Roadmaster Mortar Plus
1.Identification of substance/preparation &
company undertaking
Substance name: Tarmac DPM Component A
For further details of the specification refer to the relevant Technical Data Sheet.
Company details:
Tarmac Building Products Limited
Millfields Road
Ettingshall
Wolverhampton WV4 6JP
Telephone: 08000 32 40 20(during office hours)
Fax: 01902 353920
Web:
2. Hazard identification
Classified as hazardous (irritant) and dangerous for the environment in accordance with the Chemicals (Hazard Information and Packaging for Supply) Regulations.
Information concerning particular hazards for persons and the environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 36/38 Irritating to eyes and skin.
R 43 May cause sensitisation by skin contact.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Contains epoxy constituents. See information supplied by the manufacturer.
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literaturedata.
Product labelling
Causes skin irritation.
Causes serious eye irritation.
May cause an allergic skin reaction.
Toxic to aquatic life with long lasting effects.
Contains epoxy constituents. May produce an allergic reaction.
Prevention:
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wear protective gloves/protective clothing/eye protection/face protection.
Response:
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing.
Specific treatment (see on this label).
Take off contaminated clothing and wash before reuse.
Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
3. Composition / information on ingredients
Epoxy Resin
Reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ?700) >50-100%
CAS: 25068-38-6
NLP: 500-033-5
Reaction product: bisphenol-F-epichlorhydrin epoxy resin (number average molecular weight ?700)>10-25%
CAS: 9003-36-5
NLP: 500-006-8
Oxirane, mono[(C12-14-alkyloxy)methyl] derives 5-15%
CAS: 68609-97-2
EINECS: 271-846-8
4. First aid measures
After inhalation:
In case of unconsciousness place patient stably in side/recovery position for transportation.
Supply fresh air; consult doctor in case of complaints.
After skin contact: Wash with soap and water. Remove contaminated clothing.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing: Rinse mouth with water and then drink plenty of water, consult physician immediately.
5. Fire fighting measures
Suitable extinguishing agents: CO2, powder or water haze. Fight larger fire with alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: Water spray
Special hazards caused by the substance, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Protective equipment:
Wear self-contained respiratory protective device.
Wear fully protective suit.
Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
6. Accidental release measures
Person-related safety precautions: Wear protective clothing.
Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
7. Handling & storage
Handling:
Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
Information about fire - and explosion protection: No special measures required.
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool, but frost-proof location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Recommended storage temperature between 15 and 25°C.
8. Exposure controls / personal protection
Additional information about design of technical facilities: No further data; see item 7.
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.
Additional information: The lists valid during manufacture were used as basis.
Personal protective equipment:
General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals.
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection:
Not necessary if room is well-ventilated.
Use suitable respiratory protective device only when aerosol or mist is formed.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/the chemical mixture.
Selection of the glove material is dependant on the penetration times, rates of diffusion and degradation.
Material of gloves
The selection of suitable gloves does not only depend on the material, but also on further aspects of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior tothe application.
Penetration time of glove material
The exact break through time has to be established by the manufacturer of the protective gloves and has to be observed.
For prolonged contact gloves made of the following materials are suitable:
Nitril rubber, chloroprene and PVC.
Butyl rubber or PVC
Butyl rubber
Nitril rubber
Eye protection:
Tightly sealed goggles
Tightly sealed goggles by risk of splashing.
Body protection: Protective work clothing
9.Physical & chemical properties
General Information
Form: Fluid
Colour: Colourless
Odour: Weak, characteristic
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: > 100°C
Flash point: 130°C
Self-igniting: Product is not self-igniting.
Danger of explosion: Product does not present an explosion hazard.
Density at 20°C: 1.14 g/cm³
Solubility in / Miscibility withwater: Not soluble and miscible.
Viscosity:
Dynamic at 20°C: 1000 mPas
Solvent content:
Organic solvents: 0.0 %
Solids content: 100.0 %
10. Stability & reactivity
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided:
Dangerous reactions
May produce violent reactions with bases and numerous organic substances including alcohols and amines.
Dangerous decomposition products: Irritant gases/vapours
11. Toxicological information
Acute toxicity:
LD/LC50 values relevant for classification:
25068-38-6 reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ?700)
Oral LD50 >5000 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rat)
9003-36-5 reaction product: bisphenol-F-epichlorhydrin epoxy resin (number average molecular weight ?700)
Oral LD50 5000 mg/kg (rat)
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: No irritating effect.
Sensitization: Sensitization possible through skin contact.
Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
Sensitisation May cause sensitisation by skin contact.
12. Ecological information
Ecotoxical effects:
Remark: Toxic for fish
Additional ecological information:
General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage
system.
Danger to drinking water if even small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Toxic for aquatic organisms
13. Disposal consideration
Safe handling of residues / waste product:
Product:
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
14. Transport information
Land transport ADR/RID (cross-border)
ADR/RID class: 9 Miscellaneous dangerous substances and articles.
Danger code (Kemler): 90
UN-Number: 3082
Packaging group: III
Hazard label 9
Special marking: Symbol (fish and tree)
Description of goods: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number averagemolecular weight ?700))
Tunnel restriction code E
Maritime transport IMDG:
IMDG Class: 9
UN Number: 3082
Label 9
Packaging group: III
EMS Number: F-A-S-F
Marine pollutant: No
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular
weight ?700))
Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: 9
UN/ID Number: 3082
Label 9
Special marking: Symbol (fish and tree)
Packaging group: III
Proper shipping name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular
weight ?700))
15. Regulatory information
Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
Code letter and hazard designation of product:
Hazard-determining components of labelling:
reaction product: bisphenol-A-(epichlorhydrin) epoxy resin (number average molecular weight ?700)
reaction product: bisphenol-F-epichlorhydrin epoxy resin (number average molecular weight ?700)
oxirane, mono[(C12-14-alkyloxy)methyl] derivs
Risk phrases:
36/38 Irritating to eyes and skin.
43 May cause sensitisation by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety phrases:
2 Keep out of the reach of children.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
28 After contact with skin, wash immediately with plenty of soap and water.
29 Do not empty into drains.
37/39 Wear suitable gloves and eye/face protection.
Special labelling of certain preparations:
Contains epoxy constituents. See information supplied by the manufacturer.
National regulations:
Waterhazard class: Water hazard class 2 (Self-assessment): hazardous for water.
Other regulations, limitations and prohibitive regulations
Substances of very high concern (SVHC) according to REACH, Article 57
None of the ingredients is listed.
16. Other information
Department issuing MSDS: SHE Department
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
Recommended uses & applications:
Industrial and construction applications.
Further information:
Web:
Telephone: 08000 32 40 20
Key data used to compile data sheet:
HSE Guidance Note EH40
PPE Regulations
COSHH Regulations
Environmental Protection Act 1990
Prepared in accordance with Annex II of the REACH Regulation (EC) 1907/2006
Legal notice
The information in this Safety Data Sheet was believed to be correct at the time of issue. However, no warranty is made or implied as to the accuracy or completeness of this information. If you have purchased this product for supply to a third party for use at work, it is your duty to take all necessary steps to ensure that any person handling or using the product is provided with the information in this sheet. If you are an employer, it is your duty to tell your employees and others who may be affected of any hazards described in this sheet and any of the precautions which should be taken. This Safety Data Sheet does not constitute the user’s own assessment of workplace risk. It is the user’s sole responsibility to take all necessary precautions when using this product.