Supplementary Materials
Table of calculated structure factors squared, and observed structure factors squared with esds
for
Preparation and Structural Study of Fully dehydrated,
Highly Mg2+-exchanged Zeolite Y (FAU, Si/Al = 1.56)
from Undried Methanol Solution
by
Hu Sik Kim,a Sang June Choi,b and Woo Taik Lima*
aDepartment of Applied Chemistry, Andong National University, Andong 760-749, Korea
bDepartment of Environmental Engineering, Kyungpook National University, Daegu 702-701, Korea
|Mg34.5Na6|[Si117Al75O384]-FAU
1 / 1 / 1 / 2723678 / 429589.1 / 15886.58 / 8 / 8 / 8 / 368354.6 / 409218.5 / 5591.01
0 / 2 / 2 / 530222.1 / 591566.3 / 11392.22 / 1 / 1 / 9 / 2369.62 / 4304.04 / 72.22
2 / 2 / 2 / 7081.73 / 5042.62 / 117.73 / 1 / 3 / 9 / 114679.6 / 93036.8 / 1150.77
1 / 1 / 3 / 473826.2 / 578895.1 / 5183.24 / 3 / 3 / 9 / 1488.68 / 2312.96 / 57.7
1 / 3 / 3 / 534238.5 / 627557 / 4706.56 / 1 / 5 / 9 / 61.54 / 159.75 / 33.95
3 / 3 / 3 / 110100.2 / 88724.72 / 1286.2 / 3 / 5 / 9 / 4327.59 / 7491.16 / 71.6
0 / 0 / 4 / 66731.95 / 46110.13 / 514.88 / 5 / 5 / 9 / 135328.1 / 116804.7 / 893.57
2 / 2 / 4 / 330.32 / 523.67 / 28.83 / 1 / 7 / 9 / 140496.6 / 135481 / 750.79
0 / 4 / 4 / 266948.3 / 262433.5 / 2079.5 / 3 / 7 / 9 / 3055.69 / 1849.82 / 39.04
2 / 4 / 4 / 6731.77 / 4707.96 / 68.02 / 5 / 7 / 9 / 17044.66 / 13745.08 / 101.58
4 / 4 / 4 / 6403.43 / 4761.23 / 145.46 / 7 / 7 / 9 / 88886.84 / 82488.85 / 714.12
1 / 1 / 5 / 75695.19 / 63484.95 / 484.24 / 1 / 9 / 9 / 1072.16 / 3892.26 / 76.88
1 / 3 / 5 / 46022.04 / 37871.6 / 313.86 / 3 / 9 / 9 / 26728.11 / 23577.32 / 210.99
3 / 3 / 5 / 446441.1 / 501315.2 / 3718.7 / 5 / 9 / 9 / 132005.9 / 131767.9 / 961.58
1 / 5 / 5 / 3593.66 / 2379.65 / 67.58 / 7 / 9 / 9 / 815.99 / 1311.44 / 91.27
3 / 5 / 5 / 3050.07 / 2806.06 / 57.86 / 9 / 9 / 9 / 3299.56 / 8382.54 / 274.29
0 / 2 / 6 / 52917.8 / 43421.75 / 243.43 / 0 / 2 / 10 / 98.6 / 188.21 / 64.82
2 / 2 / 6 / 115.43 / 566.61 / 48.02 / 2 / 2 / 10 / 60868.28 / 65224.93 / 504.59
2 / 4 / 6 / 378491.8 / 437712.7 / 2652.78 / 2 / 4 / 10 / 7334.14 / 7884.39 / 70.03
4 / 4 / 6 / 0.79 / 86.42 / 28.81 / 4 / 4 / 10 / 42221.54 / 38775.13 / 329.28
0 / 6 / 6 / 464186.4 / 511940.6 / 4007.96 / 0 / 6 / 10 / 45606.3 / 37018.95 / 217.46
2 / 6 / 6 / 5237.31 / 4179.65 / 62.82 / 2 / 6 / 10 / 10876.23 / 7493.61 / 72
4 / 6 / 6 / 640226.3 / 737655.7 / 5600.55 / 4 / 6 / 10 / 1789.72 / 812.2 / 35.58
6 / 6 / 6 / 1058258 / 1785566 / 22803.21 / 6 / 6 / 10 / 3417.85 / 2782.78 / 57.77
1 / 1 / 7 / 472.13 / 1052.14 / 52.85 / 2 / 8 / 10 / 126971.8 / 114019.2 / 628.04
1 / 3 / 7 / 13502.21 / 9682.18 / 77.76 / 4 / 8 / 10 / 1097.47 / 847.58 / 60.06
3 / 3 / 7 / 96902.5 / 96952.79 / 785.52 / 6 / 8 / 10 / 2160.72 / 3961.35 / 88.96
1 / 5 / 7 / 35502.14 / 27184.08 / 185.73 / 8 / 8 / 10 / 1086.02 / 605.39 / 91.29
3 / 5 / 7 / 93806.56 / 82662.06 / 444.76 / 0 / 10 / 10 / 545272.1 / 686690.5 / 5378.88
5 / 5 / 7 / 106699.9 / 71208.05 / 559.64 / 2 / 10 / 10 / 2317.12 / 1942.99 / 67.33
1 / 7 / 7 / 72740.97 / 63352.76 / 516.74 / 4 / 10 / 10 / 53123.91 / 50274.34 / 394.02
3 / 7 / 7 / 154.34 / 139.25 / 33.61 / 6 / 10 / 10 / 20305.79 / 23619.93 / 238.63
5 / 7 / 7 / 149803.6 / 152228.4 / 1206.73 / 8 / 10 / 10 / 159939.4 / 156661.4 / 1313.41
7 / 7 / 7 / 217363.4 / 244608.3 / 3306.21 / 10 / 10 / 10 / 22202.3 / 25267.17 / 530.66
0 / 0 / 8 / 55830.54 / 49025.05 / 566.53 / 1 / 1 / 11 / 251785 / 216158.2 / 1531.29
2 / 2 / 8 / 196002.1 / 177361.6 / 1246.38 / 1 / 3 / 11 / 35161.1 / 29286.52 / 337.19
0 / 4 / 8 / 278609.8 / 269111.3 / 1321.97 / 3 / 3 / 11 / 113998.6 / 130883.3 / 961.33
2 / 4 / 8 / 25916.11 / 19393.79 / 178.04 / 1 / 5 / 11 / 51623.82 / 45150.39 / 260.81
4 / 4 / 8 / 71568.41 / 57390.18 / 490.87 / 3 / 5 / 11 / 547.3 / 1045.36 / 38.95
2 / 6 / 8 / 9257.22 / 4215.37 / 51.42 / 5 / 5 / 11 / 69128.57 / 59658.28 / 501.97
4 / 6 / 8 / 53242.95 / 46608.44 / 266.12 / 1 / 7 / 11 / 45395.59 / 42776.81 / 268.89
6 / 6 / 8 / 377.4 / 638.74 / 76.84 / 3 / 7 / 11 / 14399.93 / 14126.36 / 126.28
0 / 8 / 8 / 269336.1 / 335306.1 / 2620.09 / 5 / 7 / 11 / 24529.84 / 22283.76 / 232.38
2 / 8 / 8 / 135458.5 / 129413 / 952.52 / 7 / 7 / 11 / 32522.68 / 28169.21 / 275.25
4 / 8 / 8 / 123777.1 / 110777.8 / 802.24 / 1 / 9 / 11 / 463.81 / 532.34 / 42.35
6 / 8 / 8 / 246.13 / 1819.91 / 86.43 / 3 / 9 / 11 / 252734.1 / 269543.3 / 1345.77
h / k / l / Fcal^2 / Fobs^2 / (Fobs^2) / h / k / l / Fcal^2 / Fobs^2 / (Fobs^2)
5 / 9 / 11 / 681.53 / 1905.29 / 84.06 / 9 / 9 / 13 / 58511.7 / 61558.03 / 611.21
7 / 9 / 11 / 70941.75 / 69108.65 / 448.27 / 1 / 11 / 13 / 31864.95 / 29178.97 / 199.16
9 / 9 / 11 / 118815.1 / 114747.7 / 1006.51 / 3 / 11 / 13 / 49778.45 / 45955.63 / 276.59
1 / 11 / 11 / 682254.8 / 838517.8 / 5878.01 / 5 / 11 / 13 / 14100.63 / 13802.64 / 111.26
3 / 11 / 11 / 4381.72 / 4959.91 / 86.68 / 7 / 11 / 13 / 9219.72 / 8672.81 / 102.24
5 / 11 / 11 / 151362.7 / 148438.1 / 1064.19 / 9 / 11 / 13 / 10387.91 / 7958.03 / 169.04
7 / 11 / 11 / 6133.29 / 7923.91 / 149.42 / 11 / 11 / 13 / 39833.59 / 39584.97 / 461.09
9 / 11 / 11 / 30534.22 / 28310.66 / 332.55 / 1 / 13 / 13 / 71987.38 / 69763.12 / 580.57
11 / 11 / 11 / 1614189 / 2442973 / 32465.21 / 3 / 13 / 13 / 127250.4 / 123429.3 / 922.27
0 / 0 / 12 / 706689.2 / 756790.8 / 7180.8 / 5 / 13 / 13 / 3688.86 / 4830.44 / 96.22
2 / 2 / 12 / 2095.51 / 3900.7 / 76.96 / 7 / 13 / 13 / 3837.74 / 3468.95 / 101.04
0 / 4 / 12 / 12468.25 / 9933.22 / 87.34 / 9 / 13 / 13 / 51572.34 / 51470.31 / 552.65
2 / 4 / 12 / 74761.65 / 72430.79 / 502.1 / 11 / 13 / 13 / 17307.21 / 17565.23 / 256.74
4 / 4 / 12 / 97893.77 / 79525.29 / 620.81 / 13 / 13 / 13 / 72633.34 / 78945.94 / 1287.92
2 / 6 / 12 / 33960.66 / 27083.69 / 174.32 / 0 / 2 / 14 / 160960.2 / 153518.3 / 785.38
4 / 6 / 12 / 1889.02 / 1518.3 / 42.39 / 2 / 2 / 14 / 1855.44 / 1918.27 / 72.12
6 / 6 / 12 / 39964.57 / 33140.72 / 301.46 / 2 / 4 / 14 / 6674.49 / 5408.89 / 123.03
0 / 8 / 12 / 123996.2 / 125737.3 / 651.33 / 4 / 4 / 14 / 358.14 / 427.39 / 62.43
2 / 8 / 12 / 5204.63 / 6513.97 / 76.62 / 0 / 6 / 14 / 927.5 / 1141.58 / 47.56
4 / 8 / 12 / 15991.94 / 16197.38 / 191.84 / 2 / 6 / 14 / 197189.7 / 198322.8 / 2652.75
6 / 8 / 12 / 27459.11 / 25281.27 / 167.77 / 4 / 6 / 14 / 66867.6 / 58352.9 / 341.37
8 / 8 / 12 / 271969.4 / 288790.5 / 2365.85 / 6 / 6 / 14 / 63661.24 / 61239.52 / 515.25
2 / 10 / 12 / 3384.64 / 4505.88 / 96.24 / 2 / 8 / 14 / 2051.18 / 2249.94 / 54.39
4 / 10 / 12 / 278.43 / 861.98 / 44.14 / 4 / 8 / 14 / 6550.63 / 5393.86 / 71.6
6 / 10 / 12 / 152215.3 / 149032.3 / 803.4 / 6 / 8 / 14 / 161284.8 / 166751 / 915.42
8 / 10 / 12 / 2216.83 / 3269.32 / 79.83 / 8 / 8 / 14 / 306.04 / 499.38 / 43.22
10 / 10 / 12 / 274762.4 / 283933.1 / 2385.43 / 0 / 10 / 14 / 112312.7 / 99364.23 / 526.52
0 / 12 / 12 / 1516907 / 2294321 / 18480.35 / 2 / 10 / 14 / 3.21 / 72.55 / 50.41
2 / 12 / 12 / 25501.54 / 21161.87 / 209.81 / 4 / 10 / 14 / 810.24 / 879.24 / 50.95
4 / 12 / 12 / 14195.99 / 11397.71 / 140.47 / 6 / 10 / 14 / 703.41 / 1385.64 / 57.63
6 / 12 / 12 / 16529.46 / 16473.69 / 184.28 / 8 / 10 / 14 / 56854.13 / 53474.17 / 380.39
8 / 12 / 12 / 18769.94 / 15678.27 / 213.57 / 10 / 10 / 14 / 4972.66 / 3663.63 / 134.8
10 / 12 / 12 / 51937.84 / 47597.43 / 508.83 / 2 / 12 / 14 / 94954.86 / 90535.47 / 797.97
12 / 12 / 12 / 253762.6 / 259380.6 / 3781.75 / 4 / 12 / 14 / 3444.81 / 3550.64 / 64.63
1 / 1 / 13 / 271.62 / 456.19 / 57.62 / 6 / 12 / 14 / 2477.35 / 2127.41 / 47.59
1 / 3 / 13 / 15393.58 / 13063.85 / 99.68 / 8 / 12 / 14 / 30278.05 / 27167.34 / 232.95
3 / 3 / 13 / 82081.69 / 73908.13 / 571.9 / 10 / 12 / 14 / 46703.98 / 44935.57 / 354.34
1 / 5 / 13 / 18949.72 / 15921.11 / 117.12 / 12 / 12 / 14 / 7629.3 / 7542.64 / 173.5
3 / 5 / 13 / 940.77 / 944.11 / 44.16 / 0 / 14 / 14 / 5496.8 / 6708.29 / 125.21
5 / 5 / 13 / 50059.13 / 46638.32 / 388.11 / 2 / 14 / 14 / 33414.14 / 32548.05 / 308.07
1 / 7 / 13 / 20599.69 / 19760.09 / 137.85 / 4 / 14 / 14 / 43830.87 / 37891.98 / 349.03
3 / 7 / 13 / 140098.1 / 125276.9 / 1343.39 / 6 / 14 / 14 / 159087.8 / 154633.6 / 1133.15
5 / 7 / 13 / 78631.37 / 77782.47 / 500.95 / 8 / 14 / 14 / 42.01 / 374.48 / 105.62
7 / 7 / 13 / 9209.41 / 7955.98 / 115.93 / 10 / 14 / 14 / 1548.41 / 1330.89 / 115.31
1 / 9 / 13 / 63405.03 / 60525.42 / 338.16 / 12 / 14 / 14 / 86036.18 / 90019.2 / 894.79
3 / 9 / 13 / 33721.35 / 28719.98 / 247.97 / 14 / 14 / 14 / 70328.23 / 77902.46 / 1462.28
5 / 9 / 13 / 61807.59 / 56246.25 / 432.01 / 1 / 1 / 15 / 14098.69 / 12624.37 / 150.35
7 / 9 / 13 / 12870.78 / 12568.82 / 123.43 / 1 / 3 / 15 / 13910 / 13675.52 / 109.71
9 / 9 / 13 / 119573.7 / 120423.1 / 540.45 / 3 / 3 / 15 / 20896.29 / 26473.95 / 124.65
h / k / l / Fcal^2 / Fobs^2 / (Fobs^2) / h / k / l / Fcal^2 / Fobs^2 / (Fobs^2)
3 / 3 / 15 / 80174.16 / 80955.23 / 628.07 / 4 / 10 / 16 / 18870.94 / 18709.96 / 218.38
1 / 5 / 15 / 19689.27 / 20163.34 / 144.51 / 6 / 10 / 16 / 7138.48 / 8442.48 / 92.03
3 / 5 / 15 / 104000 / 99222.63 / 531.53 / 8 / 10 / 16 / 3526.72 / 3310.91 / 69.75
5 / 5 / 15 / 35854.75 / 32683.15 / 294.84 / 10 / 10 / 16 / 41715.38 / 39117.99 / 465.98
1 / 7 / 15 / 7214.61 / 7632.2 / 82.01 / 0 / 12 / 16 / 15774.75 / 14494.9 / 121.53
3 / 7 / 15 / 18140.71 / 14125.48 / 245.31 / 2 / 12 / 16 / 80.85 / 260.68 / 50.92
5 / 7 / 15 / 2954.56 / 3528.08 / 61.22 / 4 / 12 / 16 / 17556.51 / 14878.14 / 133.66
7 / 7 / 15 / 20337.79 / 17877.65 / 204.15 / 6 / 12 / 16 / 10333.55 / 8580.83 / 88.75
1 / 9 / 15 / 25463.01 / 22443.53 / 287.77 / 8 / 12 / 16 / 20751.42 / 25567.03 / 444.01
3 / 9 / 15 / 2165.96 / 2264.76 / 57.79 / 10 / 12 / 16 / 2024.77 / 1923.76 / 84.95
5 / 9 / 15 / 81505.53 / 75670.59 / 451.67 / 12 / 12 / 16 / 50614.52 / 51875.12 / 560.6
7 / 9 / 15 / 36467.05 / 34245.65 / 228.82 / 2 / 14 / 16 / 20829.14 / 22271.21 / 174.71
9 / 9 / 15 / 395.76 / 667.47 / 67.23 / 4 / 14 / 16 / 5599.3 / 5882.34 / 76.55
1 / 11 / 15 / 41049.45 / 36238.73 / 243.39 / 6 / 14 / 16 / 16467.22 / 15870.25 / 135.18
3 / 11 / 15 / 44361.72 / 39899.45 / 546.67 / 8 / 14 / 16 / 2994.08 / 2954.94 / 117.8
5 / 11 / 15 / 11529.77 / 11922.68 / 109.19 / 10 / 14 / 16 / 10790.84 / 11452.75 / 148.41
7 / 11 / 15 / 90344.62 / 88699.85 / 526.97 / 12 / 14 / 16 / 1361.24 / 1550.31 / 139.31
9 / 11 / 15 / 10746.5 / 10368.19 / 166.59 / 14 / 14 / 16 / 63908.06 / 66398.52 / 681.31
11 / 11 / 15 / 174.29 / 1334.76 / 129.64 / 0 / 16 / 16 / 71689.45 / 75624.44 / 675.88
1 / 13 / 15 / 7312.31 / 7800.13 / 93.69 / 2 / 16 / 16 / 25366.66 / 24149.84 / 252.78
3 / 13 / 15 / 651.72 / 869.51 / 54.34 / 4 / 16 / 16 / 65620.04 / 70430.05 / 589.48
5 / 13 / 15 / 106240.6 / 100957.3 / 559.49 / 6 / 16 / 16 / 8948.45 / 8322.13 / 135.01
7 / 13 / 15 / 1249.84 / 2359.73 / 79.27 / 8 / 16 / 16 / 20284.62 / 22891.4 / 300.5
9 / 13 / 15 / 11949.17 / 10909.49 / 140.04 / 10 / 16 / 16 / 4638.25 / 4291.53 / 149.14
11 / 13 / 15 / 1036.19 / 1048.26 / 83.16 / 12 / 16 / 16 / 8846.97 / 8256.4 / 187.97
13 / 13 / 15 / 118.1 / 288.07 / 115.23 / 14 / 16 / 16 / 591.14 / 595.46 / 124.85
1 / 15 / 15 / 13496.26 / 11855.4 / 159.55 / 16 / 16 / 16 / 252045.6 / 291777.7 / 4115.87
3 / 15 / 15 / 33589.96 / 32219.51 / 297.97 / 1 / 1 / 17 / 208052.3 / 210384.6 / 1498.34
5 / 15 / 15 / 14474.67 / 16241.35 / 188.63 / 1 / 3 / 17 / 4466.12 / 4956.64 / 71.49
7 / 15 / 15 / 23784.74 / 22245.67 / 272.06 / 3 / 3 / 17 / 3334.21 / 2405.48 / 86.6
9 / 15 / 15 / 27477.42 / 29108.69 / 364.89 / 1 / 5 / 17 / 14151.94 / 12636.17 / 109.59
11 / 15 / 15 / 4825.72 / 4552.03 / 153.98 / 3 / 5 / 17 / 8308.83 / 8144.09 / 86.96
13 / 15 / 15 / 299.73 / 561.78 / 124.84 / 5 / 5 / 17 / 897850.6 / 1140529 / 7544.86
15 / 15 / 15 / 45781.44 / 50053.56 / 1047.99 / 1 / 7 / 17 / 2362.83 / 2365.74 / 61.19
0 / 0 / 16 / 336912.9 / 373667.2 / 3624.28 / 3 / 7 / 17 / 24811.34 / 23599.61 / 175.37
2 / 2 / 16 / 32064.47 / 27556.35 / 255.02 / 5 / 7 / 17 / 279407.4 / 293550.2 / 2159.1
0 / 4 / 16 / 62521.14 / 63574 / 717.15 / 7 / 7 / 17 / 35010.42 / 32739.33 / 313.3
2 / 4 / 16 / 1815.4 / 1685.5 / 57.78 / 1 / 9 / 17 / 9634.2 / 9836.88 / 100.66
4 / 4 / 16 / 2323.55 / 16684.16 / 201.94 / 3 / 9 / 17 / 173568.6 / 173439.2 / 908.61
2 / 6 / 16 / 23672.26 / 24091.06 / 263.16 / 5 / 9 / 17 / 13393.64 / 13062.1 / 116.29
4 / 6 / 16 / 263.39 / 479.02 / 91.23 / 7 / 9 / 17 / 56760.77 / 53787.84 / 349.85
6 / 6 / 16 / 1441001 / 2147982 / 14208.45 / 9 / 9 / 17 / 40666.88 / 38645.36 / 397.14
0 / 8 / 16 / 1243.67 / 1282.9 / 52.58 / 1 / 11 / 17 / 19680.13 / 17296.14 / 140.73
2 / 8 / 16 / 8817.95 / 8344.82 / 88.54 / 3 / 11 / 17 / 16338.85 / 16189.58 / 174.37
4 / 8 / 16 / 113786.2 / 106813.6 / 584.72 / 5 / 11 / 17 / 99837.3 / 93259.74 / 863.87
6 / 8 / 16 / 17298.51 / 17463.64 / 140.6 / 7 / 11 / 17 / 44765.11 / 47773.03 / 501.05
8 / 8 / 16 / 125134.1 / 121340.7 / 974.95 / 9 / 11 / 17 / 16985.5 / 16075.86 / 172.88
2 / 10 / 16 / 613.68 / 1419.82 / 60.84 / 11 / 11 / 17 / 31709.38 / 32253.47 / 375.38
4 / 10 / 16 / 16392.08 / 15227.43 / 93.37 / 1 / 13 / 17 / 28499.09 / 28489.8 / 810.31
h / k / l / Fcal^2 / Fobs^2 / (Fobs^2) / h / k / l / Fcal^2 / Fobs^2 / (Fobs^2)
1 / 13 / 17 / 38135.27 / 36209.95 / 242.26 / 0 / 14 / 18 / 2989.85 / 2681.22 / 71.39
3 / 13 / 17 / 951.82 / 2781.28 / 67.93 / 2 / 14 / 18 / 9161.83 / 8474.3 / 100.55
5 / 13 / 17 / 18423.76 / 17119.13 / 145.6 / 4 / 14 / 18 / 49125.82 / 52694.5 / 338.19
7 / 13 / 17 / 64.12 / 167.56 / 49.58 / 6 / 14 / 18 / 6801.49 / 5818.4 / 81.74
9 / 13 / 17 / 1220.28 / 1124.94 / 88.87 / 8 / 14 / 18 / 32313.95 / 37477.79 / 315.3
11 / 13 / 17 / 9523.68 / 9044.55 / 132.99 / 10 / 14 / 18 / 4490.45 / 4807.17 / 108.85
13 / 13 / 17 / 64724.33 / 66996.23 / 676.88 / 12 / 14 / 18 / 3373.2 / 3494.02 / 141.84