Table S1 Experimental and Ideal CMC (Cm, Ci), Surface Excess Concentration ( Max), Experimental

Table S1 Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), surface concentration (C20) and surface pressure at CMC (CMC) of the binary mixtures of P105 with dimeric/monomeric surfactants versus the mole fraction of dimeric/monomeric surfactant (α) at 308.15 K

 / Cm*10
(mmol·dm-3) / Ci*10
(mmol·dm-3) / max*106(mol·m-2) / Amin
(Å2) / Aidmin
(Å2) / C20
(mmol·dm-3) / CMC
(mN·m-1)
10-2-10
0.000 / 0.083 / 0.083 / 3.20 / 51.82 / 0.037 / 28.66
0.156 / 0.091 / 0.099 / 4.08 / 40.70 / 57.96 / 0.038 / 26.19
0.356 / 0.114 / 0.131 / 3.75 / 44.23 / 61.37 / 0.035 / 26.50
0.480 / 0.147 / 0.164 / 3.37 / 49.20 / 62.05 / 0.040 / 27.08
0.625 / 0.169 / 0.228 / 1.93 / 86.11 / 63.42 / 0.045 / 28.04
0.787 / 0.287 / 0.390 / 1.89 / 87.61 / 66.83 / 0.071 / 28.62
0.903 / 0.618 / 0.831 / 1.71 / 96.94 / 70.92 / 0.163 / 29.81
1.000 / 65.000 / 65.000 / 1.38 / 120.06 / 10.211 / 26.77
12-2-12
0.000 / 0.083 / 0.083 / 3.20 / 51.82 / 0.037 / 28.66
0.156 / 0.087 / 0.099 / 3.54 / 46.89 / 55.44 / 0.030 / 27.49
0.356 / 0.100 / 0.122 / 3.37 / 49.31 / 56.89 / 0.038 / 27.33
0.480 / 0.131 / 0.161 / 2.67 / 62.05 / 61.24 / 0.036 / 27.47
0.625 / 0.193 / 0.237 / 2.10 / 78.96 / 57.61 / 0.049 / 28.54
0.787 / 0.314 / 0.387 / 1.35 / 122.57 / 61.96 / 0.072 / 28.74
0.903 / 0.604 / 0.810 / 1.60 / 103.56 / 64.14 / 0.127 / 27.02
1.000 / 9.900 / 9.900 / 1.34 / 124.29 / 1.480 / 21.98
14-2-14
0.000 / 0.083 / 0.083 / 3.20 / 51.82 / 0.037 / 28.66
0.156 / 0.073 / 0.098 / 4.59 / 36.17 / 62.53 / 0.025 / 26.95
0.356 / 0.109 / 0.119 / 5.20 / 31.95 / 63.72 / 0.031 / 27.23
0.480 / 0.113 / 0.153 / 3.14 / 52.89 / 64.91 / 0.037 / 27.97
0.625 / 0.141 / 0.215 / 2.71 / 61.21 / 69.08 / 0.042 / 29.05
0.787 / 0.154 / 0.322 / 2.15 / 77.25 / 73.85 / 0.043 / 28.78
0.903 / 0.310 / 0.547 / 1.75 / 94.83 / 79.20 / 0.076 / 27.05
1.000 / 1.320 / 1.320 / 1.49 / 111.36 / 0.230 / 20.80
DTAB
0.000 / 0.083 / 0.083 / 3.20 / 51.82 / 0.037 / 28.66
0.156 / 0.091 / 0.098 / 4.36 / 38.05 / 58.16 / 0.037 / 26.49
0.356 / 0.106 / 0.128 / 3.98 / 41.68 / 61.68 / 0.049 / 26.67
0.480 / 0.146 / 0.160 / 3.18 / 52.27 / 62.39 / 0.056 / 26.22
0.625 / 0.204 / 0.220 / 2.69 / 61.76 / 63.79 / 0.089 / 26.86
0.787 / 0.319 / 0.384 / 1.79 / 92.68 / 67.32 / 0.148 / 27.42
0.903 / 0.689 / 0.826 / 2.22 / 74.74 / 71.55 / 0.318 / 27.48
1.000 / 159.390 / 159.390 / 1.36 / 122.29 / 60.342 / 27.57
TTAB
0.000 / 0.083 / 0.083 / 3.20 / 51.82 / 0.037 / 28.66
0.156 / 0.089 / 0.098 / 3.79 / 43.77 / 56.69 / 0.043 / 26.98
0.356 / 0.106 / 0.129 / 3.40 / 48.84 / 61.56 / 0.052 / 27.17
0.480 / 0.138 / 0.159 / 3.96 / 41.88 / 63.99 / 0.058 / 28.24
0.625 / 0.192 / 0.220 / 2.96 / 56.10 / 66.43 / 0.077 / 27.03
0.787 / 0.356 / 0.390 / 1.98 / 83.98 / 64.81 / 0.150 / 27.62
0.903 / 0.724 / 0.831 / 1.57 / 105.48 / 63.99 / 0.290 / 28.28
1.000 / 39.700 / 39.700 / 1.25 / 133.01 / 15.400 / 29.07
CTAB
0.000 / 0.083 / 0.083 / 3.20 / 51.82 / 0.037 / 28.66
0.156 / 0.073 / 0.098 / 4.14 / 40.09 / 61.86 / 0.038 / 27.08
0.356 / 0.117 / 0.128 / 4.27 / 38.89 / 61.86 / 0.049 / 27.89
0.480 / 0.132 / 0.158 / 3.68 / 45.07 / 67.34 / 0.054 / 27.88
0.625 / 0.144 / 0.218 / 3.01 / 55.09 / 71.00 / 0.084 / 28.13
0.787 / 0.279 / 0.376 / 2.11 / 78.71 / 72.83 / 0.145 / 28.33
0.903 / 0.583 / 0.783 / 1.66 / 100.17 / 80.13 / 0.301 / 28.50
1.000 / 9.120 / 9.120 / 1.16 / 143.17 / 3.840 / 28.87

Table S2Experimental and ideal CMC (Cm, Ci), surface excess concentration (max), experimental and ideal values of minimum area per molecule (Amin, Aidmin), surface concentration (C20) and surface pressure at CMC (CMC) of the binary mixtures of P105 with dimeric/monomeric surfactants versus the mole fraction of dimeric/monomeric surfactant (α) at 318.15 K

 / Cm*102
(mmol·dm-3) / Ci*102
(mmol·dm-3) / max*106(mol·m-2) / Amin
(Å2) / Aidmin
(Å2) / C20
(mmol·dm-3) / CMC
(mN·m-1)
10-2-10
0.000 / 0.051 / 0.051 / 3.46 / 48.00 / 0.026 / 28.22
0.156 / 0.046 / 0.062 / 4.25 / 39.10 / 62.44 / 0.028 / 22.78
0.356 / 0.061 / 0.083 / 3.78 / 43.92 / 56.49 / 0.035 / 23.38
0.480 / 0.077 / 0.101 / 3.60 / 46.13 / 59.89 / 0.042 / 24.32
0.625 / 0.107 / 0.143 / 3.16 / 52.50 / 63.29 / 0.059 / 25.04
0.787 / 0.158 / 0.245 / 1.92 / 86.26 / 68.39 / 0.078 / 24.85
0.903 / 0.265 / 0.523 / 1.51 / 110.19 / 70.09 / 0.096 / 24.51
1.000 / 595.000 / 595.000 / 1.25 / 132.98 / 134.500 / 28.98
12-2-12
0.000 / 0.052 / 0.052 / 3.46 / 48.00 / 0.026 / 28.22
0.156 / 0.055 / 0.062 / 3.70 / 44.89 / 52.63 / 0.031 / 20.27
0.356 / 0.064 / 0.083 / 3.16 / 52.47 / 60.05 / 0.035 / 23.49
0.480 / 0.092 / 0.101 / 1.54 / 107.89 / 61.90 / 0.049 / 24.06
0.625 / 0.107 / 0.143 / 2.41 / 68.94 / 61.90 / 0.055 / 23.65
0.787 / 0.209 / 0.242 / 1.83 / 90.86 / 60.98 / 0.092 / 24.32
0.903 / 0.450 / 0.518 / 1.27 / 130.84 / 62.83 / 0.199 / 24.00
1.000 / 78.300 / 78.300 / 1.18 / 140.72 / 28.500 / 21.78
14-2-14
0.000 / 0.052 / 0.052 / 3.46 / 48.00 / 0.026 / 28.22
0.156 / 0.057 / 0.062 / 4.11 / 40.40 / 68.14 / 0.029 / 20.40
0.356 / 0.069 / 0.076 / 4.68 / 35.49 / 67.36 / 0.042 / 22.83
0.480 / 0.074 / 0.100 / 3.42 / 48.59 / 67.36 / 0.065 / 24.42
0.625 / 0.108 / 0.149 / 2.61 / 63.60 / 68.91 / 0.084 / 23.75
0.787 / 0.222 / 0.244 / 2.06 / 80.77 / 71.24 / 0.180 / 23.19
0.903 / 0.433 / 0.521 / 1.66 / 99.78 / 75.88 / 0.415 / 22.82
1.000 / 13.100 / 13.100 / 1.32 / 125.48 / 5.800 / 34.17
DTAB
0.000 / 0.052 / 0.052 / 3.46 / 48.00 / 0.095 / 28.22
0.156 / 0.051 / 0.061 / 4.22 / 39.33 / 63.01 / 0.025 / 24.50
0.356 / 0.060 / 0.080 / 5.37 / 30.93 / 56.83 / 0.032 / 25.57
0.480 / 0.098 / 0.101 / 3.73 / 44.48 / 60.36 / 0.053 / 26.84
0.625 / 0.107 / 0.139 / 3.88 / 42.82 / 63.90 / 0.079 / 26.05
0.787 / 0.199 / 0.227 / 3.19 / 52.08 / 69.20 / 0.152 / 25.59
0.903 / 0.428 / 0.517 / 1.86 / 89.12 / 70.96 / 0.342 / 26.79
1.000 / 1583.000 / 1583.000 / 1.22 / 136.34 / 602.300 / 24.34
TTAB
0.000 / 0.052 / 0.052 / 3.46 / 48.00 / 0.095 / 28.22
0.156 / 0.058 / 0.061 / 4.31 / 38.50 / 55.80 / 0.032 / 22.80
0.356 / 0.069 / 0.079 / 3.92 / 42.30 / 61.65 / 0.042 / 23.43
0.480 / 0.090 / 0.100 / 3.63 / 45.67 / 57.75 / 0.059 / 24.31
0.625 / 0.118 / 0.137 / 4.26 / 38.97 / 59.70 / 0.094 / 23.95
0.787 / 0.195 / 0.239 / 3.19 / 52.08 / 64.58 / 0.184 / 24.31
0.903 / 0.528 / 0.640 / 1.45 / 114.18 / 69.46 / 0.442 / 24.41
1.000 / 412.400 / 412.400 / 1.14 / 145.56 / 204.800 / 25.33
CTAB
0.000 / 0.052 / 0.052 / 3.46 / 48.00 / 0.095 / 28.22
0.156 / 0.053 / 0.061 / 4.17 / 39.84 / 55.94 / 0.029 / 24.09
0.356 / 0.064 / 0.080 / 4.65 / 35.69 / 62.76 / 0.032 / 25.23
0.480 / 0.088 / 0.099 / 3.75 / 44.32 / 67.30 / 0.049 / 24.74
0.625 / 0.114 / 0.138 / 3.08 / 53.89 / 69.57 / 0.066 / 24.99
0.787 / 0.174 / 0.234 / 2.27 / 73.01 / 68.43 / 0.090 / 25.81
0.903 / 0.496 / 0.556 / 1.51 / 110.15 / 66.16 / 0.230 / 25.35
1.000 / 91.400 / 91.400 / 1.03 / 161.55 / 40.500 / 26.42

Table S3Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, free energy of adsorption (ΔGoads), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of P105 with dimeric/monomeric surfactants versus the mole fraction of dimeric/monomeric surfactant (α) at 308.15 K

 / ΔGom
(kJ·mol-1) / ΔHom
(kJ·mol-1) / ΔSom
(J·mol-1·K-1) / ΔGoads
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
10-2-10
0.156 / -38.73 / 265.89 / 988.56 / -45.15 / -13.27 / -32.27
0.356 / -38.16 / 259.65 / 966.47 / -45.22 / -12.88 / -33.12
0.480 / -37.53 / 258.00 / 959.07 / -45.56 / -11.70 / -32.29
0.625 / -37.19 / 264.39 / 978.70 / -51.73 / -13.13 / -34.93
0.787 / -35.88 / 258.39 / 954.97 / -50.98 / -12.08 / -34.57
0.903 / -33.97 / 276.00 / 1005.93 / -51.38 / -11.00 / -34.45
12-2-12
0.156 / -38.83 / 268.97 / 998.88 / -46.59 / -9.75 / -32.12
0.356 / -38.49 / 263.92 / 981.38 / -46.61 / -9.65 / -32.98
0.480 / -37.82 / 255.31 / 951.29 / -48.09 / -8.94 / -32.97
0.625 / -36.86 / 252.16 / 937.92 / -50.43 / -8.19 / -32.93
0.787 / -35.65 / 228.16 / 856.13 / -56.87 / -7.55 / -33.06
0.903 / -34.03 / 201.31 / 763.75 / -50.89 / -7.19 / -33.89
14-2-14
0.156 / -39.27 / 246.23 / 926.52 / -45.14 / -7.00 / -32.71
0.356 / -38.28 / 223.97 / 851.05 / -43.52 / -4.12 / -31.00
0.480 / -38.19 / 219.23 / 835.39 / -47.10 / -5.49 / -32.74
0.625 / -37.64 / 198.47 / 766.23 / -48.35 / -5.43 / -33.34
0.787 / -37.42 / 164.68 / 655.87 / -50.81 / -6.44 / -34.89
0.903 / -35.68 / 131.05 / 541.10 / -51.14 / -5.24 / -34.74
DTAB
0.156 / -38.72 / 273.39 / 1012.85 / -44.78 / -14.93 / -32.20
0.356 / -38.35 / 277.34 / 1024.47 / -45.04 / -15.32 / -34.05
0.480 / -37.55 / 269.92 / 997.81 / -45.81 / -13.42 / -32.31
0.625 / -36.73 / 273.08 / 1005.37 / -46.71 / -12.45 / -31.84
0.787 / -35.62 / 269.52 / 990.24 / -50.92 / -13.16 / -33.81
0.903 / -33.71 / 267.32 / 976.87 / -46.08 / -11.99 / -33.50
TTAB
0.156 / -38.79 / 265.89 / 988.75 / -45.90 / -12.30 / -32.10
0.356 / -38.35 / 266.05 / 987.83 / -46.34 / -12.41 / -33.56
0.480 / -37.69 / 268.02 / 992.11 / -44.81 / -11.22 / -32.72
0.625 / -36.88 / 265.00 / 979.66 / -46.01 / -10.49 / -32.55
0.787 / -35.35 / 260.63 / 960.49 / -49.31 / -09.03 / -31.78
0.903 / -33.58 / 234.90 / 871.28 / -51.55 / -08.74 / -32.57
CTAB
0.156 / -39.27 / 260.52 / 972.89 / -45.81 / -11.33 / -33.95
0.356 / -38.10 / 256.89 / 957.32 / -44.63 / -8.09 / -31.58
0.480 / -37.80 / 246.76 / 923.45 / -45.37 / -8.57 / -32.66
0.625 / -37.59 / 246.08 / 920.55 / -46.92 / -9.60 / -34.59
0.787 / -35.95 / 231.71 / 868.60 / -49.38 / -8.01 / -33.74
0.903 / -34.12 / 193.50 / 738.67 / -51.31 / -7.03 / -33.80

Table S4Standard free energy (ΔGom) enthalpy and entropy (ΔHom, ΔSom) of micellization, free energy of adsorption (ΔGoads), Maeda’s interaction parameter and free energy (B1, ΔGoMaeda) of binary mixtures of P105 with dimeric/monomeric surfactants versus the mole fraction of dimeric/monomeric surfactant (α) at 318.15 K

 / ΔGom
(kJ·mol-1) / ΔHom
(kJ·mol-1) / ΔSom
(J·mol-1·K-1) / ΔGoads
(kJ·mol-1) / B1 / ΔGoMaeda
(kJ·mol-1)
10-2-10
0.156 / -46.14 / 283.43 / 1035.90 / -51.50 / -19.09 / -41.70
0.356 / -45.41 / 276.77 / 1014.98 / -51.60 / -20.07 / -44.72
0.480 / -44.85 / 275.01 / 1005.40 / -51.61 / -19.43 / -44.52
0.625 / -44.03 / 281.83 / 1024.25 / -51.95 / -18.63 / -44.28
0.787 / -43.06 / 275.43 / 1001.12 / -55.98 / -19.07 / -46.13
0.903 / -41.78 / 294.20 / 1056.07 / -58.05 / -19.38 / -47.89
12-2-12
0.156 / -45.66 / 286.71 / 1044.72 / -51.14 / -15.03 / -41.34
0.356 / -45.28 / 281.33 / 1027.79 / -52.71 / -15.29 / -43.20
0.480 / -44.39 / 272.15 / 994.97 / -60.03 / -12.86 / -40.60
0.625 / -44.03 / 268.78 / 983.25 / -53.85 / -14.44 / -43.60
0.787 / -42.37 / 243.40 / 897.62 / -55.68 / -12.09 / -41.36
0.903 / -40.47 / 214.59 / 801.72 / -59.34 / -10.97 / -41.10
14-2-14
0.156 / -45.57 / 262.48 / 968.26 / -50.54 / -10.54 / -39.92
0.356 / -45.12 / 238.74 / 893.67 / -50.00 / -10.09 / -40.35
0.480 / -44.94 / 233.69 / 875.82 / -52.09 / -11.30 / -42.68
0.625 / -44.01 / 211.56 / 803.31 / -53.10 / -10.54 / -42.65
0.787 / -42.22 / 175.54 / 684.49 / -53.50 / -07.84 / -40.11
0.903 / -40.56 / 131.05 / 566.60 / -54.28 / -07.92 / -41.48
DTAB
0.156 / -45.86 / 291.42 / 1060.15 / -51.66 / -22.14 / -43.31
0.356 / -45.45 / 295.63 / 1073.37 / -50.21 / -22.05 / -44.85
0.480 / -44.26 / 287.72 / 1043.47 / -51.45 / -17.66 / -39.68
0.625 / -44.02 / 291.09 / 1053.31 / -50.74 / -20.58 / -44.44
0.787 / -42.50 / -287.30 / 1036.62 / -50.53 / -18.58 / -42.54
0.903 / -40.60 / 284.94 / 1023.23 / -54.98 / -18.05 / -43.30
TTAB
0.156 / -45.53 / 283.43 / 1033.99 / -50.82 / -17.13 / -40.07
0.356 / -45.11 / 283.60 / 1034.79 / -51.08 / -17.51 / -41.86
0.480 / -44.47 / 285.70 / 1037.79 / -51.16 / -16.81 / -41.72
0.625 / -43.78 / 282.48 / 1025.52 / -49.40 / -16.49 / -42.06
0.787 / -42.55 / 277.82 / 1006.97 / -50.17 / -16.44 / -43.23
0.903 / -41.08 / 250.39 / 0912.99 / -58.87 / -14.95 / -42.81
CTAB
0.156 / -45.76 / 277.71 / 1016.73 / -51.54 / -15.81 / -41.88
0.356 / -45.29 / 273.84 / 1004.57 / -50.72 / -15.44 / -42.89
0.480 / -44.50 / 263.03 / 0966.64 / -51.10 / -13.55 / -41.06
0.625 / -43.87 / 262.31 / 0962.39 / -51.98 / -13.97 / -42.48
0.787 / -42.83 / 246.99 / 0910.96 / -54.17 / -13.86 / -43.42
0.903 / -40.23 / 206.26 / 0774.77 / -57.05 / -11.19 / -41.16

Fig.S1.Plots of βσavgversus m for the binary mixtures of P105with dimeric (full lines)

and monomeric (dotted lines) surfactantsat (♦) 298.15, (■) 308.15 and (▲)

318.15 K.

Fig.S2.r for the binary mixture of P105 withTTAB at (♦) 298.15 K, (■) 308.15 K

and(▲) 318.15 K.

Fig.S3.r for the binary mixture of P105 with CTAB at (♦) 298.15 K, (■) 308.15 K and

(▲) 318.15 K.

S1