Waste Management Procedures
Completion Fluids / Solids (Zinc Bromide)
Before you begin
Description
/ Fluid used to complete the well prior to first flow.Category
/ E&P exempt if used downhole.Analysis
/ No analysis is required, Zinc Bromide is identified from its MSDS. All completion fluid should be captured and returned to the vendor for credit.Accumulation
/ Fluids that contain zinc bromide must be contained in portable tanks, cuttings boxes or drums and sent to an E & P waste disposal facility.Waste Reduction
/ Return to vendor.Disposal
/ NOTE: Do not discharge into water· Return to vendor for credit. This completion fluid is very expensive and this completion fluid is a Marine Pollutant.
· As a last resort, dispose of at a state permitted E&P waste facility. Identify waste as 04 Completion Fluids.
Recordkeeping
/ · Complete entry in Hazardous Material Section [Section I] of the Apache Shipping Manifest.The material description “Environmentally Hazardous Substance, liquid, n.o.s. (Zinc Bromide) RQ, 9, UN3082, PGIII” should be written in a blank line in Section I. The letters RQ are not needed if the containers hold less than 1000 pounds (23 gallons). Enter the number “171” in the column headed “Emergency Response Guide”.
If the zinc bromide is being sent to a state permitted E&P waste facility:
· For shipments to shorebases in Louisiana, prepare Non-hazardous Oilfield Waste Shipping Control Ticket Form UIC-28 (See Example).
· For shipments to shorebases in Alabama, Prepare State Oil and Gas Board of Alabama Waste Liquids Manifest (See Example).
· For shipments to shorebases in Texas, or Mississippi no state documents are required.
· Maintain a copy of manifest records at offshore and onshore facilities while active. Send original manifests with shipment.
· Retain records for three years.
Shipping Instructions:
Completion Fluids / Solids (Zinc Bromide)
1. Call or FAX Dock/Base to schedule shipment.
2. Package Fluids in one of the following containers:
a. Cutting Boxes (15 barrels or less in volume)
b. 1A2 removable head and 1A1 non-removable head steel drums
c. Marine Portable Tanks
d. IM 102 Tanks
3. Mark Package:
a. Stencil container "Environmentally Hazardous Substance, liquid, n.o.s. (Zinc Bromide) RQ, 9, UN3082, PG III".
b. If shipping less than 1000 pounds (23 gallons), the letters "RQ" are not required.
c. Stencil Container-”Apache” and the generator's location (Eugene Island 158)
d. MARINE POLLUTANT placard. (See example)
1. For transport vehicles that contain bulk or non-bulk packaging holding more than one gallon of zinc bromide:
a. The MARINE POLLUTANT mark must appear on each end and each side of the transport vehicle and must be visible from the direction it faces.
b. Each side of the mark must be at least 9.8 inches (250 mm).
2. A bulk packaging holding more than one gallon of zinc bromide:
a. Must be marked with MARINE POLLUTANT on each end and each side and must be visible from the direction it faces.
b. Each side of the mark must be at least 9.8 inches (250 mm).
3. For non-bulk packaging holding more than one gallon of zinc bromide:
a. The MARINE POLLUTANT mark shall be placed in association with the CLASS 9 hazard warning label.
b. Each side of the mark must be at least 3.9 inches (100 mm).
4. Label Package:
a. CLASS 9, Miscellaneous Hazardous Materials label near the proper shipping name.
b. For packages having a volume over 64 cubic feet (478 gallons) and for portable tanks of less than 1000 gallons: place labels on at least two ends (other than the bottom) or two sides.
c. See attached labels
Shipping Instructions:
Completion Fluids / Solids (Zinc Bromide), (continued)
5. Prepare manifest using either of the following:
a. Complete entry in Hazardous Material Section [Section I] of the Apache Shipping Manifest:
The material description “Environmentally Hazardous Substance, liquid, n.o.s. (Zinc Bromide) RQ, 9, UN3082, PGIII” should be written in a blank
line in Section I. The letters RQ are not needed if the containers hold less than 1000 pounds (23 gallons).
b. For shipments to shorebases in Louisiana, prepare Prepare Non-hazardous Oilfield Waste Shipping Control Ticket Form UIC-28 in Louisiana (See Example). DO NOT SIGN THIS CONTROL TICKET. It is required to be signed in the presence of the truck driver. Dock personnel must sign.
c. For shipments to shorebases in Alabama, Prepare State Oil and Gas Board of Alabama Waste Liquids Manifest.
d. For shipments to shorebases in Texas, or Mississippi no state documents are required.
6. Placard Vehicle/Vessel:
a. For cargoes of 1000 pounds (23 gallons) or more: Class 9 placard with number 3082 in center and number 9 underlined in the lower corner.
b. For cargoes less than 1000 (23 gallons) no placard required for transport vehicle.
c. Cargo or portable tanks shall be placarded as above on opposing sides if capacity is between 119 and 999 gallons and on all four sides if 1000 gallons or more.
d. See attached placard
7. Load cargo in accordance with the following shipping limitations:
AIR / RESTRICTIONS (49 CFR 172.101)Passenger Aircraft / No Restrictions
Cargo Aircraft / No Restrictions
WATER / RESTRICTIONS (49 CFR 172.101)
Cargo and passenger vessels / No Restrictions
Other Requirements / None
8. Include MSDS with shipment.
NONHAZARDOUS OILFIELD WASTE SHIPPING CONTROL TICKET
STATE OF LOUISIANA / 1567899UIC - 28
/ OFFICE OF CONSERVATION / Manifest No.P.O. BOX 94275
BATON ROUGE, LA 70804-9275 / CONSERVATION COPY
ORIGINAL
17265451 END
PART I
/TO BE COMPLETED BY GENERATOR
CODES0152 / ↔ /
Generator
/ Apache CorporationAddress / 2014 W. Pinhook Road, Suite 800 / (337) 735-8210
City/State/Zip / Lafayette, LA, 70510 / Telephone No.
ORIGINATION OF WASTE (see instructions on back)
999997 / ↔ /
Well Name & No. / Description
/ OCS-G-12205 / ↔ / LUW Type /
Field
/ Eugene Island 175WASTE IDENTIFICATION AND AMOUNT (IN 42 GALLON BARRELS)
01 Salt Water / 07 Prod. Sands/Solids / 13 BS &W Waste
02 Oil Base Mud / 08 Fresh Water / 14 Pipeline Test Water
03 Water Base Mud / 09 Rainwater / 15 Com. Facility Waste
04 Completion Fluids / 50 / 10 Washout Water / 16 Oil Spill Waste
05 Prod. Pit Sludges / 11 Washout Pit Water / 50 Salvage Crude Oil
06 Prod Tank Sludges / 12 Gas Plant Waste / 99 Other
SITE CODE / DESTINATION OF WASTE / US Liquids
Commercial Facility (Company) Name
5101 / 1200 Young’s Road Morgan City, La. 70380
↔ /
Site Name
NOTE: MUST BE SIGNED IN THE PRESENCE OF THE TRANSPORTER!CERTIFICATION: / The waste described above was consigned to the carrier named below. I certify that the foregoing is true and correct to the best of my knowledge / am
Sam Bourque / 0/1/11 / pm
Signature of Generator’s Authorized Agent / Date and Time of Shipment
PART II:
/TO BE COMPLETED BY TRANSPORTER IN PRESENCE OF GENERATOR
PSC PERMIT9997 / ↔ / Transporter / Graham Gulf, Inc. / (985) 385-3475
Address
/ P.O. Box 2291 / Telephone No.City/State/Zip / Morgan City, LA, 70380 / Truck License No.
Trailer License No.
If transported by barge, barge and tug identification
Barge and Tug Id.
CERTIFICATION: / I certify that the waste in quantity above was received by me for shipment to the above destination. / am
pm
Signature of Transporter’s Authorized Agent / Date and Time Received
PART III
/TO BE COMPLETED BY COMMERICAL FACILITY
SITE CODEFacility (Company) Name / US Liquids
5101 / ↔ /
Site Name
/ 1200 Young’s Road Morgan City, La. 70380CHEMICAL ANALYSIS
Chloride (mg/l) / Conductivity (mmhos/cm) / pH
CERTIFICATION: / I certify that the waste described in Part I was received by me via the transporter described in Part II
Signature of Facility Agent / Date and Time Received
FORM OGB-26 STATE OIL AND GAS BOARD OF ALABAMA
P. O. Box 869999
Tuscaloosa, Alabama 35486-6999 / AP3 / OCSG 5058 #001
(205) 349-2852 Fax (205) 349-2861
www.ogb.state.al.us / Operator Code / Manifest Number
WASTES MANIFEST
PART I: TO BE COMPLETED BY THE OPERATOR
Operator Name: / Apache Corporation (Mobile 821)Address: / 7778 Dauphin Island Parkway, Theodore, AL 36582 (251) 439-7244
Origination of Waste Liquids
Operator Name: / AP3 / (337) 735-8220
Operator Type / NATURAL GAS
Field / MOBILE 821 FIELD / County / FEDERAL WATERS
Description of Waste / Zinc Bromide Completion Fluid
Quantity of Waste / 9.5 BARRELS
Destination:
Disposer’s Name / US Liquids
Business Address
Disposal Site Address / 1200 Young’s Road Morgan City, La. 70380
Disposal Method / SEPARATION AND DEWATERING
Certification: The waste described above was consigned to the carrier named below. I certify that the foregoing is true and correct to the best of my knowledge
Sam Bourque / 07 / 01 / 11 2:30 p.m.
Signature of Operator’s Agent / Date and Time Shipped
PART II: TO BE COMPLETED BY TRANSPORTER(Note: To be completed in presence of Operator)
Transporter’s Name / Gulf Glory / Code No. / ALR000011247Business Address / Graham Gulf Inc. P.O.Box 309, Bayou La Batre, AL 36509 (251) 824-1834
License Plate of Truck / License of Trailer
If Transported by Barge, Barge and Tug Identification
Certification: I certify that the waste in the quantity above was received by me for shipment to the above destination
Bill Jones / 07 / 01 / 11 2:30 p.m.Signature of Transporter’s Agent / Date and Time Received
PART III: TO BE COMPLETED BY DISPOSER
Disposer’s Name / US LiquidsDisposal Site Address / 1200 Young’s Road Morgan City, La. 70380
Certification: I certify that the waste in the quantity and description above was received by me for proper disposal.
Sam Bourque / 07 / 03 / 11 1:30 p.m.Signature of Disposer’s Agent / Date and Time Received
INSTRUCTIONS
Read Carefully and Comply Fully
1. Every shipment of wastes liquids shall be accompanied by this form.
2. At the time of transport, the operator shall initiate the manifest by completing and signing Part I. The operator shall assign a sequential manifest number in the upper right corner. The number should be preceded by the operator code number provided by the State Oil and Gas Board.
3. The transporter shall complete and sign Part II.
4. The operator shall copy form and mail to the Board within ten (10) days.
5. The original shall accompany the wastes shipment.
6. Upon receipt of the wastes, the disposer shall complete and sign Part III.
7. The transporter shall retain a copy.
8. The disposer shall retain a copy and mail a copy to the operator and the original to the Board within ten (10) days.
Version 2, October 2011 Page 7 of 7