Solutions & Solubility / Name: / /7 K / 24 I /11 C /14 A /55
PART A: Multiple Choice (11 marks)
Circle the best possible answer for the following questions
- In aqueous solution, salts exist in the form of:
- Molecules
- Atoms
- Electrons
- Ions
- The solubility of AgCl in water is 8.9 x 10-4g/100mL at 45°C. If a solution of AgCl at 45°C contains 1.4 x 10-5 g/100mL it would be described as:
- Supersaturated
- Saturated
- Unsaturated
- Concentrated
- Which of the following changes the solubility of a solid in a saturated solution?
- Stirring the solution
- Grinding the solid
- Changing the temperature of the solution
- Adding more solute
- In which of the following is concentration expressed in percent by volume?
- 10% (v/v)
- 10% (m/v)
- 10% (m/m)
- 10 %
- In a concentrated solution, there is:
- No solvent
- A large amount of solute
- A small amount of solvent
- No solute
- Identify the FINAL step to follow when preparing a stock solution from a solid?
- Mass out the solute and add it to the flask.
- Add more solvent until you reach the required amount.
- Mass out the solvent and add it to the flask.
- Add about half the required volume of solvent to the flask.
- What is a characteristic of an Arrhenius acid?
- It reacts with water to form hydrogen ions.
- It accepts a pair of electrons.
- It turns phenolphthalein solution red
- It donates a proton
- When an ionic equation is written for the double displacement reaction between H2PO4 (aq) + FeSO4 (aq)
thespectator ions are …….
- H+and PO43-
- Fe2+and SO42-
- SO42-and H+
- Fe2+and PO43-
- Which of the following would produce a bright red flame?
- KNO3
- LiCl
- CuSO4
- Ni(OH)2
- Which of the following solutions would be blue?
- LiNO3
- KCl
- NiSO4
- Cu(OH)2
- You have a solution containing Co2+, Fe3+, H+, & Ag+. 10 drops of hydrochloric acid are added – a precipitate forms! What is the precipitate?
- CoCl2
- FeCl3
- HCl
- AgCl
PART B: Match-Up (45 marks)
COLUMN A / COLUMN B____ 1. / An example of a solution of gases / A. / Bronze
____ 2. / A solution which will not dissolve any more solute / B. / Aqueous solution
____ 3. / An alloy of copper and tin used in making statues / C. / Water
____ 4. / Sugar does this in tea or coffee / D. / Air
____ 5. / The Universal solvent / E. / Pressure
____ 6. / A solution in which water is the solvent / F. / Base
____ 7. / Name given to the dissolved substance / G. / Solute
____ 8. / A factor affecting the amount of solute that can dissolve in a solvent / H. / Solution
____ 9. / A substance which produces OH- in water / I. / Mole
J. / Dissolves
K. / Saturated
PART C: Short Answer (45 marks)
Answer all questions in the space provided. For full marks, show each step in calculating your solution for numerical problems & watch sig digits.
- If 22.2 g of potassium sulfate is dissolved in 500mL of water, what is the concentration of K+ions in the solution?). [I-4]
- a) By the addition of water, 40mL of 8.0M H2SO4 is diluted to 3.0L. What is the concentration of H2SO4 after dilution? [I-3]
- Use the solubility curve below to answer the following questions:
- At what temperature is the solution of Pb(NO3)2 70g? ______
- At what temperature are the solubility of NaCl and KNO3 the same? ______
- What is the predicted solubility of KClO3 at 75°C? ______
- Describe the degree of saturation (ie. sat, unsat, supersat) of the following:
- 30 g/100mL of KCl at 50°C ______
- 70 g/100mL of KNO3 at 40°C ______
- What mass of CaCl2 is needed to saturate at 10°C a solution that already contains 45g/100mL of CaCl2.
- If 1.0 g of NaOHis dissolved in 250mL of water, what would the pH of this solution be?[I-4]
- a) If 25.0mL of acetic acid (HC2H3O2) solution was added to a flask with phenolphthalein and 24 mL of 0.62 M Ba(OH)2 are added to reach the titration end-point, what was the concentration of the acetic acid solution?[I-4]
b) Whatcolour was the solution at the end point? [K-1] ______
- Compare and contrast the effect of opening and drinking a can of icy-cold cola to the effect of opening and drinking a can of warm, totally non-refreshing cola in terms of amount of fizz. Explain what is happening in terms of solubility of carbon dioxide in each can. [C-4]
- When 200 mL of 0.300 M AgNO3 and 300 mL of 0.300 M KI are mixed, how many grams of AgI are formed in the reaction mixture?[I-6]
- Classify each reactant in the following equations as either a Bronsted-Lowry acid or base:
- F(aq) + HSO3-(aq) HF(aq) + SO32-(aq)
Acid:Base:
Conjugate Acid: Conjugate Base:
- HCO3-(aq) + C2H3O2-(aq) HC2H3O2 (aq) + CO32-(aq)
Acid:Base:
Conjugate Acid: Conjugate Base: