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WHMIS / PersonalProtectionEquipment / TDG(Ground)

Product identifier

Tradename:CanadianCrudeOil

SDSNr:SDS-0001

Chemicaldescription:PetroleumHydrocarbon

CASNo:8002-05-9

EC No:232-298-5

Registration-No:Registrationdeadline notexpired.

Use:Fueloilforheating and power generation.

Companyidentification: FreepointCommodities, LLC

58CommerceRoad

Stamford,Ct.06902

E-Mailaddress(competent person):Lou Santore

LouSantore[]

Emergencytelephonenumber:Withinthe U.S.or Canada:1800 4249300

Outside the U.S. and Canada: +1 703 527 3887(collectcallsaccepted)

MSDSprepared by:PaulePatterson,ENERCONServices, Inc.

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GHSClassification:

Flammable Liquid–Category3SkinIrritation –Category2

EyeIrritation–Category2BAspiration Hazard–Category1Carcinogenicity–Category2

Acute Toxicity - Inhalation–Category4ChronicAquaticToxicity–Category2

GHSLABELELEMENTS

Symbol(s)

SignalWord

Danger

CLPHazardStatements:PHYSICALHAZARDS:

H224:Extremelyflammableliquidandvapor.

.

HEALTHHAZARDS:

H304:Maybefatal ifswallowedand entersairways.H319:Causesseriouseyeirritation.

H336:Maycausedrowsiness or dizziness.H350:Maycausecancer.

H373:Maycausedamageto organs or organ systemsthroughprolongedorrepeated exposure.

EUH066:Repeated exposure maycauseskin dryness or cracking.

ENVIRONMENTALHAZARDS:

H441:Toxic toaquaticlifewithlong lasting effects.

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CLPPrecautionarystatementsPrevention :

P201:Obtain specialinstructionsbefore using.

P210:Keep awayfrom heat / sparks /open flames/ hotsurfaces.Nosmoking.P261:Avoid breathing dust/fume/gas/mist/vapors/spray.

P280: Wear protective gloves / protective clothing / eye protection / faceprotection.

P301+ P310: IF SWALLOWED:Immediatelycall aPOISON CENTER ordoctor/physician.

H304:Maybefatal ifswallowed.

Storage:

P403+P235:Storein a well-ventilatedplace.Keep container tightlyclosed.P405:Storelocked up.

Response :

P301+P310: IFSWALLOWED:Immediatelycall aPOISONCENTER ordoctor/physician.

P331:DoNOTinduce vomiting.

Disposal:

P501:Disposeofcontentsand containerto appropriatewastesite or reclaimer inaccordancewithlocal,state,andnationalregulations.

EC Symbols:

FHighlyflammable.TToxic.

NDangerousfortheenvironment.

EC Classification:

Highlyflammable.Toxic.Carcinogenic,category1. Mutagenic,category2.

EC Risk Phrases:

R10:Flammable

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R20:Harmful byinhalation.R35:Irritating toeyes.

R38:Irritating toskin.

R40:Limitedevidenceofcarcinogeniceffects.

R51/ 53:Toxictoaquaticorganisms.Maycauselong-termadverseeffectsintheaquaticenvironment.

R65:Harmful:maycauselung damageifswallowed.R67:Vaporsmaycausedrowsinessanddizziness.

EC SafetyPhrases:

S53 Avoidexposure.Obtain specialinstructionsbefore use.S16 Keepawayfromsourcesofignition- No smoking.

S29Do notemptyinto drains.

S45Incaseofaccidentorifyoufeelunwell,seekmedicaladviceimmediately(showthelabelwherepossible).

S61Avoidreleasetotheenvironment.Refertospecialinstructions/Safetydatasheets.

CASNumber:8002-05-9

EC Number:232-298-5

MolecularWeight: Notapplicableto mixtures

Component / CASNumber / Percent / Hazardous
DieselFuelOil(HighSulfur) / 8002-05-9 / 99- 100% / Yes

* Total Sulfur: <1.0wt%

FirstAid:Eyes

Incaseofcontactwitheyes,immediatelyflushwithclean,low-pressurewaterforatleast15 min. Holdeyelidsopentoensure adequate flushing.Seekmedicalattention.

FirstAid:Skin

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Removecontaminatedclothing.Flushcontaminatedareasforatleast15minutes.Washcontaminatedareasthoroughlywithsoapandwaterorwaterlesshandcleanser.Obtain medicalattentionifirritation or rednessdevelops.

FirstAid:Ingestion

DONOTINDUCEVOMITING.Donotgiveliquids.Obtainimmediatemedicalattention.Ifspontaneousvomitingoccurs,leanvictimforwardtoreducetheriskofaspiration.Monitorforbreathingdifficulties.Smallamountsofmaterialwhichenterthemouthshould berinsed outuntil the tasteisdissipated.

FirstAid:Inhalation

Keepvictimcalm.Removepersontofreshair.Ifpersonisnotbreathing,provideartificialrespiration.Ifnecessary,provideadditionaloxygenoncebreathingisrestorediftrained todoso.Seekmedicalattentionimmediately.

GeneralFire Hazards

See Section9for FlammabilityProperties.

Useself-containedbreathingapparatusinenclosedareas.For massivefires,useunmannedhoseholdersormonitornozzles.Ifthisisimpossible,withdrawfromareaandletfire burn.Always stayawayfromtanksengulfedin fire.

UnusualFire orExplosionHazards

Keepawayfromheat,sourcesofignitionandstrongoxidizers.Thismaterialcanreactviolentlywithoxidizing agents.

HazardousCombustionProducts

Fumes,smoke,carbonmonoxide,sulfuroxides,aldehydesandotherdecomposition products,inthecaseofincompletecombustion.

ExtinguishingMedia

SMALL FIRES: Any extinguisher suitable for Class B fires, Foam, Carbon

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Theuseofself-containedbreathingapparatusandprotectiveclothingisrecommendedforfirefighters.Avoidinhalationofvapors.

LARGEFIRES:Foam,CarbonDioxide,DryChemical,Halon,andWaterFog.Watermaybeineffectiveforfightingthefire,butmaybeusedtocoolfire-exposedcontainers.Watermaysplashandspreadflamingliquid.Avoidspreadingburningliquidwithwaterusedforcoolingpurposes.Donotflushdownpublicsewers.Theuseofself-containedbreathingapparatusandprotectiveclothingisrecommendedforfirefighters.Avoidinhalationofvapors.

UnsuitableExtinguishingMedia

Waterdirectedatsource.

FireFightingEquipment/Instructions

Smallfiresintheincipient(beginning)stagemaytypicallybeextinguishedusinghandheldportablefireextinguishersandotherfirefightingequipment.Firefightingactivitiesthatmayresultinpotentialexposuretohighheat,smokeortoxicby-productsofcombustionshouldrequireNIOSH/MSHA-approvedpressure-demandself-containedbreathingapparatuswithfullfacepieceandfullprotectiveclothing.Isolateareaaroundcontainer involvedin fire.

Cooltanks,shells,andcontainersexposedtofireandexcessiveheatwithwater.Formassivefirestheuseofunmannedhoseholdersormonitornozzlesmaybeadvantageoustofurtherminimizepersonnelexposure.Majorfiresmayrequirewithdrawal,allowingthetanktoburn.Largestoragetankfirestypicallyrequirespeciallytrainedpersonnelandequipmenttoextinguishthefire,oftenincludingtheneedforproperlyappliedfirefightingfoam.

RecoveryandNeutralization

Danger,Flammable,eliminateallignitionsources.Equipmentusedinspillcleanupmustbegroundedtopreventsparking.Prevententryintowaterways,sewers,andconfinedareas.Carefullycontainandstopthesourceofthespill,ifsafetodoso.

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Materials andMethodsforClean-Up

Takeupwithsandor other oilabsorbingmaterials.Carefullyshovel, scooporsweepupintoa waste container,sealtightlyfor proper disposal or reclamation.

EmergencyMeasuresSmallSpills:

Evacuatenonessentialpersonnelandremoveorsecureallignitionsources.Evaluatethe direction ofproducttravel,diking,sewers, etc. toconfirmspillareas.

LargeSpills(> 55gallons):

Isolatethehazardareaatleast150feetinalldirectionsandrestrictentrytounnecessarypersonnel.Shutoffsourceofleakonlyifitcanbedonesosafelyordikeandcontainthespill.Wearappropriateprotectiveclothing.Removewithvacuumtrucks.Soakupresiduewithsandorothersuitablematerial,placeincontainers forproperdisposal.Flushwithwateranddisposalofflushingsolutionsas above.Local,state and federaldisposalregulationsmustbe followed.

PersonalPrecautions andProtectiveEquipment

Responseandclean-upcrewsmustbeproperlytrainedandmustutilizeproperprotectiveequipment(seeSection 8).

EnvironmentalPrecautions

Protectbodiesofwaterbydiking,absorbents,orabsorbentboom,ifpossible.Donotflushdownsewer or drainagesystems,unlesssystemisdesignedandpermittedtohandlesuchmaterial.Theuseoffirefightingfoammaybeusefulincertainsituationstoreducevapors.Theproperuseofwaterspraymayeffectivelydisperseproductvaporsortheliquiditself,preventingcontactwithignitionsourcesorareas/equipmentthatrequireprotection-donotdischargesolidwater streampatternsinto theliquidresulting insplashing.

Preventionof SecondaryHazards

None

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HandlingProcedures

ComplywithallapplicableEPA,OSHA,NFPAandconsistentstateandlocalrequirements.Useappropriategroundingand bondingpractices.

Handleasaflammableliquid.Keepawayfromheat,sparks,andopenflame!Storeinacool,dry,well-ventilatedlocation,awayfromanyareawherethefirehazardmaybeacutethatcomplieswithNFPA30"FlammableandCombustibleLiquidCode."

Separate from incompatibles,including strong oxidizers.Donotstore nearfoodstuffs.

Storeinproperlyclosedcontainersthatareappropriately labeledandin acoolwell-ventilatedarea.

Donotcut,drill, grind or weldonemptycontainerssincetheymaycontainexplosiveresidues.

Harmfulconcentrationsofhydrogensulfide(H2S)gascanaccumulateinexcavationsandlow-lyingareasaswellasthevaporspaceofstorageandbulktransportcompartments. Stayupwindandventopen hatchesbefore unloading.

WORK/HYGIENICPRACTICES

Emergency eyewashcapabilityshouldbeavailablein the vicinity ofanypotentialsplashexposure.

Usegood personalhygienepractices.Avoidrepeatedand/or prolonged skinexposure.

Washhandsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donoteat,drinkorsmokeinareas ofuseor storage.

Donotusegasolineorsolvents(naphtha,kerosene,etc)forwashingthisproductfromexposed skin areas.Waterlesshandcleansersareeffective.

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Promptlyremovecontaminatedclothingand launderbeforereuse.Use carewhenlaundering to prevent theformationofflammablevaporswhichcouldigniteviawasherordryer.Consider theneedtodiscardcontaminatedleather shoesandgloves.

Avoid skin contact.Exercise good personalhygieneincludingremovalofsoiledclothingandpromptwashingwithsoapandwater.

Incompatibilities

Keep awayfrom strong oxidizers andheatsources.

Component ExposureLimits

Noexposurelimitsestablishedfor ingredients

PersonalProtectiveEquipment:Respiratory

ANIOSH/MSHA-approvedair-purifyingrespiratorwithorganicvaporcartridgesorcanistermaybepermissibleundercertaincircumstanceswhereairborneconcentrationsareormaybeexpectedtoexceedexposurelimitsorforodororirritation.Protection providedbyair-purifying respiratorsislimited.

Useapositivepressure,air-suppliedrespiratorifthereisapotentialforuncontrolledrelease,exposurelevelsarenotknown,inoxygen-deficientatmospheres,oranyothercircumstancewhereanair-purifyingrespiratormaynotprovideadequate protection.

For hydrogensulfide hazard(aboveH2Spermissibleexposurelimits):SCBAorasupplied air respiratormustbe used.

Refer to CSAStandard“Selection,UseandCareofRespirators” (Z94.4-02)andNIOSHRespirator DecisionLogicforadditionalguidanceonrespiratoryprotection.

PersonalProtectiveEquipment:Hands

Chemicallyresistantglovesconstructed ofnitrileor neoprenearerecommended.

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PersonalProtectiveEquipment: Eyes

Safetyglassesorgogglesarerecommendedwherethereisapossibilityofsplashing or spraying.

PersonalProtectiveEquipment: SkinandBody

ChemicalprotectiveclothingsuchasofE.I.DuPontTyChem®,Saranex®orequivalentrecommendedbasedondegreeofexposure.Note:Theresistanceofspecificmaterialmayvaryfromproducttoproductaswellaswithdegreeofexposure.Consultmanufacturer specificationsforfurther information.

HygieneMeasures

Emergencyeyewashcapabilityshouldbeavailableinthenearproximitytooperationspresentingapotentialsplashexposure.Usegoodpersonalhygienepractices.Avoidrepeatedand/orprolongedskinexposure.Washhandsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donotuseasacleaningsolventontheskin.Donotusegasolineorsolvents(naphtha,kerosene,etc.)forwashingthisproductfromexposedskin areas.Waterless handcleanersareeffective.

Promptlyremovecontaminatedclothingandlaunderbeforereuse.Usecarewhenlaunderingtopreventtheformationofflammablevaporswhichcouldigniteviawasheror dryer.Consider the needto discardcontaminatedleather shoesandgloves.

EXPOSURELIMITS

IngredientNameCAS #ExposureLimit

Benzene / 71-43-2 / ACGIHTWA= 0.5ppm (skin)
ACGIHTLV-STEL=2.5ppm
Toluene / 108-88-3 / ACGIHTWA= 50ppm (skin)
Ethylbenzene / 100-41-4 / ACGIHTWA= 100ppm
ACGIHSTEL=125ppm

Xylene,mixedisomers1330-20-7ACGIHTWA= 100ppmHydrogenSulphide7783-06-4 ACGIHTWA=5ppm

ACGIHSTEL= 10ppm

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ENGINEERINGCONTROLS

Useadequateexplosion-proof ventilation tokeep vaporandmistconcentrationsofthisproductbelowoccupationalexposureandflammabilitylimits,particularlyinconfinedspaces.Useexplosion-proofequipmentandlightinginclassified/controlledareas.

Appearance: / Darkyellowtobrownorgreenishblackliquid / Odor: / Characteristic heavy hydrocarbonodor
PhysicalState: / ViscousLiquid / pH: / ND
VaporPressure: / Varies / VaporDensity: / 3to5
BoilingPoint: / -128°F to 1000°F(-89°C - >538°C) / MeltingPoint: / -40 °F(-40 °C)
Solubility(H2O): / Insolubleto slightlysoluble / SpecificGravity: / 0.86to 0.95
EvaporationRate: / ND / VOC: / 10%
Octanol/H2OCoeff.: / ND / FlashPoint: / -4°F to 2012°F (-20°C -1100 °C)
Flash pointareintheflammable rangebutarehighlydependentoncrudeoil source.
FlashPointMethod: / TCC / UpperFlammabilityLimit (UFL): / 6.0%
LowerFlammabilityLimit (LFL): / 1.1% / BurningRate: / ND
AutoIgnition:590°F(310°C)

ChemicalStability

This is a stable material under normal conditions of use and at normaltemperaturesand pressures.

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HazardousReactionPotential

HazardousPolymerizationwill not occur.

ConditionstoAvoid

Avoid high temperatures, open flames, sparks, welding, smoking and otherignitionsources.

Incompatible Products

Keep awayfrom strong oxidizers.

HazardousDecompositionProducts

Thermaldecompositionishighlydependentonconditions.

Carbonmonoxide,carbondioxideandnon-combustedhydrocarbons(smoke),sulfur oxides,aldehydes and other decompositionproducts.

Contactwithnitric and sulfuricacidswillform nitrocresolsthatcan decomposeviolently.

IngredientCrudeOil / CASNo8002-05-9 / LD50LC50
Ratoral>5000mg/kg
DermalToxicity2000mg/kg
Toluene / 108-88-3 / Ratoral5000mg/kg400ppm/4hr
Ethylbenzene / 100-41-4 / Ratoral3500mg/kgRabbitskin17,800mg/kg
Xylene,mixedisomers / 1330-20-7 / Mouseoral1590mg/kg
Ratinhalation:6,350ppm/4hr
Benzene / 71-43-2 / Ratoral3306mg/kg
Ratinhalation10,000ppm/7hr
HydrogenSulfide / 7783-06-4 / Ratinhalation380mg/cu m 960min
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CHRONICEFFECTS/CARCINOGENICITY

Productcontains benzene.Humanhealthstudiesindicatethatprolongedand/or repeatedoverexposure to benzenemaycausedamagetothe bloodformingsystem (particularlybonemarrow),andseriousblooddisorders,suchasleukemia.Benzeneislistedbythe NationalToxicologyProgram (NTP),InternationalAgencyfor ResearchonCancer (IARC),andACGIHascarcinogenicinhumans.

AcuteToxicity

A:GeneralProduct Information

Potentialshort-term effectsofexposureare:irritationeyes,skin,nose,mucousmembrane,andrespiratorysystem.

Repeatedor prolongedskinexposureto petroleumoils maycausevariousskindisorders,suchascontactor eczematousdermatitis,folliculitis,oilacne,lipid granuloma,melanosis,andrarelyprecancerouswartsontheforearms,backs ofhandsor scrotum.Contains BenzeneandToluene,whicharereadily absorbedthroughintactskinandhaveSkinNotationsbyACGIH.

B:ComponentAnalysis- LD50/LC50

HighSulfur DieselOil(68476-34-6)Inhalation LD50/4 hr >4.1 mg/l, 4 hours(Rat)

Oral(n-Hexane) LD50 Rat>28710 mg/kg (Rat)

PotentialHealthEffects: Skin ContactProperty

Skinirritation.

PotentialHealthEffects: EyeContact Properties

Eyeirritation.

PotentialHealthEffects: Ingestion

Ingestion maycauseirritationand malaise.Swallowing or vomiting oftheliquidmayresultin aspirationinto thelungs.

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PotentialHealthEffects: Inhalation

Inhalation ofvaporsmaycausedrowsinessanddizziness.

Carcinogenicity

A:GeneralProduct Information

Productcontainspolynuclear aromatichydrocarbons(PAHs).Animalstudieshaveshownthatprolongedand/or repeated exposureto certain PAHs maycausecanceroftheskin,lung and other organs.Thisproducthasnotbeenlistedasacarcinogen byNTPor OSHA.

Reproductivetoxicity:

Thisproductisnotreportedtohaveanyreproductivetoxicityeffects.

Mutagenicity:Some crudeoilsand crude oilfractionshavebeen positiveinmutagenicassaytests.

TeratogenicityThecomponentsofthisproductarenotreportedtocauseteratogeniceffectsinhumans.Basedonbestcurrentinformation,thereisnoknownteratogenicityassociatedwiththisproduct.

Specific Target OrganToxicity- SingleExposure:Nodata available.

Specific Target OrganToxicity- RepeatedExposure:Nodata available.

Neurologicaleffects:Chronicexposuretohighconcentrationsofvarioushydrocarbonblendsmayleadtopolyneuropathy(peripheralnervedamage),characterizedbyprogressiveweaknessandnumbnessintheextremities,lossofdeeptendonreflexesandreductionofmotornerveconductionvelocity.Numerouscasesofpolyneuritishavebeenreportedfollowingprolongedexposurestoapetroleumfractioncontainingvariousisomersofheptaneasmajoringredients.Maycausecentralnervoussystemdisorder(e.g.,narcosisinvolving alossofcoordination,weakness,fatigue)and/or damage.

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Ecotoxicity:

Ecotoxicologicaldatahavenotbeendeterminedspecifically forthisproduct.Informationgivenisbasedonaknowledgeofthecomponentsandtheecotoxicologyofsimilarproducts.Unlessindicatedotherwise,thedatapresentedisrepresentativeoftheproductasawhole,rather than for individualcomponent(s).

Coatingactionofoilcankillbirds,plankton,algaeandfish.Keepoutofallbodiesofwater andsewagedrainagesystems.

AquaticAcute:Expectedtobeharmful:LL/EL/IL501-10mg/l(toaquaticorganisms)LL/EL50expressedasthenominalamountofproductrequiredtoprepareaqueoustestextract.

Fish: Expectedtobeharmful:LL/EL/IL501-10mg/l

Aquaticcrustacea:Expectedtobeharmful:LL/EL/IL501-10 mg/lAlgae/aquaticplants:Expectedtobeharmful:LL/EL/IL50 1-10 mg/lMicroorganisms : Data notavailable

AquaticChronictoxicity:Toxic toaquaticorganisms,maycauselong-term

adverseeffectsin theaquaticenvironment.

Fish: NOEC/NOELexpectedtobe 1.0- <= 10 mg/l

Aquaticcrustacea:NOEC/NOEL expected tobe1.0- <= 10 mg/l12.2

PersistenceandDegradability:Majorconstituentsareinherentlybiodegradable,butcontainscomponentsthatmaypersistin theenvironment

BioaccumulativePotential: Containsconstituentswiththe potential to bioaccumulate.

Mobilityin Soil: Ifthe productenterssoil,oneormoreconstituentswill ormaybemobile and maycontaminategroundwater.Containsvolatileconstituents.Partlyevaporatesfrom water or soilsurfaces,but asignificantproportionwillremainafteroneday. Floatsonwater and formsaslick.

Otheradverseeffects:Noinformationavailable.

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Additionalecologicalinformation:

Waterhazardclass1(Self-assessment):slightlyhazardousfor water

Donotallowundiluted productor largequantitiesofittoreachgroundwater,watercourseorsewagesystem.

Waste DisposalInstructions

CleanupConsiderations: ThisproductasproducedisnotspecificallylistedasanEPARCRAhazardouswasteaccording tofederalregulations(40CFR261).However,whendiscardedordisposedof,itmaymeetthe criteria ofan"characteristic" hazardouswaste.Thisproductcouldalsocontainbenzeneat >0.5ppm andcouldexhibitthecharacteristicsof"toxicity"asdeterminedbythetoxicitycharacteristicleachingprocedure(TCLP).Thismaterialcouldbecome ahazardouswasteifmixedorcontaminatedwith a hazardouswasteorothersubstance(s).

It istheresponsibilityoftheuser todetermineifdisposalmaterialishazardousaccording tofederal,stateandlocalregulations.

Emptycontainer:scrapmetalrecyclingor re-conditioningSoiledcontainer:(treatmentlikeproductitself)

Disposalof ContaminatedContainersorPackaging

Disposeofcontents/container inaccordance withlocal,state,and federalregulations.

Recover or recycleifpossible.It istheresponsibilityofthewastegenerator todetermine the toxicity and physicalpropertiesofthe materialgenerated todetermine the properwasteclassification anddisposalmethodsin compliancewithapplicableregulations.

Donotdisposeintothe environment,in drainsor inwater courses.Donotdispose of tankwater bottomsbyallowing themtodrainintotheground.This willresultinsoiland groundwater contamination.Wastearisingfromaspillageortank cleaning should bedisposed ofin accordancewithprevailing regulations,preferablytoarecognizedcollector or contractor.The competence ofthecollector or contractorshould be established beforehand.

DisposalRegulatoryRequirements:

Refer tolatestEPAorstateregulationsregarding properdisposal.

ContainerCleaningandDisposal:“Empty”ContainerWarning:

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“Empty” containersretainproductresidue (liquidand/or vapor) andcanbedangerous.DONOTPRESSURIZE,CUT,WELD, BRAZE,SOLDER,DRILL,GRIND, OR EXPOSESUCHCONTAINERSTOHEAT,FLAME,SPARKS,STATICELECTRICITY, OR OTHER SOURCESOF IGNITION.THEYMAYEXPLODEANDCAUSEINJURYOR DEATH.

DOTInformation:

ShippingName:PETROLEUM CRUDEOIL,FLAMMABLE,TOXIC

UN #:3494

HazardClass:3-Packing -I

Placard:

Canadian(TDG)

ShippingDescription:Shippingdescriptiononlyvalidifvaporpressureis<=300kPa(43.5 psia) at50°C (122°F).Ifnot,Call 1 8004249300for assistance.

14.1UNnumber:UN3494

14.2UNproper shipping name:Petroleumcrudeoil

14.3Transporthazardclass(es): 3

14.4Packing group:IPetroleumcrude oilFlammable liquids

14.5Environmentalhazards:Yes

Note:Packinggroupisdependentonboilingpoint(BP)ofthematerial:IifBP<=35°C;II ifBP35° C

Landtransport(ADR/RID):ADR

14.1UNnumber:UN3494

14.2UNproper shipping name:Petroleumcrudeoil

14.3Transporthazardclass(es): 3

14.4Packing group:IPetroleumcrude oil

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Flammable liquids

14.5Environmentalhazards:Yes

RID

14.1UNnumber:UN3494

14.2UNproper shipping name:Petroleumcrudeoil

14.3Transporthazardclass(es): 3

14.4Packing group:IPetroleumcrude oilFlammable liquids

14.5Environmentalhazards:Yes

Seatransport(IMDGCode):

14.1UNnumber:UN3494

14.2UNproper shipping name:Petroleumcrudeoil

14.3Transporthazardclass(es): 3

14.4Packing group:Ior Petroleum crudeoilFlammable liquids

14.5Environmentalhazards:Yes

14.5 Environmentalhazards:Yes.MarinePollutant

Air transport(IATA):

14.1UNnumber:U3494

14.2UNproper shipping name:Petroleumcrudeoil

14.3Transporthazardclass(es): 3

TransportInformation:Thismaterialwhentransported viaUScommerce wouldberegulatedbyDOTRegulations.

USfederalregulations:

USTSCAChemicalInventorySection8(b):Thisproductand/oritscomponentsarelistedontheTSCAChemicalInventory.

OSHAHazardCommunicationStandard:ThisproducthasbeenevaluatedanddeterminedtobehazardousasdefinedinOSHA'sHazardCommunicationStandard.

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EPASuperfundAmendmentReauthorizationAct(SARA):

SARASection302: Thisproductcontainsthefollowingcomponent(s) thathavebeenlistedonEPA'sExtremely HazardousSubstance(EHS)List:

NameCERCLA/SARA-Section302ExtremelyHazardousSubstancesandTPQs

Petroleum CrudeOilNANormalHexaneNATolueneNA

XyleneNA

SulfurCompoundsNABenzeneNA

HydrogenSulfidehydrogensulfide

SARASection304: Thisproductcontainsthefollowingcomponent(s) identifiedeitherasanEHSora CERCLAHazardoussubstance whichincaseof a spillor releasemaybesubject toSARAreportingrequirements:

NameCERCLA/SARA-HazardousSubstancesandtheir ReportableQuantities

Petroleum CrudeOilNA

NormalHexane = 2270kgfinalRQ=5000lbfinalRQToluene=0.454kgfinalRQ=1lbfinalRQ

=10lbfinalRQ

=100lbfinalRQ

=1000lbfinalRQ

=4.54kgfinalRQ

=45.4kgfinalRQ

=454kg finalRQ

Xylene =100lbfinalRQ =45.4kgfinalRQSulfurCompoundsNA

Benzene =0.454kg finalRQ = 0.454kg statutoryRQ

=1lbfinalRQ

=1lbstatutoryRQ

=10lbfinalRQ

=10lbfinalRQreceivesanadjustableRQof10lbsbasedonpotentialcarcinogenicityinAugust14,1989finalrule

=100lbfinalRQ

=4.54kgfinalRQ

=4.54kgfinalRQreceivesanadjustableRQof10lbsbasedonpotentialcarcinogenicityinAugust14,1989finalrule

=45.4kgfinalRQ

HydrogenSulfide =100lbfinalRQ = 45.4kgfinalRQ

/ SAFETYDATASHEET / Page:Page20of21
Revisionedition:0
Date:5/18/2015
CanadianCrudeOil / Supersedes:MSDS0000001
SDS-0001

SARASection311/312:The followingEPAhazardcategoriesapplytothisproduct:AcuteHealth Hazard

NameCERCLA/SARA313 Emissionreporting:

Petroleum CrudeOil=100lbReportingThresholdChemicalCategoryN590,PBTChemicalsNormalHexane =1.0%concentration

Toluene=1.0%concentrationXylene =1.0%concentrationSulfurCompoundsNoneBenzene =0.1%concentrationHydrogenSulfideNone

CanadianRegulatoryInformation:

CanadaDSL/NDSLInventory:Thisproductand/oritscomponentsarelistedeither ontheDomesticSubstances List(DSL)orthe NonDomesticSubstanceList(NDSL).

NameCanada-WHMIS:ClassificationsofSubstances: Canada - WHMIS:IngredientDisclosure:

Petroleum CrudeOilB2

NormalHexaneB2;D2B1% (EnglishItem827,FrenchItem964)1% (EnglishItem 828,FrenchItem 965)

TolueneB2;D2A1% (EnglishItem1578,FrenchItem 1622)XyleneB2;D2A;D2B

BenzeneB2;D2A0.1% (EnglishItem153,FrenchItem 277)

HydrogenSulfideA;B1;D1A;D2B1% (English Item851,FrenchItem 1550)

AdditionalInformation:The pronouncedandeasily-recognizedrotteneggodor ofhydrogensulfidegas(H2S) canbedetectedatconcentrationsaslowas0.003-0.13ppm.SincehigherH2Sconcentrations(100-200ppm) causeolfactoryfatigueandotherhydrocarbonodorscan"mask"H2S, the senseofsmellcannotbeusedasa reliableindicatorofH2Sexposure.

49CFRTableListofHazardousMaterials

UN#,ProperShippingNames,PG. -CanadaGazettePartII,Vol.122,No.2.

RegistrationSOR/88-64,31December 1987.HazardousProducts Act"IngredientDisclosureList"Canadian TransportofDangerousGoods,RegulationsandSchedules,Clear Languageversion2005.

/ SAFETYDATASHEET / Page:Page21of21
Revisionedition:0
Date:5/18/2015
CanadianCrudeOil / Supersedes:MSDS0000001
SDS-0001

DISCLAIMEROFLIABILITY:Beforeusingthisproductinanynewprocessorexperiment,a thoroughmaterialcompatibilityand safetystudyshouldbe carriedout.

Thisdocumentisgeneratedforthepurposeofdistributinghealth,safety,andenvironmentaldata.

InformationiscorrecttothebestofourknowledgeatthedateoftheSDSpublication.Itisnotaspecificationsheetnorshouldanydisplayeddatabeconstruedasaspecification.

Theinformationonthiswasobtainedfromsourceswhichwebelievearereliable.However,theinformationisprovidedwithoutanywarranty,expressedorimplied,regardingitscorrectness.Someinformationpresentedandconclusionsdrawnhereinarefromsourcesotherthandirecttestdataonthesubstanceitself.Theconditionsormethodsofhandling,storage,useanddisposaloftheproductarebeyondourcontrolandmaybebeyondourknowledge.Forthisandotherreasons,wedonotassumeresponsibilityandexpresslydisclaimliabilityforloss,damage,orexpensearisingoutoforinanywayconnectedwithhandling,storage,use,ordisposalofthisproduct.Iftheproductisusedasacomponentinanotherproduct,thisMSDSinformationmaynotbeapplicable.