Appendix 2 – Example of statistical evaluation within one period

Median Calculation and Marking Strange Data

PK – Mehlich 3 soil extraction and pH

Mg [mg/kg]

Sample 5721 5795 5701

Laboratory

2778 169 239 143

2901 172 254 136 /POE

3183 163 243 135 /FBA

3425 170 233 153 /FAA

3555 165 243 146 /FAB

3754 172 252 143 XXX/FAA

4451 176 254 145 XXX/FAA

4493 182 260 149

4655 173 250 147 /FAA

4840 179 239 147 /FAA

5509 170 241 137 /POE

5662 174 251 145 /POE

5993 173 249 148 /FAA

6019 183 ** 254 143 /FAA

6203 169 249 139 /FAB

6569 171 238 141 /POE

6664 169 237 133

6891 171 243 140 /FAA

6897 176 254 144 /POE

6933 179 254 145

6974 190 ** 280 ** 148 /POE

8102 172 246 140

8408 173 254 140 /FAB

8662 167 236 137 /FAA

8810 173 249 145 /FAA

8935 165 247 132 /FAA

8984 168 243 147

9467 172 247 138

Median 1 172.0 247.0 143.0

MAD 1 3.0 6.0 4.0

1st limit 10.1 20.2 13.5

Median 2 172.0 247.0 143.0

MAD 2 3.0 5.0 4.0

2nd limit 10.2 16.9 13.5

Appendix 2 – Example of statistical evaluation within one period

The Results of Horn Procedure for the Small Sample Sizes

PD - 2M cold HNO3 soil extraction

V [mg/kg]

Sample 5721 5795 5701

Laboratory

1152 7.17 14.40 8.56 KD1/POE

3183 6.62 13.23 ** 8.39 KD1/FBA

3555 6.65 14.57 7.90 KD1/FBA

3754 6.75 14.23 8.93 KD1/POE

4633 6.20 14.76 7.87 KD1/POE

5509 6.73 14.50 8.35 KD1/POE

5662 6.84 15.80 8.55 KD1/POE

6569 6.60 14.78 7.88 KD1/POE

6974 6.90 15.13 8.80 KD1/POE

7590 6.21 16.18 9.60 KD1/FBA

8408 7.00 16.00 8.50 /ICP

Median 1 6.730 14.760 8.500

MAD 1 0.130 0.370 0.300

1st limit 0.532 1.514 1.227

Median 2 6.730 14.770 8.500

MAD 2 0.130 0.365 0.300

2nd limit 0.532 1.540 1.227

X_Horn 6.750 15.100 8.350

S_Horn 0.164 0.763 0.491

Appendix 2 – Example of statistical evaluation within one period

Calculation and Demonstration of Z-score

RZ - Macronutrients

Year : 2008 period: 1 parameter: N_Kjel [%]

sample: 9078 N: 32 rob.aver.: 4.188 rob.s.d.: 0.083

-5-4-3-2-1 0 1 2 3 4 5

Lab. Value Z-score │ │ │ │ │ │ │ │ │ │ │

1605 2.11 -25.04 !! ◄══════════╣

8578 3.25 -11.30 !! ◄══════════╣

7337 4.06 -1.54 ═══╣

5649 4.08 -1.30 ═══╣

9206 4.09 -1.18 ══╣

5092 4.09 -1.18 ══╣

1692 4.09 -1.18 ══╣

5175 4.12 -0.82 ══╣

6751 4.14 -0.58 ═╣

1288 4.14 -0.58 ═╣

9348 4.15 -0.46 ═╣

5782 4.16 -0.34 ═╣

1880 4.17 -0.22 ║

2506 4.17 -0.22 ║

9016 4.19 0.02 ║

9754 4.20 0.14 ║

6454 4.21 0.27 ╠═

2644 4.21 0.27 ╠═

6014 4.22 0.39 ╠═

1209 4.22 0.39 ╠═

2797 4.23 0.51 ╠═

7764 4.23 0.51 ╠═

6162 4.23 0.51 ╠═

4592 4.23 0.51 ╠═

3793 4.23 0.51 ╠═

1393 4.25 0.75 ╠══

2378 4.26 0.87 ╠══

8765 4.27 0.99 ╠══

5995 4.27 0.99 ╠══

9343 4.31 1.47 ╠═══

2955 4.31 1.47 ╠═══

1042 5.97 21.47 !! ╠══════════►