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WHMIS / PersonalProtectionEquipment / TDG(Ground)

Product identifier

Tradename:Diesel

SDSNr:SDS-0006

Chemicaldescription:Hydrocarbonmixture

CASNo:#1Diesel68334-30-5

#2Diesel68476-34-6

EC No:231-159-6

Registration-No:Registrationdeadline notexpired.

Use:Fuelforpropulsion,generation, orheating.

Companyidentification: FreepointCommodities, LLC

58CommerceRoad

Stamford,Ct.06902

E-Mailaddress(competent person):Lou Santore

LouSantore[]

Emergencytelephonenumber:Withinthe U.S.or Canada:1800 4249300

Outside the U.S. and Canada: +1 703 527 3887(collectcallsaccepted)

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MSDSprepared by:PaulePatterson,ENERCONServices, Inc.

Thispreparationisnotclassifiedashazardousaccording to29CFR1910-1200.

GHSClassification:

Flammable Liquids - Category4Carcinogenicity- Category2

SpecificTargetOrgan Toxicity(SingleExposure) –Category3Aspiration Hazard–Category1

Acute AquaticToxicity –Category3

GHSLABELELEMENTS

Symbol(s)

SignalWord

Warning

CLPHazardStatements:

.

HEALTHHAZARDS:

H227:Combustibleliquid.

H304:Maybefatal ifswallowedorentersairways.H336:Maycausedrowsiness or dizziness.

H351:Suspectedofcausing cancer.

ENVIRONMENTALHAZARDS:

H402:Harmfulto aquaticlife.

CLPPrecautionarystatementsPrevention :

P261:Avoidbreathing dust /fume/ gas /mist/ vapors / spray.P281:Wearprotectiveclothing.

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P301+310:IFSWALLOEDImmediatelycallaPOISONCENTERordoctor/physician.

P331:DONOTInducevomiting.

Disposal:

P501:Disposeofcontentsand containerto appropriatewastesite or reclaimer inaccordancewithlocal,state,andnationalregulations.

EC Risk Phrases:

R40:Limitedevidenceofacarcinogeniceffect.R52:Harmfultoaquaticorganisms.

R65:Harmful:maycauselung damageifswallowed.R67:Vaporsmaycausedrowsinessanddizziness.

MolecularWeight: Notapplicableto mixtures

Ingredient / %Weight / OSHAPEL / ACGIHTVL
Diesel / 99.5 / 5 mg/m3(mineraloilmist) / 100mg/m3(vapor/aerosol)
Toulene / 0 – 0.5 / 750mg/m3 / 75 mg/m3
Naphthalene / 0 – 0.5 / 50 mg/m3 / 52 mg/m3

FirstAid:Eyes

Flushwithlukewarm,gentlyflowingwaterforatleastfifteen(15)minuteswhileholdingeyelid(s) open. Immediatelyobtain medicalattention.

FirstAid:Skin

Removeallclothingimpregnatedwithmaterialimmediately.Consulta physician for majorexposuresofinhalationorskincontact.

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FirstAid:Ingestion

DONOTINDUCEVOMITING.Monitorforbreathingdifficulties.Immediatelyseekmedicaladviceandbring acopyof thisSDS.

FirstAid:Inhalation

Keep victimcalm.Removeperson to freshair.Ifpersonisnotbreathing,provideartificialrespiration.Ifnecessary,provideadditionaloxygenonce breathing isrestorediftrained todoso.Seekmedicalattentionimmediately

GeneralFire Hazards

See Section9for FlammabilityProperties.Incompleteburningcanproducecarbonmonoxide.Vapors willbereleasedabove flashpointand whenmixedwithair,canburnorexplodeinconfined spaceifexposedtosourcesofignition.

UnusualFire orExplosionHazards

Donotmixorstorewithstrongoxidants.Donotstoreorpournearsourcesofignition.Donotpressurize,cut,heat,weld,orexposeemptycontainerstosourcesofignition.Vaporsareheavierthanairandmaytravelaconsiderabledistancetoasource ofignitionand flashback.

HazardousCombustionProducts

Fumes,smoke,carbonmonoxideandotherdecompositionproducts,inthecaseofincompletecombustion.

ExtinguishingMedia

SMALLFIRES:

Usefoam,drychemical,CO

,waterfog or vaporizingliquid(Halon).Keeppersonnel

2

removedfromand up-windoffire.Cooladjacentstructuresandstoragedrumswith

waterspray. Evacuatearea.

Preventrunofffromfirecontroldilutionfromenteringstreamsordrinkingwater supply.Withdrawimmediatelyintheeventofrisingsoundfrom ventingsafetydeviceor anydiscolorationofstoragetankduetofire.

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LARGEFIRES:

Usefoam,drychemical,CO

,waterfog or vaporizingliquid(Halon).Keeppersonnel

2

removedfromand up-windoffire.Cooladjacentstructuresandstoragedrumswith

waterspray. Evacuatearea.

Preventrunofffromfirecontroldilutionfromenteringstreamsordrinkingwater supply.Withdrawimmediatelyintheeventofrisingsoundfromventingsafetydeviceoranydiscolorationofstoragetankdueto fire.

RecoveryandNeutralization

Controlsourceofspillageifpossibletodososafely. Cleanupspilledmaterialimmediately.

Materials andMethodsforClean-Up

Wash spillagesinto an effluenttreatmentplant or proceed asfollows:

Contain andcollectspillagewithnon-combustible,absorbentmateriale.g.sand,earth,vermiculiteor diatomaceousearthandplaceincontainerfordisposalaccording tolocalregulations.

Usespark-prooftoolsand explosion-proofequipment.

Disposeofviaalicensedwastedisposalcontractor.Contaminated absorbentmaterialmayposethe same hazardasthespilledproduct.

Donotemptyinto drains or theaquaticenvironment. Observelocal,state,andfederalgovernmentalregulations.

PersonalPrecautions andProtectiveEquipment

Responseandclean-upcrewsmustbeproperlytrainedandmustutilizeproperprotectiveequipment(seeSection 8).

EnvironmentalPrecautions

LANDSPILL:

Avoiddispersalofspilledmaterialandrunoffandcontactwithsoil,waterways,drainsandsewers.Informthe relevantauthoritiesif theproducthascausedenvironmentalpollution(sewers,waterways,soilorair).

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Shutoffandeliminateallignitionsources.Keeppeopleaway.Removeleakingcontainerstoa safearea.Containandremovebymechanicalmeans.Addsand,earthorother suitableabsorbent to spillareathan scrapeoff theground.Guardagainstcontaminationofwatersupplies.Reportspillstoappropriateauthorities.Disposeofinaccordance withFederal,StateandLocalregulations

WATERSPILL:

Spillmayberemovedfromwater withmechanicaldredgesor lifts.Reportspillstoappropriateauthorities.DisposeofinaccordancewithFederal,StateandLocalregulations.

HandlingProcedures

ComplywithallapplicableEPA,OSHA,NFPAand consistentstateandlocalrequirements.Use appropriategrounding and bonding practices.

Ground andbondalltransferand storage equipment.Drumsmustbegrounded/bonded/equippedwith self- closing valves, pressurevacuumbungsand flamearrestors.

Keep awayfrom ignitionsources.

Storein acool,well-ventilatedlocation.Outsideordetachedstorageispreferred.

Donotstore nearfoodstuffs.

WORK/HYGIENICPRACTICES

Emergency eyewashcapabilityshouldbeavailablein the vicinity ofanypotentialsplashexposure.

Usegood personalhygienepractices.Wash handsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donoteat,drinkor smokeinareas ofuseor storage.

Incompatibilities

Strongacids,alkaliesandoxidizers. Avoidheat,sparks,flameandstaticelectricity.Maybeignitedbyopenflamesorother hightemperaturesources.

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Component ExposureLimits

Ingredient / OSHAPEL / ACGIHTVL
Diesel / 5 mg/m3(mineraloilmist) / 100mg/m3(vapor/aerosol)
Toulene / 750mg/m3 / 75 mg/m3
Naphthalene / 50 mg/m3 / 52 mg/m3

PersonalProtectiveEquipment:Respiratory

MSHA/NIOSHapproveddustrespirator.Appropriaterespiratordependsupontypeand magnitudeofexposure.

ANIOSH/MSHA-approvedair-purifyingrespiratormaybepermissibleundercertaincircumstanceswhereairborneconcentrationsareormaybeexpectedtoexceedexposure limitsorfor odor or irritation.

PersonalProtectiveEquipment:Skin and Body

ChemicalprotectiveclothingsuchasofE.I.DuPontTyChem®,Saranex®orequivalentrecommendedbasedondegreeofexposure.Note:Theresistanceofspecificmaterialmayvaryfromproducttoproductaswellaswithdegreeofexposure.Consultmanufacturer specificationsforfurther information.

EyeProtection

Usechemicalsafetygoggles and/ora fullfaceshield.

HygieneMeasures

Emergencyeyewashandsafetyshowercapabilityshouldbeavailableinthenearproximitytooperationspresentingapotentialsplashexposure.Usegoodpersonalhygienepractices.Avoidrepeatedand/orprolongedskinexposure.Washhandsbeforeeating,drinking,smoking,orusingtoiletfacilities.Donotuseasacleaningsolventontheskin.Donotusegasolineorsolvents(naphtha,

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kerosene,etc.)forwashingthisproductfromexposedskinareas.Waterlesshandcleanersare effective.

Promptlyremovecontaminatedclothingandlaunderbeforereuse.Usecarewhenlaunderingtopreventtheformationofflammablevaporswhichcouldigniteviawasherordryer.Considertheneedtodiscardcontaminatedleathershoesandgloves.

ENGINEERINGCONTROLS

Ventilation:Useadequatelocalor generalventilation tomaintain theconcentrationoffumesinthe workingenvironment wellbelowrecommendedoccupationalexposurelimits.Supplysufficientreplacementair tomakeupforair removedbytheexhaustsystem.

Appearance: / Reddish metal / Odor: / Strong hydrocarbonodor
PhysicalState: / Liquid / pH: / ND
VaporPressure: / 2.1 to 2.6 Torrat 70 ⁰F(21⁰C) / VaporDensity: / N/D
BoilingPoint: / 320 ⁰F(160⁰C) / MeltingPoint: / 64.4⁰F(18 ⁰C)
Solubility(H2O): / Negligible / SpecificGravity: / 8.94
EvaporationRate: / Slow,varieswithconditions / VOC: / ND
Octanol/H2OCoeff.: / ND / FlashPoint: / 125.6⁰F(52 ⁰C)
FlashPointMethod: / TCC / UpperFlammabilityLimit (UFL): / 6.0–7.5%
LowerFlammabilityLimit (LFL): / 0.6 –1.3% / BurningRate: / ND
AutoIgnition:489to 545⁰F (254⁰C - 285⁰C)
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ChemicalStability

This is a stable material under normal conditions of use and at normaltemperaturesand pressures.

HazardousReactionPotential

HazardousPolymerizationwill not occur.

ConditionstoAvoid

Heat,flames,ignitionsourcesandincompatibles.

Incompatible Products

Incompatiblewithstrongoxidizingagentssuchashydrogenperoxideandstrongacidssuchashydrochloricacid.Alsoincompatiblewithzinc,magnesium,andcadmiumchlorates.Maybeignitedbyopenflamesorotherhightemperaturesources.

HazardousDecompositionProducts

Thermaldecompositionmayreleasevarioushydrocarbonsand hydrocarbonderivativesincluding carbon dioxide,water,organicacids,and aldehydes.

EmergencyOverview:

WARNING! COMBUSTIBLE. CAUSES RESPIRATORY TRACT, EYE AND SKINIRRITATION.HARMFUL IF INGESTED.ASPIRATIONHAZARD.

AcuteToxicity

OralLD50: 5000 mg/kg (rat)

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A:GeneralProduct Information

Combustibleliquid.Keepawayfromheat,sparksandflame.Avoidexposure-obtainspecialinstructionsbeforeuse.Donotbreathevaporormist.Donotingest.Avoidcontactwitheyes,skinandclothing.Washthoroughlyafterhandling.

B:ComponentAnalysis- LD50/LC50

Notclassified

PotentialHealthEffects: Skin ContactProperty

Maycauseskinirritation.

PotentialHealthEffects: EyeContact Properties

Eyeirritation.

PotentialHealthEffects: Ingestion

Irritation,giddiness,vertigo,headache,anestheticstupor,CNSdepression,comaand death.

PotentialHealthEffects: Inhalation

Mistorvapormaycauserespiratorytractirritation.CNSdepressant.Highlevelsmaycausegiddiness,headache,dizziness,nausea,vomiting,andlossofcoordination,narcosis,stupor,coma,andunconsciousness.

ChronicToxicity:

Inhalation:Prolonged exposuremaycause dizziness,weakness,weightloss,anemia,nervousness,and paininthelimbs,peripheralnumbness,andparesthesia.Renalfailureispossible.Degenerativechangesofliver andkidneysmayoccur after prolongedexposuretohighconcentrations.

SkinContact:Repeatedor prolonged exposuremaycauseirritation,dermatitis,andarash ofpimplesandspots.

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Carcinogenicity

A:GeneralProduct Information

For Fuel,Diesel:

ACGIH: A3- Animalcarcinogen.“Availableevidence suggeststhattheagentisnot likelytocausecancer inhumansexceptunder uncommonorunlikelyroutesor levels of exposure.”

IARC: 3-Theagent(mixture,exposurecircumstance) isnotclassifiable as to itscarcinogenicitytohumans.

Reproductivetoxicity:

Thisproductisnotreportedtohaveanyreproductivetoxicityeffects.

Mutagenicity:This productisnotreported to haveanyreproductivetoxicityeffects.

TeratogenicityThecomponentsofthisproductarenotreportedtocauseteratogeniceffectsinhumans.Basedonbestcurrentinformation,thereisnoknownteratogenicityassociatedwiththisproduct.

Specific Target Organ Toxicity - Single Exposure: May cause drowsiness ordizziness.

Specific Target OrganToxicity- RepeatedExposure:Nodata available.

Ecotoxicity:

Verytoxictoaquaticlifewithlonglastingeffects.96hLC50Pimephalespromelas-35mg/L(flowthrough)

Persistence andDegradability:Major constituentsareinherentlybiodegradable.

BioaccumulativePotential: Doesnotbioaccumulate.

Mobilityin Soil:Notmobile.

Otheradverseeffects:Noinformationavailable.

Additionalecologicalinformation:No additionalinformation available

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Waste DisposalInstructions

CleanupConsiderations: ThisproductasproducedisnotspecificallylistedasanEPARCRAhazardouswasteaccording tofederalregulations(40CFR261).However,whendiscardedordisposedof,itmaymeetthe criteria ofa"characteristic" hazardouswaste.Thismaterialcouldbecome ahazardouswasteifmixedorcontaminatedwith a hazardouswasteorothersubstance(s).

Thismaterialanditscontainermustbe disposedofin asafeway.

It istheresponsibilityoftheuser todetermineifdisposalmaterialishazardousaccording tofederal,stateandlocalregulations.

DisposalRegulatoryRequirements:

Refer tolatestEPAorstateregulationsregarding properdisposal.

DOTInformation:

PackingGroup: III

DOTInformation:

LandTransportADR/RIDandGGVS/GGVE(CrossBorder / Domestic)UNNumber:UN1993

UNProperShippingName: COMBUSTIBLE- LIQUID,N.O.S.(FUEL,DIESEL)

Transport HazardClass(es):3- CombustibleLiquid

MaritimeTransport IMDG/GGVSeaUNNumber:UN1202 UN

ProperShippingName:FLAMMABLELIQUID,N.O.S.(FUEL,DIESEL)

Notregulatedifflashpointis 60CTransport HazardClass(es):3MarinePollutant:Yes

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AirTransport ICAO-TIandIATA-DGRUNNumber:UN1202 UN

ProperShippingName:FLAMMABLELIQUID,N.O.S.(FUEL,DIESEL)

Notregulatedifflashpointis 60C

Transport HazardClass(es):3

Transportin Bulkaccording toAnnexII ofMARPOL73/78andthe IBCCode.

SpecialPrecautionsforUser:Noadditionalinformation

USfederalregulations:

Anyspilloruncontrolledreleaseofthisproduct,includinganysubstantialthreatofrelease,maybesubjecttofederal,stateand/localreportingrequirements.Thisproductand/oritsconstituentsmayalsobesubjecttootherregulationsatthestateand/orlocallevel.Consultthoseregulationsapplicabletoyour facility/ operation.

U.S.FederalRegulations:

TSCA4(a)final testrules:No productslisted.TSCA8(a) PAIR:No productslisted.

UnitedStatesinventory(TSCA8b):Allcomponentsare listed or exempted.TSCA12(b):Noproductslisted.

SARA302/304/311/312extremelyhazardoussubstances:Noproductslisted.SARA302/304 emergencyplanning and notification:Noproductswere found.SARA302/304/311/312hazardouschemicals:Noproductslisted.

SARA311/312MSDSdistribution-chemicalinventory-hazardidentification:Noproductslisted.

CleanWaterAct (CWA)307:EthylbenzeneCleanWaterAct (CWA)311:Ethylbenzene

CleanAirAct(CAA)112accidentalreleaseprevention:Noproductswerefound.CleanAirAct(CAA)112regulatedflammablesubstances:Noproductslisted.CleanAirAct(CAA)112regulatedtoxicsubstances:Noproductswerefound.SARA313FormR–ReportingRequirementsandSupplierNotification:Noproductslisted.

SARA313notifications must not bedetachedfromtheSDSandanycopyingandredistributionoftheSDSshallincludecopyingandredistributionofthenoticeattached tocopiesoftheSDSsubsequentlyredistributed.

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HCSClassification:Combustible liquidCarcinogen

SARA313FormR–ReportingRequirementsandSupplierNotification:Noproductslisted.SARA313notifications mustnotbedetachedfromtheSDSandany copyingandredistributionoftheSDSshallincludecopyingandredistributionofthenoticeattachedtocopiesoftheSDSsubsequentlyredistributed.

StateRegulations:

NewJerseyHazardousSubstances:The following componentsare listed:DieselFuelCaliforniaProp.65: The following componentsarelisted:Ethylbenzene

InternationalLists:

Thisproduct,(anditsingredients) is(are) listedonnationalinventories, or is(are)exempted from being listed,inAustralia(AICS),inEurope (EINECS/ELINCS),in Korea(TCCL),inJapan(METI),in thePhilippines(RA6969.)

DISCLAIMEROFLIABILITY:Beforeusingthisproductinanynewprocessorexperiment,a thoroughmaterialcompatibilityand safetystudyshouldbe carriedout.

Thisdocumentisgeneratedforthepurposeofdistributinghealth,safety,andenvironmentaldata.

InformationiscorrecttothebestofourknowledgeatthedateoftheSDSpublication.Itisnotaspecificationsheetnorshouldanydisplayeddatabeconstruedasaspecification.

Theinformationonthiswasobtainedfromsourceswhichwebelievearereliable.However,theinformationisprovidedwithoutanywarranty,expressedorimplied,regardingitscorrectness.Someinformationpresentedandconclusionsdrawnhereinarefromsourcesotherthandirecttestdataonthesubstanceitself.Theconditionsormethodsofhandling,storage,useanddisposaloftheproductarebeyondourcontrolandmaybebeyondourknowledge.Forthisandotherreasons,wedonotassumeresponsibilityandexpresslydisclaimliabilityforloss,damage,orexpensearisingoutoforinanywayconnectedwithhandling,storage,use,ordisposalofthisproduct.Iftheproductisusedasacomponentinanotherproduct,thisMSDSinformationmaynotbeapplicable.