, 363,509–516[article]
50.Bravo, J.; Bolaño, S.; Gonsalvi, L.; Peruzzini, M.
Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for tailored ligands, complexes and related applications.
Coord. Chem. Rev. 2010, 254, 555–607[article]
51.Di Credico, B.; Fabrizi de Biani, F.; Gonsalvi, L.; Guerri, A.; Ienco, A.; Laschi, F.; Reginato, G.; Rossin, A.; Zanello, P.; Peruzzini, M.
Cyclopentadienyl Ruthenium(II) Complexes with Bridging Alkynylphosphine Ligands.
Chem. Eur. J. 2009, 15, 11985 – 11998[article]
52.Rossin,A.; Caporali, M.; Gonsalvi, L.; Guerri, A.; Lledos,A.; Peruzzini, M.; Zanobini, F.
Selective B-H vs. N-H bond activation in ammoniaborane by [Ir(dppm)2][OTf]
Eur. J. Inorg. Chem.,2009, 3055-3059 [article]
53.Servin, P.; Laurent, R.; Gonsalvi, L.; Tristany, M.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.
Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in aqueous media
Dalton Trans. 2009,4432 - 4434 [article]
54.Legrand, F.-X.; Hapiot, F.; Tilloy, S.; Guerriero, A.; Peruzzini, M.; Gonsalvi, L.; Monflier, E.
Aqueous rhodium-catalyzed hydroformylation of1-decene in the presence of randomly methylated-cyclodextrin and 1,3,5-triaza-7-phosphaadamantanederivatives
Appl. Catal. A: Gen. 2009, 362, 62-66 [article]
55.Renfrew, A. K.; Phillips, A. D.; Egger, A.; Hartinger, C. G.; Bosquain, S. S.; Nazarov, A. A.; Keppler, B. K.; Gonsalvi, L.; Peruzzini, M.; Dyson, P. J.
Influence of structural variation on the anticancer activity of RAPTA-type complexes: ptn versus pta
Organometallics 2009, 28, 1165–1172[article]
56.Caporali, M.; Barbaro, P.; Bolaño, S.;Gonsalvi, L.; Mañas Carpio, S.; Peruzzini, M.
NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP){Pt(PPh3)2}]OTf (M = Rh, Ir) derived from the stepwise activation of white phosphorus