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1.IDENTIFICATIONOFPRODUCTCOMPANYPRODUCTNAME2-packPrimer
INTENDEDUSEAutomotive Re-finishForProfessionalUseONLY.
DETAILOFCOMPANYMK1 Paints 58Perry Street, Wednesbury, West Midlands,WS10OAZ. Emergency Tele. 0121 5020050
2.COMPOSITION/INFORMATIONONINGREDIENTS.
Substancespresenting ahealthhazardwithinthe meaning ofthe Chemicals (Hazard Information &Packaging)Regulations 1993.
SubstanceName / CAS No. / EINEC No. / Conc..Range / Symbols / Risk Phrases*BUTYL ACETATE XYLENE,MIXTUREOFISOMERS 1,2,4-TRIMETHYLEBENZINE SOLVENTNAPTHA
METHYL ISOBUTYLE KETONE ETHYLETHOXYPROPIONATE / 123-86-4 1330-20-7 95-63-6 64742-95-6 108-10-1 763-69-9 / 123-86-4 215-535-7
265-150-3 203-550-1 212-112-9 / 10-20 5-101-10 10-20 5-105-10 / Xn Xn,Xi X,n Xn,n Xn,F / 10-66-67 20/21-38
20,36/37/38,51/53 65,66,67,51/53
11-20-36/37-66 52/53
T+=VeryToxicT=ToxicXn=HarmfulC=CorrosiveXi=IrritantE=ExplosiveO=OxidisingF+=ExtremelyFlammable F=Highly Flammable N=Environmentally Hazardous
*Fordetails of Risk Phrases seeSection 16 3.HAZARDSIDENTIFICATION. HAZARDS
FlammableHarmfulIrritant to eyes RISKS
Highly Flammable
Harmful by inhalation, incontact with skin and may causelung damage if swallowed. Irritationtorespiratory systemeyes and skin
Harmful to aquatic organisms, may causelong-termadverseeffects inaquatic environment
Inhalationofvapoursfromthisproductcancausenarcosisand,withcontinuedexposureabovetheOEL,possiblelong termeffects.
4.FIRSTAIDMEASURESGENERAL
Inallcasesofdoubtorwhensymptomspersistseekmedicalattention.Nevergiveanythingbymouthtoanunconscious person.
INHALATION.
Movetheexposedpersontofreshairkeepwarmandatrest.Ifbreathingisirregularorhasstoppedgiveartificial respiration. Givenothing by mouth ifunconscious placeinrecovery position andseekmedical advice.
INGESTION
If accidentally swallowedobtainmedical attention.Keep at rest DONOTinduce vomiting. SKIN
Removecontaminatedclothing.Washskinthoroughlywithsoapandwateroruseaproprietaryskincleaner.DoNOT useSolvent or Thinners.Obtain medical adviceshould blistering orrednesspersist.
EYES.
Contactlensesshouldberemoved.Irrigatecopiouslywithclean,freshwaterforatleast10minutesholdingtheeyelids apart; seek medical advice should sorenessorrednesspersist.
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5.FIREFIGHTINGMEASURES. EXTINGUISHINGMEDIA.
RECOMMENDEDCarbon-Dioxide,Dry Powder,Sand, Foam. DONOTUSEWater
ThismaterialisFlammable.UsealcoholresistantfoamUsedrychemicalorcarbondioxide.Keepcontainersand surroundingscool with water spray.
SPECIALINSTRUCTIONSTOFIREFIGHTINGPERSONNEL
Wearprotectiveclothingandself-containedbreathingapparatus.Firewillproducedenseblacksmokecontaining hazardous productsofcombustion.Decompositionofproducts may causea hazard tohealth.Coolclosedcontainers exposedtofirewithawaterspray.DonotallowrunofffromthefirefightingtoenterdrainsorwatercoursesVapours can travela considerabledistance toa sourceofignition and flashback.
6.ACCIDENTALRELEASEMEASURES. SPILLCLEANUPMETHODS
Excludesourcesofignitionandventilatearea.Excludenon-essentialpersonnel.Avoidbreathingvapours.Refertoprotective measureslistedinSection78.Containandcollectanyspillagewithnon-combustibleabsorbentmateriale.g.sand,earthor otherinertmaterialandplaceinasuitablecontainerfordisposalinaccordancewithwasteregulations.DoNotallowtoenter drainsorwatercourses.Ifit doesthelocalwatercompanyshouldbenotifiedimmediately,incaseofcontaminationofstreams, riversorlakes TheNational Rivers Authority.Clean preferably with adetergent, avoid useofsolvents.
7.HANDLINGSTORAGE
HANDLING:PRECAUTIONS:Useinwellventilatedare.Avoidinhalingvapour.Avoidcontactwitheyes,skinand clothing.Keepcontainertightlyclosedwhennotinuse.Vapoursareheavierthanairandmayspreadalongfloors,theymay formexplosivemixtureswithair.Preventthecreationofflammableorexplosiveconcentrationsofvapourinairandavoid vapourconcentrationshigherthantheoccupationalexposurelimits.Additionally,theproductshouldonlybeusedinareas fromwhichallnakedlightsandothersourcesofignitionhavebeenexcluded.Electricalequipmentshouldbeprotectedtothe appropriatestandard.Excludesourcesofheat,sparksandopenflame.Nonsparkingtoolsshouldbeused.Smoking,eating anddrinkingshouldbeprohibitedinareaofstorageanduse.Neverusepressuretoempty,thecontainerisnotapressure vessel.
STORAGEPRECAUTIONS:Storeinaccordancewiththeconditionsofthelicence,whichisnecessaryunderthePetroleum (Consolidation)Act.SeetheHSEguidancenoteforStorageofFlammableLiquidsinContainers.Observethelabel precautions.Upto50litresofsuchflammableliquidsmaybekeptinaworkroomprovidedtheyarekeptinaseparate storeroomconformingtothestructuralrequirementsoftheregulations.Storeawayfromsourcesofheatandignition.And directsunlight.NoSmoking.Storebetween5-25deg.Cinadryventilatedareas.Preventunauthorisedaccesscontainers, whichareopened,shouldbeproperlyresealed andkeptuprighttopreventleakage.Storeseparately from oxidisingagents and stronglyalkalineandacidicmaterials..TheprinciplescontainedintheHSE’sGuidancenoteStorageofPackagedDangerous Substancesshould beobserved whenstoring this product.
8.EXPOSURECONTROLSANDPERSONALPROTECTIONSubstanceName / LTEL / STEL / Notes*
ppm / mgm/m3 / p.p.m / mgm/m3
NBUTYLACETATEXYLENE,MIXTUREOFISOMERS1,2,4-TRIMETHYLEBENZINESOLVENTNAPTHA
METHYLISOBUTYLEKETONE
ETHYLETHOXYPROPIONATEACETATE. / 15010025
50 / 710435 / 200150125200
100 / 950650545 / Sk,OESSk,OESOES
OEL
NOTES
LT =LongTermExposureLimit - 8 hour time weighted average. ST =Short TermExposure Limit - 10minute referenceperiod.
Notations =Sk- Risk ofabsorptionthrough skin. Sen -respiratorysensitizer.
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OES= Occupational ExposureStandard. MEL = MaximumExposureLimit
OEL’sarefromEH40 exceptwheremarkedSUP, which areassignedby thesupplier ofthe substance. EngineeringMeasures
Provideadequateventilation.Wherereasonablypracticablethisshouldbeachievedbytheuseofdilutionandlocalexhaust ventilationandgoodgeneralextraction.Ifextractionmethodsareinsufficienttomaintainconcentrationsofparticulateand/or solvent vapours belowrelevant OEL’s,suitable respiratory protective equipment should beworn.
General
Personswithahistoryofasthma,allergiesorchronicorrecurrentrespiratorydiseaseshouldonlybeemployedinprocessesin which this product is usedunderappropriate medical supervision.
Skincontactconstitutesthemostpronouncedhazard.Personswithahistoryofskinsensitisationproblemsshouldonlybe employed inprocessesinwhich this product is usedunderappropriate medical supervision.
GeneralProtection
HandProtection:
Eyeprotection:
RespiratoryEquipment:
SkinProtection:
All ppe, including rpe, used tocontrolexposure to hazardoussubstancesmust be selected to meet therequirements of the COSHHregulations.
Polyvinyl acetate gloves.Seek relevant advice fromGloveManufacturer. Barrier cream may be ofhelp but it shouldnot beapplied afterexposurehas occurred.
Eye protection designedto protect against chemical liquid splashes shouldbe worn.
Respiratory protection should be wornifthereis ariskofexposuretohighvapour concentrations.
Cotton orcotton/synthetic overalls arenormallysuitable.
HygienicWorkRoutines:Washattheendofeachwork shiftand beforeeating,smokingandusingthetoiletWash promptlyifskinbecomeswetorcontaminated.Removeanycontaminatedclothingat once.Useappropriateskincreamtopreventdryingofskin.Noeating,smokingor drinkingwhile workingwiththismaterial.DONOTSMOKE INWORKAREA!
9.PHYSICALCHEMICALPROPERTIES.
PHYSICALSTATE:Free Flowing liquid COLOURLight GreyFLASHPOINT29C
LOWEREXPLOSIONLIMIT.8%vol SOLUBILITYINWATERImmiscible VAPOURDENSITY Heavierthan air SPECIFICGRAVITY 1.5-+ 0.50gcm VOCCONTENT 0.43 Kgs/Lt
10.STABILITYREACTIVITY.
Stable undertherecommendedstoragehandlingconditions(seeSect.7).In afire, hazardousdecompositionproductssuchas smoke,carbonmonoxide,carbondioxide,andoxidesornitrogenmaybeproduced.Keepawayfromoxidisingagentsand strongly alkaline and acid materials toprevent the possibility ofexothermic reaction.
11.TOXICOLOGICALINFORMATION.
There is nodata available on theproduct itself.Respiratoryexposure may cause acuteirritation &/orsensitisation of
Therespiratorysystemresultinginasthmaticsymptoms.Repeatedexposuremayleadtopermanentrespiratorydisability. Exposuretoorganicsolventvapoursmayresultinadversehealtheffectssuchasirritationofthemucousmembraneandthe respiratorysystemandadverseeffectsontherenalandcentralnervoussystem.Symptomsincludeheadache,dizziness, fatigue, muscularweakness,drowsinessandin extreme cases,lossofconsciousness.
Repeatedorprolongedcontactwiththeproductmayleadtotheremovalofnaturalfatsfromtheskinresultinginnon-allergic contact dermatitisandabsorption throughtheskin.Splashesin theeyes may cause irritation and reversiblelocaldamage.
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12.ECOLOGICALINFORMATION
Theproductshouldnotbeallowedtoenterdrainsorwatercoursesorbedepositedwhereitcanaffectgroundorsurface waters.TheAirPollutionControl requirements ofregulations madeundertheEnvironmentalProtection Actmayapply to the useofthis product
13.DISPOSALCONSIDERATIONS.
Donotallowintowatercoursesordrainsordisposeofwheregroundorsurfacewatersmaybeaffected.Wastesincluding emptiedcontainers,arecontrolledwastesandshouldbedisposedofinaccordancewithregulationsmadeundertheControlof PollutionActandtheEnvironmentalProtectionAct.(Usingtheinformationprovidedinthissafetydatasheet,adviceshould be obtained fromthe Waste Regulation Authority whether theSpecial Waste regulations apply)
14.TRANSPORTINFORMATIONDomesticRoad/Rail
Road/Rail (RID/ADR) UNNumber
PackingGroup Class
Designation
1263 III
3.3
Paint related material
Sea
PackingGroup=30lts PackingGroup 30lts.
MarinePollutant... Main Risk... ShippingName..
1263 IIIIII
No Flammable
.Paint Related Material
Air
UN/IATAID Number.1263 PackingGroup=30lts III PackingGroup 30lts. III Class 3.3
Shipping Name.Paint Related Product Main Risk... Flammable
SubRiskNarcosis
InternationalRoad/Rail
ItemNumber31C Class3.3 Packing Group.. .III UNNumber...1263
Main Risk...Flammable SubRiskNarcosis
Chemical Name.. Paint Related Products
NOTE:Theaboveregulatory prescriptionsarethosevalid onthedateofpublicationof thissheet.
Giventhepossibleevolutionof transport regulations for hazardousmaterials,it wouldbe advisableto check their validity.
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15.REGULATORYINFORMATION
ThisproductisclassifiedandlabelledforsupplyinaccordancewiththeChemicals(HazardInformationandPackaging) Regulations as follows:
Classification
Flammable
Contains
RiskPhrases
SafetyPhrases
“P”Phrases
StatutoryInstruments
ApprovedCodeofPractise
GuidanceNotes
Harmful
BUTYL ACETATE
XYLENE, MIXTURE OF ISOMERS 1,2,4-TRIMETHYLEBENZINE SOLVENT NAPTHA
METHYL ISOBUTYLE KETONE ETHYL ETHOXY PROPIONATE
R10Flammable.
R11Highly flammable
R20/2Harmful by inhalationandincontact with skin R38Irritating toskin
S2Keepoutofreachofchildren S25Avoidcontact with eyes.
Donot breathe vapourorspray
FORUSEININDUSTRIAL INSTALLATIONSONLY
Chemicals(HazardInformationandPackaging)Regulations.ControlofSubstances Hazardous toHealth
Classification andLabelling ofSubstances and Preparations Dangerousfor Supply.
OccupationalExposureLimitsEH40,IntroductiontoLocalExhaustVentilationHS (G)37. CHIPfor everyoneHSG(108).
TheinformationcontainedinthisSafetyDataSheetdoesnotconstitutetheuser’sownassessmentoftheworkplacerisksas requiredbyotherHealthSafetylegislation.TheprovisionsoftheHealthSafetyatWorketc.ActandtheControlof Substances Hazardoustohealthregulationapply to theuseof this productatwork.
16.OTHERINFORMATION.
TheinformationcontainedinthisSafetyDataSheetisprovidedinaccordancewiththerequirementsoftheChemicals(Hazard InformationandPackaging)Regulations.TheproductshouldnotbeusedforpurposesotherthanthoseshowninSection1 withoutfirstreferringtothesupplierandobtainingwritteninstructions.Asthespecificconditionsofuseoftheproductare outsideofthesupplier’scontrol,theuserisresponsibleforensuringthattherequirementsofrelevantlegislationarecomplied with.Theinformationgivenisbasedonthepresentstateofknowledgeandcurrentnationallegislationandsupersedesall SafetyDataSheetsissuedpriortotheissuedate.Itprovidesguidanceonhealth,safetyandenvironmentalaspectsofthe productsandshould notbe construedas any guaranteeoftechnical performance or suitability for particular applications.
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Furtherinformation andrelevant advicecanbefound in: -
The control ofsubstancesHazardous toHealthRegulations 1988(S11988:1657) TheManual HandlingOperations Regulations 1992 (SI:1992)
Storage of Flammable Liquidsin Containers HS(G)51 Storage of PackagedDangerousSubstances HS(G)71
The Environmental Protection(Duty ofCare)Regulations 1992 (SI 1988:2839)
TextofRiskPhrasesListedinSection2
R10R11R20R20/21
R20/21/22R23
R36R36/37/38R38
R42R42/43R43R51/53
R66R67
Flammable.Highly flammable.
Harmfulbyinhalation.
Harmfulbyinhalationandincontactwithskin.
Harmfulbyinhalationandincontactwithskinandifswallowed.Toxicbyinhalation.
Irritatingtoeyes.
Irritatingtoeyes,respiratorysystemandskin.Irritatingtoskin.
Maycausesensitisationbyinhalation.
Maycausesensitisationbyinhalationandskincontact.Maycausesensitisationbyskincontact
Toxictoaquaticorganisms,maycauselong-termadverseeffectsintheaquaticenvironment
RepeatedexposuremaycauseskindrynessorcrackingVapoursmaycausedrowsinessanddizziness.