Tradename:Heavycrudeoil

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WHMIS / PersonalProtectionEquipment / TDG(Ground)

Product identifier

Tradename:HeavyCrudeOil

SDSNr:SDS-0020

Chemicaldescription:CrudeOil

CASNo:8002-05-9 (100%)Petroleumdistillates(naphtha)71-43-2 (<1%)Benzene

EC No:232-298-5

Registration-No:Registrationdeadlinenotexpired.

Use:Manufacture ofanddistillationofsubstances.Useasa blowingagent,fuel,formulationand(re)packingofsubstancesandmixtures,polymerproductionandprocessing,functionalfluids,andasa propellant.

Companyidentification: FreepointCommodities, LLC

58CommerceRoad

Stamford,Ct.06902

E-Mailaddress(competent person):Lou Santore

LouSantore[]Emergencytelephonenumber:Withinthe U.S.or Canada:1800 4249300

Outside the U.S. and Canada: +1 703 527 3887(collectcallsaccepted)

MSDSprepared by:PaulePatterson,ENERCONServices, Inc.

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GHSClassification:

Flammable Liquids - Category2

GermCellMutagenicity – Category1BCarcinogenicity-Category1A

SpecificTarget Organ ToxicitySingle Exposure -Category3

SpecificTargetOrgan ToxicityRepeatExposure- Category2

GHSLABELELEMENTS

Symbol(s)

SignalWord: Danger

HazardPictograms:

CLPHazardStatements:

HEALTHHAZARDS:

H224:Extremelyflammableliquidandvapor.

H304: Maybefatal ifswallowedand entersairways.

H319:Causesseriouseyeirritation.

H336:Maycause drowsiness or dizziness.

H340:Maycausegeneticdefects.

H350:Maycausecancer.

H373:Maycause damageto organs or organ systemsthroughprolongedorrepeated exposure.

EUH066:Repeated exposure maycauseskin dryness or cracking.

ENVIRONMENTALHAZARDS:

H411:Toxic to aquatic lifewith long lasting effects.

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CLPPrecautionarystatementsPrevention:

P201: Obtainspecialinstructionsbefore use.

P210: Keepawayfrom heat/sparks/open flames/hotsurfaces. - No smoking.

P280:Wearprotectivegloves/protectiveclothing/eyeprotection/face protection.

Response:

P301+P310: IF SWALLOWED:Immediatelycall aPOISONCENTER ordoctor/physician.

P331:DoNOTinduce vomiting.

Disposal:

P501:Dispose ofcontentsand containerto appropriatewastesite or reclaimer inaccordancewithlocal,state,andnationalregulations.

EC Classification:F+: ExtremelyFlammable

EC Risk Phases:

R12: Extremelyflammable

EC SafetyPhrases:

S9:Keep container inawellventilatedplace.

S16:Keep awayfrom sourcesofignition –No smoking.

S23:Donotbreathe gas/fumes/vapor/spray.

S36/37:Wear suitable protectiveclothing and gloves.

S45:Incaseofaccidentor ifyou feelunwell, seekmedicaladviceimmediately.

S51:Useonlyinwell-ventilated areas.

Otherhazards:HealthHazards:

Hydrogensulfideishighlytoxicandmaybefatalifinhaled.Hydrogensulfide(H2S),anextremelyflammableandtoxic gas,andotherhazardousvaporsmayevolveandcollectintheheadspaceofstoragetanks,transportvesselsandotherenclosedcontainers.

Maydullthesenseofsmell,sodonotrelyonodoras anindicationofhazard.

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H2Shasabroadrangeofeffectsdependentontheairborneconcentrationandlengthofexposure:0.02ppmodorthreshold,smellofrotteneggs;10ppm eye andrespiratorytractirritation;100ppmcoughing,headache,dizziness,nausea,eyeirritation,lossofsenseofsmellinminutes;200ppmpotentialforpulmonaryedemaafter>20-30minutes;500ppmlossofconsciousnessaftershortexposures,potentialforrespiratoryarrest;>1000ppmimmediatelossofconsciousness,mayleadrapidlytodeath,promptcardiopulmonaryresuscitationmayberequired.

Donot dependonsenseofsmellforwarning.H2Scausesrapidolfactoryfatigue.Thereis noevidencethatH2Swillaccumulateinthebodytissueafter repeatedexposure.

Repeatedexposurecauseskindrynessorcracking.

Acomponentorcomponentsofthismaterialmaycausecancer.

Thisproductcontainsbenzenewhichmaycauseleukemia(AML-acutemyelogenousleukemia).MaycauseMDS(MyelodysplasticSyndrome).

SafetyHazards:May igniteonsurfacesattemperaturesaboveauto-ignitiontemperature.Flammablevaporsmaybepresentevenattemperaturesbelowtheflashpoint.Thismaterialis a staticaccumulator.Evenwithpropergroundingandbonding,thismaterialcanstillaccumulateanelectrostaticcharge.Ifsufficientchargeisallowed to accumulate,electrostaticdischargeandignitionofflammableair-vapormixtures canoccur.

Other Information:

Thisproductisintendedfor useinclosedsystemsonly.

The substance doesnotfulfillallscreening criteria for persistence,bioaccumulation andtoxicityand hence isnotconsidered to be PBTorvPvB.

Anaturalproductderivedfromvariousoilproductionfieldsprimarilyconsistingofacomplexcombinationofparaffinicandaromatichydrocarbonsandsmallamountsofnitrogenandsulfur compounds.

Substance / Preparation:Substance.

Substance / %Weight / CAS# / EC Index # / EC # / Classification
Petroleumdistillates(naphtha) / 100 / 8002-05-9 / N/A / 232-298-5 / H224;H350;H319;H373;H336;H411;
H304
Benzene / <1 / 71-43-2 / 601-020-00-8 / 200-753-7 / H225SkinIrrit. 2H315EyeIrrit. 2H319Muta. 1B H340Carc. 1A H350STOTRE 1H372Asp.Tox. 1H304
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FirstAid: Eyes

In case ofcontactwitheyes,immediatelyflushwith clean,low-pressurewater for atleast15min.Hold eyelidsopen to ensure adequate flushing.Seek medical attention.

FirstAid: Skin

Remove contaminated clothing.Wash contaminated areasthoroughlywithsoap andwaterorwaterlesshand cleanser.Obtainmedical attention ifirritation orrednessdevelops.

Thermalburnsrequire immediatemedical attention depending on the severityand the areaofthe bodyburned.

FirstAid: Ingestion

DONOTINDUCEVOMITING.Do notgive liquids.Obtain immediatemedicalattention.Ifspontaneousvomiting occurs,lean victimforward to reduce the riskof aspiration.Monitorforbreathing difficulties. Smallamountsofmaterialwhich enterthemouth should be rinsedoutuntilthe taste isdissipated.

FirstAid: Inhalation

Remove person tofresh air.Ifperson isnotbreathing,provide artificialrespiration.Ifnecessary,provide additionaloxygen once breathing isrestored iftrained to do so.Seekmedicalattention immediately.

Noactionshallbetakeninvolvinganypersonalriskor withoutsuitabletraining.Ifitissuspectedthatfumesarestillpresent, therescuer shouldwearanappropriatemaskorself-containedbreathingapparatus.Itmaybedangeroustothepersonprovidingaid togivemouth-to-mouthresuscitation.Washcontaminatedclothingthoroughly withwaterbefore removingit,orweargloves.

Notes tophysician:Symptoms:Dizziness,Headache,Nausea,Frostbite,Vomiting,DiscomfortHazards:

Thismaterialmaybe a cardiacsensitizer;avoidthe use ofepinephrine.

Treatment:Treatmentofoverexposureshouldbedirectedatthe controlofsymptomsand theclinicalconditionofthe patient.

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GeneralFire Hazards

See Section9for FlammabilityProperties.Incompleteburningcanproducecarbonmonoxide. Vaporswillbereleasedabove flashpointandwhenmixedwithair, can burnorexplodeinconfinedspaceifexposedto sources ofignition. Thisproducthasbeendetermined to beaflammableliquidper theOSHAHazardCommunicationStandard,andshouldbehandledaccordingly.Vaporsmay travelalongthegroundor bemovedbyventilationandignitedbymanysourcessuch aspilotlights,sparks,electricmotors,staticdischarge,orother ignitionsourcesatlocationsdistantfrom materialhandling.Flashbackcanoccur alongvapor trail.

ForadditionalfirerelatedinformationseeNFPA30or NorthAmericanEmergencyResponseGuide115.

Specific methods:Ifpossible,stopflowofproduct.

UnusualFire orExplosionHazards

Donotmixorstorewithstrongoxidants.Donotstoreorpournearsourcesofignition.Donotpressurize,cut,heat,weld,orexposeemptycontainerstosourcesofignition.Vaporsareheavierthanairandmaytravelaconsiderabledistancetoasourceofignitionandflashback.Runofftosewerorlowlyingareasmaycreatefireor explosionhazard.

FIREFIGHTINGEQUIPMENT:

UseofSCBAinenclosedor confinedspaces,or asotherwiseneeded.

HazardousCombustionProducts

Fumes,smoke,carbonmonoxideandotherdecompositionproducts,inthecaseofincompletecombustion.

ExtinguishingMedia

SMALL FIRES:Anyextinguishersuitable forClass Bfires,drychemical,CO2,waterspray,firefighting foam, orgaseousextinguishing agent.

LARGEFIRES:Waterspray, fog orfirefighting foam.Watermaybe ineffectiveforfighting the fire, but maybe used to coolfire-exposedcontainers.

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For massivefiresthe useofunmannedhoseholdersor monitornozzlesmaybeadvantageoustofurther minimizepersonnelexposure.Major firesmayrequirewithdrawal,allowingthetanktoburn.Largestoragetankfirestypically requirespeciallytrainedpersonnelandequipmenttoextinguish thefire,oftenincluding the needforproperly appliedfire-fightingfoam.Refer toNAERGGuide128.

Furtherinformation:

Smallfires in the incipient(beginning)stage maytypicallybe extinguished using handheldportable fire extinguishersand otherfirefighting equipment. Firefighting activitiesthat mayresultin potentialexposure to high heat,smoke ortoxicby-productsofcombustion shouldrequire NIOSH/MSHA-approved pressure-demand self-contained breathing apparatuswithfullface piece and full protective clothing.Isolate area around containerinvolved in fire.

Cooltanks,shells,andcontainersexposed to fire and excessive heatwithwater.Formassive firesthe use ofunmanned hose holdersormonitor nozzles maybe advantageoustofurtherminimize personnelexposure.Majorfiresmayrequirewithdrawal,allowing thetank to burn.Large storage tank fires typicallyrequire speciallytrainedpersonnelandequipmentto extinguishthefire,often includingthe need for properlyapplied firefightingfoam.

Evacuate nonessentialpersonneland remove orsecure allignition sources.Considerwinddirection;stayupwind and uphill,ifpossible.Evaluate the direction ofproducttravel,diking,sewers,etc.toconfirmspillareas.Product mayrelease substantialamountsofflammablevaporsand gases(e.g., methane,ethane,andpropane),atorbelowambienttemperaturedepending on source and processconditions and pressure.

RecoveryandNeutralization

Controlsourceofspillageifpossible todoso safely.

Environmentalprecautions: Trytostoprelease.

Prevententryintowaterways,sewers,basements,confined areas,workpits, oranyplacewhereitsaccumulation canbe dangerous.

Cleanupmethods:

Takeupwithsandor otheroilabsorbingmaterials.Carefully shovel,scoopor sweepupinto a wastecontainerforreclamationor disposal.

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EnvironmentalPrecautions

Protectbodiesofwaterbydiking,absorbents,orabsorbentboom,ifpossible.Do notflushdown sewerordrainagesystems, unlesssystemisdesigned and permitted to handle suchmaterial.The use offirefightingfoam maybe useful in certain situationsto reduce vapors.The properuse ofwaterspraymayeffectivelydisperse productvaporsorthe liquid itself,preventing contactwithignition sourcesorareas/equipment thatrequire protection -do notdischarge solidwaterstreampatternsinto the liquid resulting in splashing.

PersonalPrecautions andProtectiveEquipment

Responseandclean-upcrewsmustbeproperlytrainedandmustutilizeproperprotectiveequipment(seeSection 8).

HandlingProcedures

ComplywithallapplicableEPA,OSHA,NFPAand consistentstateandlocalrequirements.Use appropriategrounding and bonding practices.

Keepawayfrom flame,sparks,andexcessivetemperatures.Storeonlyinapprovedcontainers.Bondandgroundcontainers.Useonlyinwellventilatedareas.

Special slowloadproceduresfor "switchloading" mustbe followed to avoid thestaticignitionhazardthatcan existwhenthisproductisloadedintotankspreviouslycontaininglowflash pointproducts(suchasgasoline) -seeAPIPublication2003,"ProtectionAgainstIgnitionsArisingOutOfStatic,LightningandStrayCurrents.”

Requirementsfor storageareasandcontainers:

Keepawayfrom flame,sparks,excessivetemperaturesandopenflame.Useapprovedcontainers.Keepcontainersclosedandclearly labeled.Emptyor partiallyfullproductcontainersorvesselsmaycontainexplosivevapors.Donotpressurize,cut,heat,weldor exposecontainerstosourcesofignition.Storeina well-ventilatedarea.

STORAGE:

Amplefirewatersupplyshouldbeavailable.Afixedsprinkler/delugesystemisrecommended.

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Segregatefrom oxidant gasesandotheroxidantsinstore.Keepcontainerbelow122°F(50°C) in a wellventilatedplace.Outsideor detachedstoragepreferred.Storagecontainersshouldbegroundedandbonded.

Handlecontainers withcare.Openslowlyinorder tocontrolpossiblepressurerelease.Useonlyproperlyspecifiedequipmentwhichissuitable for thisproduct,itssupplypressureandtemperature.Contactyoursupplierifindoubt.

Thisstorageareashouldcomply withNFPA30"Flammableand CombustibleLiquidCode".Avoidstoragenearincompatiblematerials.

WORK/HYGIENICPRACTICES

Emergency eyewashcapabilityshouldbeavailablein the vicinity ofanypotentialsplashexposure.

Usegood personalhygienepractices.Wash handsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donoteat,drinkor smokeinareas ofuseor storage.

Incompatibilities

Avoidheat,sparks,flameandstaticelectricity.

Maybeignitedbyopenflamesorother hightemperaturesources.Avoidstrongoxidizers.

Component ExposureLimits

Ingredient / OSHAPEL / ACGIHTWA / NIOSHRELTWA
Petroleumdistillates / 400ppm(1600mg/m3) / 1000 ppm (1800mg/m3) / 350mg/m3TWA
1800mg/m3Ceiling(15min)
Benzene / 0.5ppm
5ppmSTEL
ActionLevel;1ppm / 0.5ppm
2.5ppmSTEL / 0.1ppm
1ppmSTEL

PersonalProtectiveEquipment:Respiratory

A NIOSH/ MSHA-approved air-purifying respirator with organic cartridges or self-containedbreathingapparatus(SCBA)maybepermissibleundercertaincircumstances

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whereairborneconcentrationsareormaybeexpectedtoexceedexposurelimitsorforodororirritation.

PersonalProtectiveEquipment:Skin and Body

Personalprotectiveequipmentforthe body shouldbeselectedbasedonthetaskbeingperformedandtherisks involvedandshouldbeapprovedbya specialistbefore handlingthisproduct.

Chemicalprotectiveclothingsuchas ofE.I.DuPontTyChem®,Saranex®or

equivalentrecommendedbasedondegreeofexposure.Note:Theresistanceofspecificmaterialmayvaryfromproducttoproductaswellaswithdegreeofexposure.Consultmanufacturer specificationsfor further information.

Recommended:chemicalgoggles,leatherorimpermeablegloves,bootsandwholebodyprotection.

EyeProtection

Usechemicalsafetygoggles and/ora fullfaceshield.

HygieneMeasures

Emergencyeyewashandsafetyshowercapabilityshouldbeavailableinthenearproximitytooperationspresentingapotentialsplashexposure.Usegoodpersonalhygienepractices.Avoidrepeatedand/orprolongedskinexposure.Washhandsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donotuseasacleaningsolventontheskin.Donotusegasolineorsolvents(naphtha,kerosene,etc.)forwashingthisproductfrom exposedskinareas.Waterlesshandcleanersareeffective.

Promptlyremovecontaminatedclothingandlaunderbeforereuse.Usecarewhenlaunderingto preventtheformationofflammablevaporswhichcouldigniteviawasherordryer.Consider theneedtodiscardcontaminatedleather shoesandgloves.

ENGINEERINGCONTROLS

Ventilation:Useadequatelocalor generalexplosionproofventilation tomaintaintheconcentrationoffumesinthe workingenvironmentwellbelowrecommendedoccupationalexposurelimits.Supplysufficientreplacementair tomakeupfor air removedbythe exhaustsystem.

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Appearance: / Thick,darkyellowtobrownorgreenishblack / Odor: / CharacteristicHydrocarbonodor
PhysicalState: / Liquid / pH: / N/A
VaporPressure: / Variable / VaporDensity: / 3 – 5Typical
BoilingPoint: / >176⁰F(>80⁰C) / MeltingPoint: / ND
Solubility(H2O): / Insoluble to lightlysoluble / SpecificGravity: / 0.7 –0.9
EvaporationRate: / Variable / VOC: / N/A
Octanol/H2OCoeff.: / ND / FlashPoint: / >73⁰F( >23⁰C)
FlashPointMethod: / ClosedCup / UpperFlammabilityLimit (UFL): / ND
LowerFlammabilityLimit(LFL): / ND / BurningRate: / ND
AutoIgnition: 259⁰F (498⁰C)

ChemicalStability

This is a stable material under normal conditions of use and at normaltemperaturesand pressures.

ConditionstoAvoid

Heat,flames,ignitionsources,directsunlight, and incompatibles.

Incompatible Products

Incompatiblewithoxidizing agents andcopper.Explosionhazardwhenexposedtonickelcarbonyl/oxygen mixtures.

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HazardousDecompositionProducts

Carbonmonoxide,carbondioxideandnon-combustedhydrocarbons(smoke)arepossiblehazardousdecomposition products.

A:GeneralProduct Information

Component Carcinogenicity:Acute:

Petroleum distillates (naphtha): Oralrat>4300mg/kgLD50

Dermalrabbit>2000 mg/kg LD50

Benzene (71-43-2):Inhalation rat13050-14380 ppm4 hrLC50

Oralrat1800mg/kgLD50

PotentialHealthEffects: Skin ContactProperty:Practicallynon-toxicifabsorbedfollowing acute (single)exposure.Maycause skin irritationwith prolonged orrepeatedcontact.

Liquidmaybe absorbedthrough the skin in toxic amountsiflarge areasofskin are exposedrepeatedly.

Rare,precancerouswartsontheforearms,backsofhandsandscrotumhavebeenreported fromprolonged orrepeated skin contact.

PotentialHealthEffects:EyeContactProperties:Contactwitheyesmaycausemoderate to severe irritation.

PotentialHealthEffects:Inhalation:Excessiveexposuremaycauseirritationstothenose,throat,lungsandrespiratorytract.Centralnervoussystem(brain)effectsmayincludeheadache,dizziness,lossofbalanceandcoordination,unconsciousness,coma,respiratoryfailure,and death.

Simpleasphyxiant:Actsbydisplacingoxygeninthelungstherebydiminishingthesupplyofoxygenavailabletothebloodandtissues.Symptomsincludeshortnessofbreath,rapidheartrate,incoordination,lethargy,headaches,nausea,vomiting,anddisorientation.Continuedlackofoxygenmayresultinconvulsions,lossofconsciousness and death. Since exercise increases the tissue need for oxygen,

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symptomswilloccurmorequicklyduringexertioninanoxygendeficientenvironment.Oxygeninenclosedspacesshould be maintained at21 percent byvolume.

Exposureto highconcentrationsmycausecardiacsensitization.

PotentialHealthEffects:Ingestion:Ingestionmaycause gastrointestinaldisturbances,includingirritation,nausea,vomitinganddiarrhea,andcentralnervoussystem(brain)effectssimilartoalcoholintoxication.Inseverecases,tremors,convulsions,lossofconsciousness,coma,respiratoryarrest,anddeath mayoccur.

ReproductiveToxicity:NoData.

SpecifiedTarget OrganGeneralToxicity:(SingleExposure) NoData

SpecifiedTarget OrganGeneralToxicity:Maycausedamagetoorgans (liver,kidneys,blood,nervoussystemandskin) throughprolongedor repeatedexposure.

Carcinogenicity:Maycausecancer.

Studieshaveshownthatsimilarproductsproduceskintumorsinlaboratoryanimalsfollowingrepeatedapplicationswithoutwashingorremoval.

Thesignificanceofthisfindingtohumanexposurehasnotbeendetermined.Otherstudieswithactiveskincarcinogenshaveshownthatwashingtheanimal'sskinwithsoapandwaterbetweenapplicationsreducedtumorformation.

Thisproductcontainsbenzene.Humanhealthstudiesindicatethatprolongedand/orrepeatedoverexposuretobenzenemaycausedamagetotheblood-formingsystem(particularlybonemarrow),andseriousblooddisorderssuchasaplasticanemiaandleukemia.

BenzeneislistedasahumancarcinogenbytheNTP,IARC,OSHAandACGIH.

Mutagenicity:Maycausegeneticdefects.Somecrude oilsandcrudeoilfractions havebeenpositiveinmutagenicitystudies.

TeratogenicityThecomponentsofthisproductarenotreportedtocauseteratogeniceffectsinhumans.Basedonbestcurrentinformation,thereisnoknownteratogenicityassociatedwiththisproduct.

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GeneralProductInformation

Keepoutofsewers,drainageareasandwaterways.Reportspillsandreleases,asapplicable,underFederaland Stateregulations.

Eco toxicity:

Petroleum distillates (naphtha)
TestSpecies / Conditions
96 HrLC50 Salmo gairdneri / 258mg/L [static]
24 HrEC50 Daphnia magna / 36mg/L
48 HrEC50 Daphnia magna / <0.26mg/L[Static]
Benzene
TestSpecies / Conditions
96 HrLC50 Pimephalespromelas / 10.7-14.7mg/L [flow-through]
96 HrLC50 Oncorhynchusmykiss / 5.3mg/L[flow-through]
96 HrLC50 Lepomismacrochirus / 22.49mg/L [static]
96 HrLC50 Poecilia reticulata / 28.6mg/L[static]
96 HrLC50 Pimephalespromelas / 22330-41160 μg/L [static]
96 HrLC50 Lepomismacrochirus / 70000-142000 μg/L [static]
72 HrEC50 Pseudokirchneriella subcapitata / 29mg/L
48 HrEC50 Daphnia magna / 8.76 - 15.6mg/L[Static]
48 HrEC50 Daphnia magna / 10mg/L

Persistence andDegradability:

Thehydrocarbonsin thismaterialare expectedtobeinherentlybiodegradable.Inpractice,hydrocarbongasesarenotlikelyto remain insolutionlong enough forbiodegradation tobea significantlossprocess.

BioaccumulativePotential: Noadditionalinformation available.

Mobilityin Soil:No additionalinformation available.

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Waste DisposalInstructions

Canbeincinerated according to Federal,State,andlocalregulations.

CleanupConsiderations: ThisproductasproducedisnotspecificallylistedasanEPARCRAhazardouswasteaccording tofederalregulations(40CFR261).

Thismaterialanditscontainermustbe disposedofin asafeway.

It istheresponsibilityoftheuser todetermineifdisposalmaterialishazardousaccording tofederal,stateandlocalregulations.

It istheresponsibilityoftheuser todetermineifdisposalmaterialishazardousaccording tofederal,stateandlocalregulations.

DisposalRegulatoryRequirements:

Refer tolatestEPAorstateregulationsregarding properdisposal.

DOTInformation:

UNNumber:UN1267

UNProper Shipping Name:PetroleumCrudeOil

TransportHazard:3

Packing Group: 1

LandTransportADR/RIDandGGVS/GGVE(CrossBorder / Domestic)

14.1 UNNo.: 1267

14.2UNProperShippingName:Petroleum HeavyCrudeOil,Flammable,Toxic

Technicalname: PetroleumCrude Oil

14.3Transport HazardClass: 3

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14.4Packing group : IDanger label(primaryrisk): 3

Danger label(subsidiaryrisk): 6.1

14.5Environmentalhazards:Yes

14.7TransportinBulkaccording to AnnexII ofMARPOL 73/78 and theIBCCode

RID

14.1 UNNo.: 1267

14.2UNProperShippingName:Petroleum HeavyCrudeOil,Flammable,Toxic

Technicalname: PetroleumCrude Oil

14.3Transport HazardClass: 3

14.4Packing group : IDanger label(primaryrisk): 3

Danger label(subsidiaryrisk): 6.1

14.5Environmentalhazards:Yes

14.7TransportinBulkaccording to AnnexII ofMARPOL 73/78 and theIBCCode

Seatransport (IMDGCode):

14.1 UNNo.: 1267

14.2UNProperShippingName:Petroleum HeavyCrudeOil,Flammable,Toxic

Technicalname: PetroleumCrude Oil

14.3Transport HazardClass: 3

14.4Packing group : IDanger label(primaryrisk): 3

Danger label(subsidiaryrisk): 6.1

14.5Environmentalhazards:Yes

14.7TransportinBulkaccording to AnnexII ofMARPOL 73/78 and theIBCCode

Inlandwaterwaystransport (ADN):

14.1 UNNo.: 1267

14.2UNProperShippingName:Petroleum HeavyCrudeOil,Flammable,Toxic

Technicalname: PetroleumCrude Oil

14.3Transport HazardClass: 3

14.4Packing group : IDanger label(primaryrisk): 3

Danger label(subsidiaryrisk): 6.1

14.5Environmentalhazards:Yes

14.7TransportinBulkaccording to AnnexII ofMARPOL 73/78 and theIBCCode

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USfederalregulations:

Anyspilloruncontrolledreleaseofthisproduct,includinganysubstantialthreatofrelease,maybesubjecttofederal,stateand/localreportingrequirements.Thisproductand/oritsconstituentsmayalsobesubjecttootherregulationsatthestateand/orlocallevel.Consultthoseregulationsapplicabletoyour facility/ operation.

ComponentAnalysis

SARASECTION 313-SUPPLIERNOTIFICATION

Thismaterial contains one or moreofthefollowing chemicalsrequired to be identified underSARASection302(40CFR355AppendixA),SARASection313(40CFR372.65)and/or

CERCLA(40 CFR302.4).

Benzene
SARA313 / 0.1%deminimisconcentration
CERCLA / 10lb.finalRQ(receivedanadjustedRQof10lbs.basedonpotentialcarcinogenicity inanAugust14,1989finalrule);4.54kgfinalRQ(receivedanadjustedRQof10lbs.basedonpotentialcarcinogenicityinanAugust14,1989finalrule)

Thisproductcontains the following toxicchemicalssubjectto the reporting requirementsofsection 313 ofthe EmergencyPlanning and CommunityRight-To-KnowAct(EPCRA)of1986 and of40 CFR372:

Ingredientname (CASnumber) / Concentration percentbyweight
Benzene (71-43-2) / <0.1–2.0

TheCERCLAdefinitionofhazardoussubstancescontains a“petroleumexclusion”clausewhichexemptscrudeoil.Fractionsofcrudeoil,andproducts(bothfinishedandintermediate)fromthecrudeoilrefiningprocessandanyindigenouscomponentsofsuchfromtheCERCLASection103reportingrequirements.However,otherfederalreportingrequirements,includingSARASection304,aswellastheCleanWaterActmaystillapply.

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SDS-0020

TSCAStatus:On TSCAInventory

DSLStatus:Allcomponentsofthisproduct areon theCanadianDSLlist.

SARA311/312 FormR –Reporting Requirementsand Supplier Notification:

Component / Weight % / FireHazard / Suddenreleaseof pressure / Reactive / Immediate(acute)healthhazard / Delayed(chronic)healthhazard
PetroleumCrudeOil / 100 / Yes / No / No / Yes / Yes

State RegulationsComponentAnalysis-State

Thefollowing componentsappearon one ormore ofthefollowing state hazardoussubstanceslists:

Component / CAS# / CA / MA / MN / NJ / PA / RI
Petroleumdistillates(naphtha) / 8002-05-9 / No / Yes / Yes / Yes / Yes / No
Benzene / 71-43-2 / Yes / Yes / Yes / Yes / Yes / No

Thefollowing statement(s)are provided underthe California Safe DrinkingWaterand ToxicEnforcementActof1986 (Proposition 65):

WARNING!Thisproductcontains a chemicalknown to the state ofCalifornia to causecancer.

WARNING!ThisproductcontainsachemicalknowntothestateofCaliforniatocausereproductive/developmentaleffects.

ComponentAnalysis-WHMISIDL

The following components are identified under the Canadian Hazardous Products ActIngredientDisclosure List:

Component / CAS# / Minimumconcentration
Benzene / 71-43-2 / 0.1%

ComponentAnalysis-Inventory

Component / CAS# / TSCA / CAN / EEC
Petroleumdistillates(naphtha) / 8002-05-9 / Yes / DSL / EINECS
Benzene / 71-43-2 / Yes / DSL / EINECS
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HeavyCrudeOil(Canadian) / Supersedes:N/A
SDS-0020

DISCLAIMEROFLIABILITY:Beforeusingthisproductinanynewprocessorexperiment,a thoroughmaterialcompatibilityand safetystudyshouldbe carriedout.

Thisdocumentisgeneratedforthepurposeofdistributinghealth,safety,andenvironmentaldata.

InformationiscorrecttothebestofourknowledgeatthedateoftheSDSpublication.Itisnotaspecificationsheetnorshouldanydisplayeddatabeconstruedasaspecification.

Theinformationonthiswasobtainedfromsourceswhichwebelievearereliable.However,theinformationisprovidedwithoutanywarranty,expressedorimplied,regardingitscorrectness.Someinformationpresentedandconclusionsdrawnhereinarefromsourcesotherthandirecttestdataonthesubstanceitself.Theconditionsormethodsofhandling,storage,useanddisposaloftheproductarebeyondourcontrolandmaybebeyondourknowledge.Forthisandotherreasons,wedonotassumeresponsibilityandexpresslydisclaimliabilityforloss,damage,orexpensearisingoutoforinanywayconnectedwithhandling,storage,use,ordisposalofthisproduct.Iftheproductisusedasacomponentinanotherproduct,thisSDSinformationmaynotbeapplicable.