Intendeduseautomotive Re-Finishforprofessionaluseonly

Intendeduseautomotive Re-Finishforprofessionaluseonly

PRODUCTSAFETYDATASHEETDATEOFISSUE04-1-05

Page1Issue 2

1.IDENTIFICATIONOFPRODUCTCOMPANY

PRODUCTNAME2-packPrimer

INTENDEDUSEAutomotive Re-finishForProfessionalUseONLY.

DETAILOFCOMPANYMK1 Paints 58Perry Street, Wednesbury, West Midlands,WS10OAZ. Emergency Tele. 0121 5020050

2.COMPOSITION/INFORMATIONONINGREDIENTS.

Substancespresenting ahealthhazardwithinthe meaning ofthe Chemicals (Hazard Information &Packaging)Regulations 1993.

SubstanceName / CAS No. / EINEC No. / Conc..Range / Symbols / Risk Phrases*
BUTYL ACETATE XYLENE,MIXTUREOFISOMERS 1,2,4-TRIMETHYLEBENZINE SOLVENTNAPTHA
METHYL ISOBUTYLE KETONE ETHYLETHOXYPROPIONATE / 123-86-4 1330-20-7 95-63-6 64742-95-6 108-10-1 763-69-9 / 123-86-4 215-535-7
265-150-3 203-550-1 212-112-9 / 10-20 5-101-10 10-20 5-105-10 / Xn Xn,Xi X,n Xn,n Xn,F / 10-66-67 20/21-38
20,36/37/38,51/53 65,66,67,51/53
11-20-36/37-66 52/53

T+=VeryToxicT=ToxicXn=HarmfulC=CorrosiveXi=IrritantE=ExplosiveO=OxidisingF+=ExtremelyFlammable F=Highly Flammable N=Environmentally Hazardous

*Fordetails of Risk Phrases seeSection 16 3.HAZARDSIDENTIFICATION. HAZARDS

FlammableHarmfulIrritant to eyes RISKS

Highly Flammable

Harmful by inhalation, incontact with skin and may causelung damage if swallowed. Irritationtorespiratory systemeyes and skin

Harmful to aquatic organisms, may causelong-termadverseeffects inaquatic environment

Inhalationofvapoursfromthisproductcancausenarcosisand,withcontinuedexposureabovetheOEL,possiblelong termeffects.

4.FIRSTAIDMEASURESGENERAL

Inallcasesofdoubtorwhensymptomspersistseekmedicalattention.Nevergiveanythingbymouthtoanunconscious person.

INHALATION.

Movetheexposedpersontofreshairkeepwarmandatrest.Ifbreathingisirregularorhasstoppedgiveartificial respiration. Givenothing by mouth ifunconscious placeinrecovery position andseekmedical advice.

INGESTION

If accidentally swallowedobtainmedical attention.Keep at rest DONOTinduce vomiting. SKIN

Removecontaminatedclothing.Washskinthoroughlywithsoapandwateroruseaproprietaryskincleaner.DoNOT useSolvent or Thinners.Obtain medical adviceshould blistering orrednesspersist.

EYES.

Contactlensesshouldberemoved.Irrigatecopiouslywithclean,freshwaterforatleast10minutesholdingtheeyelids apart; seek medical advice should sorenessorrednesspersist.

PRODUCTSAFETYDATASHEETDATEOFISSUE04-1-05

Page2Issue 2

5.FIREFIGHTINGMEASURES. EXTINGUISHINGMEDIA.

RECOMMENDEDCarbon-Dioxide,Dry Powder,Sand, Foam. DONOTUSEWater

ThismaterialisFlammable.UsealcoholresistantfoamUsedrychemicalorcarbondioxide.Keepcontainersand surroundingscool with water spray.

SPECIALINSTRUCTIONSTOFIREFIGHTINGPERSONNEL

Wearprotectiveclothingandself-containedbreathingapparatus.Firewillproducedenseblacksmokecontaining hazardous productsofcombustion.Decompositionofproducts may causea hazard tohealth.Coolclosedcontainers exposedtofirewithawaterspray.DonotallowrunofffromthefirefightingtoenterdrainsorwatercoursesVapours can travela considerabledistance toa sourceofignition and flashback.

6.ACCIDENTALRELEASEMEASURES. SPILLCLEANUPMETHODS

Excludesourcesofignitionandventilatearea.Excludenon-essentialpersonnel.Avoidbreathingvapours.Refertoprotective measureslistedinSection78.Containandcollectanyspillagewithnon-combustibleabsorbentmateriale.g.sand,earthor otherinertmaterialandplaceinasuitablecontainerfordisposalinaccordancewithwasteregulations.DoNotallowtoenter drainsorwatercourses.Ifit doesthelocalwatercompanyshouldbenotifiedimmediately,incaseofcontaminationofstreams, riversorlakes TheNational Rivers Authority.Clean preferably with adetergent, avoid useofsolvents.

7.HANDLINGSTORAGE

HANDLING:PRECAUTIONS:Useinwellventilatedare.Avoidinhalingvapour.Avoidcontactwitheyes,skinand clothing.Keepcontainertightlyclosedwhennotinuse.Vapoursareheavierthanairandmayspreadalongfloors,theymay formexplosivemixtureswithair.Preventthecreationofflammableorexplosiveconcentrationsofvapourinairandavoid vapourconcentrationshigherthantheoccupationalexposurelimits.Additionally,theproductshouldonlybeusedinareas fromwhichallnakedlightsandothersourcesofignitionhavebeenexcluded.Electricalequipmentshouldbeprotectedtothe appropriatestandard.Excludesourcesofheat,sparksandopenflame.Nonsparkingtoolsshouldbeused.Smoking,eating anddrinkingshouldbeprohibitedinareaofstorageanduse.Neverusepressuretoempty,thecontainerisnotapressure vessel.

STORAGEPRECAUTIONS:Storeinaccordancewiththeconditionsofthelicence,whichisnecessaryunderthePetroleum (Consolidation)Act.SeetheHSEguidancenoteforStorageofFlammableLiquidsinContainers.Observethelabel precautions.Upto50litresofsuchflammableliquidsmaybekeptinaworkroomprovidedtheyarekeptinaseparate storeroomconformingtothestructuralrequirementsoftheregulations.Storeawayfromsourcesofheatandignition.And directsunlight.NoSmoking.Storebetween5-25deg.Cinadryventilatedareas.Preventunauthorisedaccesscontainers, whichareopened,shouldbeproperlyresealed andkeptuprighttopreventleakage.Storeseparately from oxidisingagents and stronglyalkalineandacidicmaterials..TheprinciplescontainedintheHSE’sGuidancenoteStorageofPackagedDangerous Substancesshould beobserved whenstoring this product.

8.EXPOSURECONTROLSANDPERSONALPROTECTION
SubstanceName / LTEL / STEL / Notes*
ppm / mgm/m3 / p.p.m / mgm/m3
NBUTYLACETATEXYLENE,MIXTUREOFISOMERS1,2,4-TRIMETHYLEBENZINESOLVENTNAPTHA
METHYLISOBUTYLEKETONE
ETHYLETHOXYPROPIONATEACETATE. / 15010025
50 / 710435 / 200150125200
100 / 950650545 / Sk,OESSk,OESOES
OEL

NOTES

LT =LongTermExposureLimit - 8 hour time weighted average. ST =Short TermExposure Limit - 10minute referenceperiod.

Notations =Sk- Risk ofabsorptionthrough skin. Sen -respiratorysensitizer.

PRODUCTSAFETYDATASHEETDATEOFISSUE04-1-05

Page3Issue 2

OES= Occupational ExposureStandard. MEL = MaximumExposureLimit

OEL’sarefromEH40 exceptwheremarkedSUP, which areassignedby thesupplier ofthe substance. EngineeringMeasures

Provideadequateventilation.Wherereasonablypracticablethisshouldbeachievedbytheuseofdilutionandlocalexhaust ventilationandgoodgeneralextraction.Ifextractionmethodsareinsufficienttomaintainconcentrationsofparticulateand/or solvent vapours belowrelevant OEL’s,suitable respiratory protective equipment should beworn.

General

Personswithahistoryofasthma,allergiesorchronicorrecurrentrespiratorydiseaseshouldonlybeemployedinprocessesin which this product is usedunderappropriate medical supervision.

Skincontactconstitutesthemostpronouncedhazard.Personswithahistoryofskinsensitisationproblemsshouldonlybe employed inprocessesinwhich this product is usedunderappropriate medical supervision.

GeneralProtection

HandProtection:

Eyeprotection:

RespiratoryEquipment:

SkinProtection:

All ppe, including rpe, used tocontrolexposure to hazardoussubstancesmust be selected to meet therequirements of the COSHHregulations.

Polyvinyl acetate gloves.Seek relevant advice fromGloveManufacturer. Barrier cream may be ofhelp but it shouldnot beapplied afterexposurehas occurred.

Eye protection designedto protect against chemical liquid splashes shouldbe worn.

Respiratory protection should be wornifthereis ariskofexposuretohighvapour concentrations.

Cotton orcotton/synthetic overalls arenormallysuitable.

HygienicWorkRoutines:Washattheendofeachwork shiftand beforeeating,smokingandusingthetoiletWash promptlyifskinbecomeswetorcontaminated.Removeanycontaminatedclothingat once.Useappropriateskincreamtopreventdryingofskin.Noeating,smokingor drinkingwhile workingwiththismaterial.DONOTSMOKE INWORKAREA!

9.PHYSICALCHEMICALPROPERTIES.

PHYSICALSTATE:Free Flowing liquid COLOURLight GreyFLASHPOINT29C

LOWEREXPLOSIONLIMIT.8%vol SOLUBILITYINWATERImmiscible VAPOURDENSITY Heavierthan air SPECIFICGRAVITY 1.5-+ 0.50gcm VOCCONTENT 0.43 Kgs/Lt

10.STABILITYREACTIVITY.

Stable undertherecommendedstoragehandlingconditions(seeSect.7).In afire, hazardousdecompositionproductssuchas smoke,carbonmonoxide,carbondioxide,andoxidesornitrogenmaybeproduced.Keepawayfromoxidisingagentsand strongly alkaline and acid materials toprevent the possibility ofexothermic reaction.

11.TOXICOLOGICALINFORMATION.

There is nodata available on theproduct itself.Respiratoryexposure may cause acuteirritation &/orsensitisation of

Therespiratorysystemresultinginasthmaticsymptoms.Repeatedexposuremayleadtopermanentrespiratorydisability. Exposuretoorganicsolventvapoursmayresultinadversehealtheffectssuchasirritationofthemucousmembraneandthe respiratorysystemandadverseeffectsontherenalandcentralnervoussystem.Symptomsincludeheadache,dizziness, fatigue, muscularweakness,drowsinessandin extreme cases,lossofconsciousness.

Repeatedorprolongedcontactwiththeproductmayleadtotheremovalofnaturalfatsfromtheskinresultinginnon-allergic contact dermatitisandabsorption throughtheskin.Splashesin theeyes may cause irritation and reversiblelocaldamage.

PRODUCTSAFETYDATASHEETDATEOFISSUE04-1-05

Page4Issue 2

12.ECOLOGICALINFORMATION

Theproductshouldnotbeallowedtoenterdrainsorwatercoursesorbedepositedwhereitcanaffectgroundorsurface waters.TheAirPollutionControl requirements ofregulations madeundertheEnvironmentalProtection Actmayapply to the useofthis product

13.DISPOSALCONSIDERATIONS.

Donotallowintowatercoursesordrainsordisposeofwheregroundorsurfacewatersmaybeaffected.Wastesincluding emptiedcontainers,arecontrolledwastesandshouldbedisposedofinaccordancewithregulationsmadeundertheControlof PollutionActandtheEnvironmentalProtectionAct.(Usingtheinformationprovidedinthissafetydatasheet,adviceshould be obtained fromthe Waste Regulation Authority whether theSpecial Waste regulations apply)

14.TRANSPORTINFORMATIONDomesticRoad/Rail

Road/Rail (RID/ADR) UNNumber

PackingGroup Class

Designation

1263 III

3.3

Paint related material

Sea

PackingGroup=30lts PackingGroup 30lts.

MarinePollutant... Main Risk... ShippingName..

1263 IIIIII

No Flammable

.Paint Related Material

Air

UN/IATAID Number.1263 PackingGroup=30lts III PackingGroup 30lts. III Class 3.3

Shipping Name.Paint Related Product Main Risk... Flammable

SubRiskNarcosis

InternationalRoad/Rail

ItemNumber31C Class3.3 Packing Group.. .III UNNumber...1263

Main Risk...Flammable SubRiskNarcosis

Chemical Name.. Paint Related Products

NOTE:Theaboveregulatory prescriptionsarethosevalid onthedateofpublicationof thissheet.

Giventhepossibleevolutionof transport regulations for hazardousmaterials,it wouldbe advisableto check their validity.

PRODUCTSAFETYDATASHEETDATEOFISSUE04-1-05

Page5issue2

15.REGULATORYINFORMATION

ThisproductisclassifiedandlabelledforsupplyinaccordancewiththeChemicals(HazardInformationandPackaging) Regulations as follows:

Classification

Flammable

Contains

RiskPhrases

SafetyPhrases

“P”Phrases

StatutoryInstruments

ApprovedCodeofPractise

GuidanceNotes

Harmful

BUTYL ACETATE

XYLENE, MIXTURE OF ISOMERS 1,2,4-TRIMETHYLEBENZINE SOLVENT NAPTHA

METHYL ISOBUTYLE KETONE ETHYL ETHOXY PROPIONATE

R10Flammable.

R11Highly flammable

R20/2Harmful by inhalationandincontact with skin R38Irritating toskin

S2Keepoutofreachofchildren S25Avoidcontact with eyes.

Donot breathe vapourorspray

FORUSEININDUSTRIAL INSTALLATIONSONLY

Chemicals(HazardInformationandPackaging)Regulations.ControlofSubstances Hazardous toHealth

Classification andLabelling ofSubstances and Preparations Dangerousfor Supply.

OccupationalExposureLimitsEH40,IntroductiontoLocalExhaustVentilationHS (G)37. CHIPfor everyoneHSG(108).

TheinformationcontainedinthisSafetyDataSheetdoesnotconstitutetheuser’sownassessmentoftheworkplacerisksas requiredbyotherHealthSafetylegislation.TheprovisionsoftheHealthSafetyatWorketc.ActandtheControlof Substances Hazardoustohealthregulationapply to theuseof this productatwork.

16.OTHERINFORMATION.

TheinformationcontainedinthisSafetyDataSheetisprovidedinaccordancewiththerequirementsoftheChemicals(Hazard InformationandPackaging)Regulations.TheproductshouldnotbeusedforpurposesotherthanthoseshowninSection1 withoutfirstreferringtothesupplierandobtainingwritteninstructions.Asthespecificconditionsofuseoftheproductare outsideofthesupplier’scontrol,theuserisresponsibleforensuringthattherequirementsofrelevantlegislationarecomplied with.Theinformationgivenisbasedonthepresentstateofknowledgeandcurrentnationallegislationandsupersedesall SafetyDataSheetsissuedpriortotheissuedate.Itprovidesguidanceonhealth,safetyandenvironmentalaspectsofthe productsandshould notbe construedas any guaranteeoftechnical performance or suitability for particular applications.

PRODUCTSAFETYDATASHEETDATEOFISSUE04-1-05

Page6issue2

Furtherinformation andrelevant advicecanbefound in: -

The control ofsubstancesHazardous toHealthRegulations 1988(S11988:1657) TheManual HandlingOperations Regulations 1992 (SI:1992)

Storage of Flammable Liquidsin Containers HS(G)51 Storage of PackagedDangerousSubstances HS(G)71

The Environmental Protection(Duty ofCare)Regulations 1992 (SI 1988:2839)

TextofRiskPhrasesListedinSection2

R10R11R20R20/21

R20/21/22R23

R36R36/37/38R38

R42R42/43R43R51/53

R66R67

Flammable.Highly flammable.

Harmfulbyinhalation.

Harmfulbyinhalationandincontactwithskin.

Harmfulbyinhalationandincontactwithskinandifswallowed.Toxicbyinhalation.

Irritatingtoeyes.

Irritatingtoeyes,respiratorysystemandskin.Irritatingtoskin.

Maycausesensitisationbyinhalation.

Maycausesensitisationbyinhalationandskincontact.Maycausesensitisationbyskincontact

Toxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment

RepeatedexposuremaycauseskindrynessorcrackingVapoursmaycausedrowsinessanddizziness.