SafetyDataSheet

CM GREEN MIX 4-2-2

SDSNumber: / 305-O / Revision: / Jan 3, 2016
Section1: / IDENTIFICATION

ProductName:CM GREEN MIX 4-2-2

OtherIdentification:

ChemicalFamily:Mixture of liquid micronutrients

RecommendedUse ofChemical:AgriculturalIndustry–Fertilizeruse

Manufacturer:CUSTOM AG FORMULATORS, INC

3430 S. Willow Ave

Fresno, CA 93725

Information:(559) 435-1052

Emergency Contact:CUSTOM AG FORMULATORS, Inc.(800)355-4457

CHEMTREC(800)424-9300 Domestic

Section2:HAZARD(S)IDENTIFICATION

Hazard Classification:

Acute Tox.Category 4 (Oral)

Eye Dam. Category 2

Specific target organ toxicity, repeated exposureCategory 2

Hazardous to the aquatic environment, acute hazardCategory 3

Hazardous to the aquatic environment, long-term hazardCategory 3

Symbol(s):

SignalWord:WARNING

Hazard Statement(s):Harmful if swallowedCauses serious eye irritation. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life. Harmful to aquatic life with long lasting effects.

Precautionary statements (GHS-US): Wash Skin thoroughly afterhandling

Do not eat,drink or smoke when using this product

Do not breathe mist or vapor.

Wear eye protection protective gloves

Ifswallowed: Call a doctor if you feel unwell

Ifin eyes: Rinse cautiously with water forseveral minutes. Remove contact lenses, if present and easy todo. Continue rinsing

Collect spillage and store away from incompatible materials.

Dispose ofcontents/container toan authorized waste collection point

Section3:COMPOSITION/INFORMATIONonINGREDIENT

ChemicalIngredients:(SeeSection8forexposureguidelines)

Chemical / Synonym CommonName / CAS No. / EINECSNo. / % byWt.
Ferrous Sulfate
Zinc sulfate
Manganese Sulfate
Other components below reportable levels / N/A
N/A
N/A
N/A / 7782-63-0
7733-02-0
77-92-9 / N/A
N/A
N/A / Proprietary
Proprietary
Proprietary
TOTALS TO
100%

Section4:FIRSTAID MEASURES

Symptoms/Effects:

Acute:Eyecontactmaycauseeyeirritation.Repeatedor prolonged skincontactmay causeskinirritation. Ingestion mayirritatethegastrointestinal tract.

Chronic:No known chroniceffects.

Eyes:Immediatelyflushwith largequantitiesofwaterfor15minutes.Holdeyelids apart duringirrigationtoensurethoroughflushingof theentirearea of theeyeandlids. Get medical attention if irritation develops and persists.

Skin:Immediatelyflushwith largequantitiesofwater. Removecontaminatedclothing underasafetyshower. Continuerinsing. Obtainmedical attentionifirritation occurs.

Ingestion:Rinse mouth. If vomiting occurs, keep head low so that stomach content doesn’t get into the lungs. Obtainmedical attention if you feel unwell.

Inhalation:Removevictimfromcontaminatedatmosphere. If breathingislabored, administer oxygen.If breathinghas ceased, clear airwayandstart CPR.Obtainmedical attention.

CM GREEN MIX 4-2-2

Section5:FIREFIGHTINGMEASURES

FlammableProperties: (SeeSection9for additional flammable properties)

ExtinguishingMedia:

SuitableExtinguishingMedia:Notflammable, usemediasuitablefor combustibles involved infire.

UnsuitableExtinguishingMedia:Noneknown

Protection of Firefighters:

SpecificHazards ArisingfromtheChemical:

Physical Hazards:Heating(flames)ofclosedor sealed containers maycause violentruptureofcontainer dueto thermalexpansionof compressed gases.

ProtectiveEquipmentandPrecautionsforFirefighters:

Firefighters shouldwear self-contained breathing apparatus(SCBA)andfull fire-fightingturnoutgear. Keep containers/storagevesselsinfire area cooled withwater spray.

Section6:ACCIDENTALRELEASE MEASURES

PersonalPrecautions:Usepersonal protectiveequipment specifiedinSection8.

Isolatethehazardarea anddenyentrytounnecessary, untrainedandunprotectedpersonnel.

EnvironmentalPrecautions:Keepoutof“watersoftheUnitedStates”becauseof

potentialaquatic toxicity.

MethodsofContainment:

SmallRelease:Confineandabsorbsmall releaseswithsand, earth or other inertabsorbents.

Large Release:Shut off releaseif safetodoso. Dikespill areawithearth, sandorotherinertabsorbentstopreventrunoff into surfacewaterways (potential aquatic toxicity),stormdrains.

CM GREEN MIX 4-2-2

MethodsforCleanup:

SmallRelease:Shoveluptheabsorbedmaterial andplaceindrums for disposal as achemicalwaste orrecycleasafertilizer as the original productwasintended.

Large Release:Recover asmuchofthe spilled productas possibleusing portable pumpandhoses.Userecoveredmaterialas originallyintended ordispose ofasachemicalwaste. Treat remainingmaterial asasmall release(above).

OtherInformation:Notapplicable

Section7:HANDLINGand STORAGE

Handling:Avoidcontactwith eyes.Use onlyin awell-ventilatedarea.Washthoroughlyafter handling.Avoidprolongedor repeatedcontactwith theskin. Do not breathe mist or vapor.

Storage:Storein well-ventilatedareas.Donotstorecombustibles in theareaofstorage vessels.Keepawayfromanysourcesof heator flame.Storetotesandsmaller containersoutofdirectsunlightatmoderatetemperatures.

Section8:EXPOSURECONTROLS/PERSONALPROTECTION

ExposureGuidelines:

Chemical / OSHAPELs / ACGIHTLVs
TWA / STEL/C / TLV / STEL
Notapplicable

EngineeringControls:Useadequateexhaustventilationtopreventinhalationof product vapors.Keep eyewash/safetyshower inareaswhereproductis commonlyhandled.

CM GREEN MIX 4-2-2

PersonalProtectiveEquipment(PPE):

Eye/FaceProtection:Chemicalgogglesor a faceshield is recommended.

SkinProtection:Neoprenerubberglovesandapron shouldbewornto prevent repeatedor prolonged contactwith theliquid.Washcontaminated clothingprior toreuse.

RespiratoryProtection: Chemical respirator with organic vapor cartridge if there is a risk of exposure exceeding the exposure limits.

HygieneConsiderations: Use of goodindustrial hygiene practicesshouldbefollowed, suchaswashingthoroughlyafter handlingandbeforeeatingor drinking.

Section9:PHYSICALandCHEMICALPROPERTIES

Appearance:Dark brown liquid

Odor:Lignin odor

OdorThreshold:Notdetermined

pH:5.3-5.7

BoilingPoint:212°C

Flash Point:Notapplicable

Evaporation Rate:Notapplicable

Flammability:Notapplicable

Upper/LowerFlammabilityLimits:Notapplicable

VaporPressure:Notdetermined

VaporDensity:Notdetermined

Specific Gravity:10.12 lbs/gallon (typical)

Solubility (inwater):Complete

PartitionCoefficient:Not applicable

Auto-ignitionTemperature:Notapplicable

DecompositionTemperature:500°C

Viscosity:Data not available.

CM GREEN MIX 4-2-2

Section10:STABILITYandREACTIVITY

Reactivity:Avoidinteractionwith heat(flames),oxidizers oracids.

ChemicalStability:This is a stableproductundernormal (ambient)

temperatureandpressureconditions.

Possibilityof Hazardous Reactions:None known

Conditions toAvoid:No additional information.

IncompatibleMaterials:This productis notcompatible withleadormercuryor their alloys.Thesematerials ofconstructionshouldnotbe used inhandlingsystemsor storagecontainers for this product.

HazardousDecompositionProducts:None Known.

Section11:TOXICOLOGICALINFORMATION

NUTRA BUILDER ESTIMATED AS PRODUCT

LD50ORAL: RAT24226 mg/kg estimated

DERMAL: RAT28406 mg/kg estimated

Acute Toxicity: Harmful if swallowed

Dermal:Slightly irritating

Inhalation:Prolonged inhalation may be harmful. May cause damage to organs through prolonged repeated exposure.

Eyes:Causes serious eye irritation

Chronic/Carcinogenicity:Notlisted inNTP, IARC, ACGIH,orbyOSHA.

Teratology:Notdetermined

Reproduction:Notdetermined

Mutagenicity:Notdetermined

CM GREEN MIX 4-2-2

Section12:ECOLOGICAL INFORMATION

12.1 Ecotoxicity:Not determined.

12.2PersistenceDegradability:Notdetermined

12.3BioaccumulativePotential:This productisnotbioaccumulative.

12.4Mobilityin Soil:Notdetermined

12.5OtherAdverse Effects:Notdetermined

Section13:DISPOSALCONSIDERATIONS

Consultfederal,stateandlocal regulationsfordisposal requirements.

Section14:TRANSPORTINFORMATION

14.1BasicShippingDescription:

14.1.1 ProperShippingName:Notregulated by DOT

14.1.2 HazardClasses:Notapplicable

14.1.3 IdentificationNumber:Notapplicable

14.1.4 PackingGroup:Notapplicable

14.1.5 HazardousSubstance:No

14.1.6 MarinePollutant:No

CM GREEN MIX 4-2-2

14.2 AdditionalInformation:

14.2.1OtherDOTRequirements:

14.2.1.1 ReportableQuantity:Notapplicable

14.2.1.2 Placard(s):Notapplicable

14.2.1.3 Label(s):Notapplicable

14.2.2USCGClassification:Class 43,Misc.watersolutions

14.2.3InternationalTransportation:

14.2.3.1IMO:Non-hazardous underIMOregulations.

14.2.3.2IATA:Non-hazardous underIATAregulations.

14.2.3.3TDG (Canada):Non-hazardous underTDGregulations.

14.2.3.4ADR (Europe):Non-hazardous underADRregulations.

14.2.3.5ADG(Australia):Non-hazardous underADGregulations.

14.2.4 EmergencyResponseGuide:Notapplicable

14.2.5 ERAP– Canada:Notapplicable

14.2.6 SpecialPrecautions:None

Section15:REGULATORYINFORMATION

15.1 U.S. FederalRegulations:

15.1.1 OSHA:This productmeets thecriteria oftheFederal

OSHA HazardCommunicationStandard(29CFR

1910.1200).

15.1.2TSCA:Productis not containedinUSEPAToxicSubstance

ControlActInventory.

15.1.3CERCLA:Reportable Quantity –Notapplicable

CM GREEN MIX 4-2-2

15.1.4SARATitle III:

15.1.4.1ExtremelyHazardousSubstance(EHS):
15.1.4.2Section 312(TierII)Ratings: / Notlisted
Immediate(acute) / Yes
Fire
SuddenRelease
Reactivity
Delayed (chronic) / No
No No No
15.1.4.3Section 313(FORMR): / Notapplicable
15.1.5RCRA: / Notapplicable
15.1.6 CAA(Hazardous AirPollutant/HAP): / Notapplicable

15.2 InternationalRegulations:

15.2.1 Canada:

15.2.1.1 WHMIS:Nothazardous

15.2.1.2 DSL/NDSL:Not Applicable.

15.3State regulations:

15.3.1 CAProposition65:NotApplicable

Section16:OTHERINFORMATION

REVISIONS:5/10/2015

PREVIOUS REVISION: 4/1/2015

FURTHER INFORMATION:

The above information is based on data of which the manufacturer is aware and is believed to be correct as of the date hereon. Since the information contained herein may be applied under conditions beyond the manufacturer’s control and which may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, the manufacturer does not assume any responsibility for the results of its use. This information is furnished upon the condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.

CM GREEN MIX 4-2-2