Chemistry 121H Professor Knapp

University of Massachusetts Amherst -- Fall, 2002

Chemistry 121 H – Section 3

Tue Thu 2:30- 3:45 LGRT 201

Course Information and Syllabus

Administration

Course Description: With lab. Basic principles of structure and reactivity. Microscopic nature of atoms and molecules; the macroscopic properties of chemical systems. Topics include stoichiometry, thermochemistry, atomic structure, molecular structure, properties of gases. Prerequisite: secondary school chemistry; concurrent enrollment in MATH 135. Open to chemistry majors and Commonwealth College students. Biochemistry and chemical engineering majors and others: by permission of instructor.

Required Text & CD: Chemistry and Chemical Reactivity by Kotz & Treichel, 5th Ed., Thomson/Brooks-Cole Publishing, 2002. 997 pages. (Textbook Annex)

Instructor:

Chemistry 121H Professor Knapp

Michael J. Knapp, Ph.D.

Tel: (413) 545-4001

Assistant Professor of Chemistry

E-mail:

Office: 512 Lederle Grad. Research Tower

Web: http://www.chem.umass.edu/~mknapp

Mailing Address:

Michael J. Knapp

Department of Chemistry-LGRT

710 North Pleasant Street

University of Massachusetts

Amherst, MA 01003

Chemistry 121H Professor Knapp

Class Schedule/Location: Tue Thu 2:30 PM – 3:45 PM LGRT 201

Office Hours: Mon, Wed 12:30 – 1:30 (512 LGRT)

Attendance Policy: Attendance at all lectures is expected. This is especially important since each lecture section of CHEM121H is independent, with its own schedule of topics and exams. You cannot miss a lecture and expect to make it up by attending another lecture section. Students are responsible for all material covered and assignments made during lectures. No grade reduction is made for missed classes.

Add/Drop: Except for Continuing Education students, all add, drop and section changes, until the Add/Drop deadline are done using the telephone course registration system. After the Add/Drop period ends, all add, drop and section changes are done by Ms. Linda Warren in Goessmann 149C. Any change in lecture section must be done before the first exam, on October 3.

Academic Honesty: See regulation on "Academic Honesty" in the "Undergraduate Rights & Responsibilities" Student Handbook. The bottom line is that dishonesty is NOT tolerated.

Copyright: Most of the materials created for this course are the intellectual property of the instructor. This includes, but is not limited to, the syllabus, lectures, handouts and class notes. Except to the extent not protected by copyright law, any use, distribution or sale of such materials requires the written permission of the instructor. Please be aware that it is a violation of University policy to reproduce, for distribution or sale, class lectures or class notes, unless copyright has been explicitly waived in writing by the instructor.

Laboratory

Laboratory begins the week of September 8. Lab procedures and data sheets can be obtained from the Web – go to http://www.chem.umass.edu/genchem and follow the appropriate links. Students must complete all laboratory experiments to pass the laboratory component of the course. If you fail either the lecture or the laboratory component of, you will be required to repeat the entire course. There are no “lab waivers”.

Required Materials: (needed by first lab Monday September 9th)

1. Safety Glasses (American Optical Co. # 484A)

2. Masterlock #1525

3. Calculator (preferably one that can handle logarithms)

4. Lab Notebook – Student Lab Notebook by Hayden-McNeil

The above items are available at the University Store, or at the Textbook Annex.

Learning Resources

The Chemistry Resource Center (CRC) is located in 151 Goessmann and is open 9 AM – 12 PM Mondays through Thursdays, 10 AM- 4:30 PM Friday, and 5 PM to 12 PM Sunday. The CRC is staffed with a chemistry graduate student and an undergraduate who is familiar with the computers and other resources available. During weekday afternoons, from 1 PM to 5 PM, there will also be a general chemistry professor in the CRC. The CRC is the best place to do chemistry OWL homework and get chemistry-related questions answered. Help is also available at Learning Support Services, 1020 W.E.B. DuBois Library.

Office Hours: Mon, Wed 12:30 – 1:30 (512 LGRT)

Important web addresses:

http://www.chem.umass.edu/~mknapp. The web site for this class. Follow appropriate links. The site contains a copy of this syllabus, homework assignments and solutions, copies of old exams and answers/solutions, handouts, examinations, and other important class information. Check this class web site often as new and updated materials are added frequently.

http://www.chem.umass.edu/genchem. The General Chemistry web page. Has links to the Online Web-based homework & Learning system (OWL) and to the chemistry department CHEM121H course web site. This site has links to the laboratory schedule, OWL login, old exam questions sorted by topic, and our section’s class web site.

Lecture Handouts/Supplements: Most handouts will be available prior to class from the course web site. Chemland Chemistry software for Windows PCs is available free from

http://soulcatcher.chem.umass.edu under “downloads.”

Homework

Textbook homework is neither collected nor graded. However, it is of great importance in learning chemical concepts and principles. Assignments will be made at the beginning of each class. Solutions are posted on the course web site.

Online Web-based Learning (OWL) (http://owl.oit.umass.edu/owlc/user/loginpage.cgi?UserType=Student&Server=owl-chemistry))

OWL is a computer delivered homework system covering the topics in this course. Students can access OWL from the CRC or any computer with Internet access. All students should log on to OWL as soon as possible to check that they have access to the system. Your user name is your 9 digit student number and your password is your last name. The first OWL assignment is due Sunday, September 8th at midnight. OWL assignments are computer graded and, in total, comprise 10% of the final course grade. Assignments may be re-taken until successfully passed (only your highest grade will be retained). If you experience any problems logging on or completing assignments, notify the instructor by e-mail ASAP. The first few assignment due dates are shown below, others will follow each week during the semester. A few "Discovery" modules may also be assigned.

Name of assignment Chapter/Unit Due date

Intro to OWL (tutorial) 0-1a,b,c; 0-2a,b September 8

Unit Analysis 1-1c; 1-2b; 1-4c September 11

Examinations:

Exam #1: Thursday, October 3

Exam #2: Thursday, October 31 {Last date to drop with "W" is Monday, Oct. 29}

Exam #3: Tuesday, December 5.

Final Examination: TBA

There are no early Final Examinations. The actual date (and time, location, etc.) of the

Final Examination will be announced as soon as it is made available to instructors.

Grading: There will be three (3) 90 minute examinations (100 points each) and one (1) cumulative final examination (100 points). The laboratory is valued at 100 points and the OWL homework at 50 points. Students must independently pass both the laboratory and examination portions of the course to pass the course. Hour exams will be held during class time on the dates shown on the lecture/exam schedule (see above). The maximum point total for the entire course is 550 points. If the final exam grade is higher than any one of the hour exams, the lowest hour exam grade will be dropped and the final exam grade doubled. Final course grades are earned as below. These are the minimum point totals needed to guarantee the grades shown. Grade adjustments on exams or final course grades are at the instructor’s discretion.

495-550 = A 479-494 = AB 440-478 = B 424-439 = BC

385-423 = C 369-384 = CD 330-368 = D < 330 = F

Make-Up Policy: No make-up exams will be given without notification of absence prior to exam time, and written documentation of mandated absence from an exam due to legal, medical, military or other extraordinary University-related reason. This policy is strictly enforced. Make-up exams may or may not have the same format, number of questions, and grading scheme as the regularly scheduled exam. Make-up exams for the final are governed by University policy.

Schedule

The lecture schedule details the sequence of topics. Although the actual rate of coverage may vary slightly from that projected, the exams will be given on the dates shown. The material tested on any exam will be that covered since the beginning of the semester or previous exam. The final exam is cumulative, covering the entire semester.

Week # Dates Chapters Topics

1 Sept. 5 1 Matter and Measurement

2 10 12 2, 23 Atoms, Nuclear Chemistry

3 17 19 3 Molecules, Ions, Compounds

4 24 26 4, 5 Chemical Reactions

5 Oct. 1 3 Exam Oct. 3

6 8 10 6 Energy and Chemical Reactions

7 15 17 7 Atomic Structure

8 22 24 8 Electron Configuration, Periodicity

9 29 31 Exam Oct 31

10 Nov. 5 7 9 Bonding and Molecular Structure

11 12 14 10 Orbital Hybridization and MOs

12 19 21 11 Organic Chemistry

13 26 28 12 Gases

14 Dec. 3 5 Exam Dec 5

15 10 12 Review and Extra Topics

Class does not meet on the date in italics.

The Fall 2002 final exam schedule will be available in October.