SDS Sheets Template
SDS Sheet
Page 1 of 13
Creation Date: 22.02.1996
Revision Date: 23.03.2012
Legal Disclaimer
The information and recommendations in this publication are, to the best of our knowledge, information and belief, accurate at the date of publication.
Nothing herein is to be construed as a warranty, express or implied. In all cases it is the responsibility of the users to determine the applicability of such information or the suitability of any products for their own particular purpose.
1.Identification of the Substance/Mixture and the Company Undertaking
Product Identifier
Product Name:Chloracoat Rubber Paint
Product Code:1122181050 (Light Blue 5 Litres)
1122182050 (Mid Blue 5 Litres)
1122183050 (White 5 Litres)
Relevant Identified Uses of the Substance or Mixture and Uses Advised Against:
Application of the substance/
the Preparation:Coating Compound/surface coating/paint
Details of the Supplier of the Safety Data Sheet
Name of Supplier:Golden Coast Ltd
Address of Supplier:Fishleigh Road, Roundswell Commercial Park West, Barnstaple, Devon. EX31 3UA
Telephone:01271 378100.
Responsible Person:Jamie Adams
Email:
Emergency Telephone Number01271 378100 (office hours)
2.Hazards Identification
Classification of the Substance or Mixture
Classification according to Directive 67/548/EEC or directive 199/45/EC:
Xn: Harmful
R20/21/22-40-48/20:harmful by inhalation, in contact with skin and if swallowed. Limited evidence of a carcinogenic effect.
Harmful: Danger of serious damage to health by prolonged exposure through inhalation
Xi: Irritant
R38Irritating to skin
N: Dangerous for the environment
R51/53-59:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Dangerous to ozone layer
R10:Flammable
Information concerning particular hazards for humans and environment:
The product has to be labelled due to the calculation procedure of the “General Classification guideline for preparations of the EU” In the
latest version.
Classification System
The classification is according to the latest editions of the EU-lists and extended by company and literature data.
Chemical:Xylene (mix)
CAS No:1330-20-7
Chemical:Carbon tetrachloride
CAS No:56-23-5
Label Elements
Labelling According to EU Guidelines:
The product has been classified and marked in accordance with EU Directives/Ordinance on Hazardous Materials
Code Letter and Hazard Xn: Harmful
Designation of Product:N: Dangerous to the environment
Hazard Determining Chloropolyolefin
Componentsof Labelling:Chlorinated paraffins, C10-13
Carbon tetrachloride
Xylene (mix)
Risk Phrases:
R10Flammable
R20/21/22Harmful by inhalation, in contact with skin and if swallowed
R38Irritating to skin
R40Limited evidence of a carcinogenic effect
R48/20Harmful: danger of serious damage to health by prolonged exposure through inhalation
R51/53Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R59Dangerous to the ozone layer
Safety Phrases:
S9Keep container in a well-ventilated place
S23Do not breathe fumes/vapour/spray
S25Avoid contact with eyes
S36/37Wear suitable protective clothing and gloves
S43In case of fire, use water or powdered extinguishing agent
S59Refer to manufacturers/supplier for information on recovery/recycling
Other Hazards
Results of PBT and vPvB assessment
PBT:chlorinated paraffins C10-13
vPvB:Chlorinated parrafins C10-13
3.Composition/Information on Ingredients
Chemical Characterization Mixtures
Chemical Name:Chloropolyolefin
Concentration:25-50%
CAS Number:9006-03-5
R/H PhrasesR20/21/22-48
Symbols: Xn
Chemical Name:Xylene (mix)
Concentration:10-25%
CAS Number:1330-20-7
EINECS Number:215-535-7
R/H PhrasesR20/21 R38 R10
Symbols: Xi; Xn
Chemical Name:chlorinated paraffins, C10-13
PBT; vPvB
Concentration:2.5-10%
R/H PhrasesR40 R50/53
Symbols: Xn
N
Carc. Cat. 3
Chemical Name:Carbon tetrachloride
Concentration: 2.5%
CAS Number:56-23-5
EINECS Number:200-262-8
R/H PhrasesR23/24/25-48/23 R40 R52/53 R59
Symbols: Xn
N
T
Carc. Cat. 3
SVHC:Chlorinated paraffins C10-13
Additional Information:For the wording of the listed risk phrases refer to Section 16
4.First Aid Measures
Description of First Aid Measures
General Information:Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident
After Inhalation:Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms persist
In case of unconsciousness place the patient stably in side position for transportation
After Skin Contact:Immediately wash with water and soap rinse thoroughly.
After Eye Contact:Rinse opened eye for several minutes under running water
After Swallowing:Call for a doctor immediately
Information forDoctor:
Most Important Symptoms and
Effects, both Acute and Delayed:No further relevant information available
Indication of Immediate MedicalAttention Special Treatment Needed
No further information available
5.Fire Fighting Measures
Extinguishing Media
Suitable extinguishing Media:CO2 powder or water spray. Fighter larger fires with water spray or alcohol resistant foam
Unsuitable extinguishing Media:Water with full jet
Special Hazards Arising from
the Substance or MixtureNo further information available
Advice for Fire Fighters
Special Protective Equipment:Mount respiratory protective device
6.Accidental Release Measures
Personal Precautions, Protective Equipment and Emergency Procedures:
Personal Protection:Wear protective equipment. Keep unprotected persons away
Environmental Precautions:Inform respective authorities in case of seepage into water or sewage system
Do not allow to enter sewers/surface or ground water
Methods and Material for
Containment and Cleaning Up:Absorb with liquid-binding material(sand, diatomite, acid binders, universal binders, sawdust)
Dispose contaminated material as waste according to item 13
Ensure adequate ventilation
Reference to Other Sections:See Section 7 for information on safe handling
See Section 8 for information on personal protection equipment
See Section 13 for disposal information
7.Handling and Storage
Precautions for Safe Handling:Keep receptacles tightly sealed
Ensure good ventilation
Prevent formation of aerosols
Information about Fire Keep ignition sources away – DO not smoke
And Explosion Protection:Protect against electrostatic charges
Conditions for Safe Storage, Including any Incompatibilities
Storage:
Requirements to be met by
Storeroomsand receptacles:No special requirements
Information about storage in one
Common storage facility:Not required
Further Information about
Storage Conditions:Keep receptacle tightly sealed
Specific End Use(s)No further relevant information available
8.Exposure Controls/Personal Protection
Additional information about design of technical facilities: No further data; see item 7
Control Parameters
Ingredients with limit values that require monitoring at the workplace
Chemical:Xylene (mix)
CAS No:1330-20-7
WEL
Long-term value:220mg/m3 50ppm
Short-term value:441mg/m3 100ppm
Chemical:carbon tetrachloride
CAS No:56-23-5
WEL
Long-term value:13mg/m3 2ppm
Sk
Additional Information:The lists valid during the making were used as basis
Exposure Controls
Personal Protective Equipment:
General protective andImmediately remove all soiled and contaminated clothing
Hygienic measures:Wash hands before breaks and at end of work
Keep away from foodstuffs, beverages and feed
Avoid contact with the skin
Avoid contact with the eyes and skin
Respiratory Protection:When spraying the product, use a respiratory protective device
Protection of Hands:When skin exposure may occur, advice should be sought from the glove supplier on appropriate
types and usage times for this product
Protective Gloves
The glove material has to be impermeable and resistant to the product/ the substance/the preparation
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation.
Material of Gloves:The selection of suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of glove material can not be calculated and has therefore to be checked
prior to the application
Penetration time of glove material:The exact break through time has to be found out by manufacturer of the protective gloves and has to
be observed
Eye Protection: Tightly sealed goggles
9.Physical and Chemical Properties
9.1Information on Basic Physical and Chemical Properties
General Information:
Odour:Characteristic
Odour Threshold:not determined
Appearance:Fluid
ColourAccording to product specification
pH value:Not determined
Melting Point:Undetermined
Boiling Point:137C
Vapour Pressure @ 20C:23 hPa
Density @ 20C:1.731g/cm3
Water Solubility:NOT MISCIBLE
Flammability (solid, gaseous):Not applicable
Flash Point:25C
Ignition Temperature:500C
Auto Ignition Point:Product is not self igniting
Explosive:Product does not present an explosion hazard. However, formations of explosive air/vapour mixtures are possible
Lower Explosion Limit:1.1 Vol %
Upper: Explosion Limit7.0 Vol %
Decomposition Temperature:Not determined
Segregation Coefficient:
(n-octanol/water):Not determined
Evaporation Point:Not determined
Viscosity:Not determined
Solvent Content:Organic Solvents: 24.1%
Solids Content:51.4%
Other InformationNo further relevant information available
10.Stability and Reactivity
Reactivity
Chemical Stability
Thermal Decomposition:No decomposition if used according to specifications
Possibility of Hazardous Reactions:No dangerous reactions known
Conditions to Avoid:No further relevant information available
Incompatible Materials:No further relevant information available
Hazardous Decomposition ProductsNo dangerous decomposition products known
11.Toxicological Information
Information on Toxicological Effects
Acute toxicity
LD/LC50 values relevant for classification:
Chemical:Xylene
CAS Number:1330-20-7
OralLD50 8700 mg/kg (rat)
Dermal LD50 2000mg/kg (rabbit)
Inhalative:LC50/4h 6530 m g/l (rat)
Chemical:carbon tetrachloride
CAS Number:56-23-5
OralLD50 43 mg/kg (HMN)
Dermal LD50 5070mg/kg (rat)
Inhalative:LC50/4h 1000 m g/l (HMN)
Primary Irritant Effect:
Contact with Skin:Irritant to skin and mucous membranes
Contact with Eyes:No irritating effect
Sensitization:No sensitizing effects known
Additional toxicological information
The product shows the following dangers according to the calculation of the general EU Classification Guidelines for Preparations as issued in the latest version
Harmful
Irritant
12.Ecological Information
Toxicity
Aquatic toxicity:No further relevant information available
Persistence and DegradabilityNo further relevant information available
Behaviour in environmental systems
Bioaccumulation Potential:No further relevant information available
Mobility in Soil:No further relevant information available
Ecotoxical Effects:
Remark:Toxic for fish
Additional ecological information:
General notes:Water danger class 3 (German regulation) (Self-assessment):extremely hazardous for water.
Do not allow to reach ground water, water course or sewage systems, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground
Also poisonous for fish and plankton in water bodies
Toxic for aquatic organisms
Results of PBT and vPvB Assessment
PBT:chlorinated paraffins C10-13
vPvB:chlorinated paraffins C10-13
Other Adverse EffectsNo further relevant information available
13.Disposal Considerations
Waste Treatment Methods
Recommendation:Must not be disposed together with household waste. Do not allow product to reach sewage system
Uncleaned Packaging
Recommendation:Disposal must not be made accordingto official regulations
14.Transport Information
Un Number:
ADR, IMG, IATAUN1263
UN Proper Shipping Name
ADR:1263 PAINT (not viscous), ENVIRONMENTALLY HAZARDOUS
IMDG, IATAPAINT
Transport Hazard class(es)
ADR
ADR/RID class:3 Flammable Liquids
Hazard Label3
IMDG
Class3 Flammable Liquids
Hazard Label3
IATA
Class:3 Flammable Liquids
Label:3
ICAO Packing Group:III
Packing Group
ADR IMDG IATAIII
Environmental Hazards
Marine Pollutant:No
Special marking (ADR)Symbol (fish and tree)
Special Precaution for user:Warning: Flammable Liquids
Danger Code (Kemler):30
EMS Number:F-E, S-E
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code:Not applicable
Transport/Additional Information:
ADR Tunnel Restriction:D/E
15.Regulatory Information
Safety, Health and Environmental Regulations/Legislation Specific for the Substance or Mixture
National regulations
Technical instructions (air):
Class:I
Share in %7.3
Class:NK
Share in %47.9
Water Hazard Class:Water hazard class 3 (self-assessment): extremely hazardous to water
Substances of very high concern
(SVHC) according to REACH
Article 57chlorinated paraffins C10-13
Chemical Safety AssessmentA chemical safety Assessment has not been carried out.
16.Other Information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship
Relevant Phrases
R10Flammable
R20/21Harmful by inhalation and in contact with skin
R20/21/22Harmful by inhalation, in contact with skin and if swallowed
R23/24/25Toxic by inhalation, in contact with skin or if swallowed
R38Irritating to skin
R40Limited evidence of a carcinogenic effect
R48Danger of serious damage to health by prolonged exposure
R48/23Toxic: danger of serious damage to health by prolonged exposure through inhalation
R50/53Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R52/53Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R59Dangerous to the ozone layer
R66repeated exposure may cause skin dryness
Note:
This data sheet does not constitute a user’s assessment of workplace risk as required by HSW act, COSHH, management of health and safety at work regulations, or other health and safety legislation.