Chemistry 167 SI
Supplemental Instruction
Iowa State University / Leader: / Sean Frey
Course: / Chemistry 167 SI
Instructor: / Dr. Bonaccorsi
Date: / 11/30/16

What will be the equilibrium expression for the following equations?

  • N2O4(g) ⇌ 2 NO2(g)
  • 2 NO(g) + O2(g) ⇌ 2 NO2(g)
  • F- (aq) + H2O(l) ⇌ HF(aq) + OH- (aq)
  • HF(aq) ⇌ H+ (aq) + F- (aq)

Given the two reactions

  • F- (aq) + H2O (l) ⇌ HF (aq) + OH- k= 6.8 × 10-4
  • HF (aq) ⇌ H+ (aq) + F- (aq) k= 1.5 × 10-11
  • What is the equilibrium constant for H2O(l) ⇌ H+ (aq) + OH– (aq)?

Given the two reactions

  • PbCl2⇌ Pb2+ + 2Cl– K1 = 1.77×10−10
  • AgCl⇌ Ag+ + Cl– K2 = 1.14×10−4
  • What is the equilibrium constant K for the following reaction? PbCl2 + 2 Ag+⇌ 2 AgCl + Pb2+

What is the new equilibrium constant?

  • F- (aq) + H2O (l) ⇌ HF (aq) + OH- k= 6.8 × 10-4
  • 2HF (aq) + 2OH- ⇌ 2F- (aq) + 2H2O (l) k=

Where would you expect the reaction to move towards if the k value is greater than 1?

Where would you expect the reaction to move towards if the k value is less than 1?

Consider the equilibrium CH3OH(g) ⇌ CO(g) + 2 H2(g), ∆H° = + 91 kJ.

Complete the statements below using the words increases, decreases, or does not change.

a) As the temperature increases, the amount of CH3OH(g)______.

b) As the volume of the container in which the reaction occurs decreases, the amount of H2(g)_____ .

c) The amount of CH3OH(g) _____ if a catalyst is added.

d) The amount of CO(g) ______after adding more CH3OH(g).

4.00 moles of HI are placed in an evacuated 5.00 L flask and then heated to 800 K

Kc= 0.016 for the equation2 HI(g) H2(g) + I2(g)

What is the concentration of H2?