EMCD
042-18-34.1.23/02-2013 / 18.09.2013
№1edition / Page1 from10
MINISTRY OF SCIENCE AND EDUCATION OF THE REPUBLIC OF KAZAKHSTAN
STATE UNIVERSITY NAMED AFTER SHAKARIM, SEMEY
Document of 3 level by MQS / EMCD / EMCD
042-18-34.1.23/02-2013
EMCD
Syllabusfordiscipline «Physical methods of Chemical research»for students / «18»__09__2013
№ 1edition

EDUCATIONAL-METHODICAL COMPLEX OF DISCIPLINE

«Physical methods of Chemical research»

For the specialty

5B011200– «Chemistry»

SYLLABUS FORSTUDENTS

Semey

2013

Content

1. General provisions

2. Contents and distribution of hours by type of training

3. Guidelines for the study of discipline

4. The format of the course

5. Rate policy

6. Grading policy

7. Literature

GENERAL PROVISIONS

1,1 General information about the teacher and discipline

Akimzhanova Khafiza Gabdulmulicovna, master of pedagogical science, senior teacher

The chair of Chemistry and Geography

Contact Information – phone: 35-05-90, building #3, office № 413

Place of training – lecture room № 406

Number of credits - 2

1.2 Course brief description:The course of Physical methods of Chemical research gives students the opportunity to form the basic knowledge of major characteristics of modern physical-chemical analysis methods used for the identification and quality control of engineering processes of biologically active compounds in the organic and pharmacological production. The course of Physical methods of Chemical research reveals the essence, principles, basic concepts and rules of methods in chemical research.

1.3 The purpose of this course.The purpose of this course is to study the scientific approaches of classificationof physical methods ofanalysis, theabsorptionof molecular analysis, visual methods of quantitative analysis, photocolorimetric methods,electrochemicalmethods of analysis,potentiometry,coulometricmethod,voltammetry, polarography, amperometrictitration, X-rayanalysis,emission spectral analysis, chromatography.

1.4 The main objectives of the course are as follows:

-to extend the knowledge in the usage sphere of the modern physical-chemical methods for the identification and quality control of biologically active compounds in the organic and pharmacological engineering processes;

-to study theoretical basis of physical-chemical methods of analysis;

-to teach students how to use laboratory equipment in a concrete method

1.5 Studying this discipline the student must:

  • activate self study;
  • master elementary techniques of researches of objects.
  • consolidate the obtained knowledge by participating in seminar lessons, studying scientific journals;
  • assess his/her obtained knowledge through examinations and tests.

After the end ofthe disciplinethe student mustpossess the followingknowledge, skills(competencies):

Take notice of

-features ofphysical methods of analysis

-characterizationof spectral andother opticalmethods of analysis

-the basisof electrochemicalmethods of analysis

-chromatographic methods

Be able to

-use thereference andthe scientific and technicalliterature

-identifyspectra of molecules

-construct redoxcouplesand calculatethe electrochemical potential

1.6 Course pre-requisites: the studying of the course "Physical methods of Chemical research" is required necessaryknowledge and skills:

-Theoretical basisof inorganic chemistry - atomic structure, radioactivity, electrolysis

-Analytical Chemistry - quantitative methods of analysis, types of titrations, oxidation-reduction reactions

-Theoretical basisof Organic Chemistry - functional groupsof organic molecules, molecular spectra,the isotopemethod for studying thereactions

1.7 Course post-requisites: knowledge of Physical methods of Chemical research provide the skills needed in the study of:

- Chemical Technology - control over the compositionof the product, qualitative determination ofimpurities

- Chemical Synthesis - interpretationof the spectraof molecules andatoms

- Physical Chemistry - Optical properties ofmaterials, electrochemical potential

- Chemistry of Ground - studythe content ofelements,anions andcationsin the environment

2 CONTENTS AND DISTRIBUTION OF HOURS BY TYPE OF TRAINING

Table 1

№ / Name of the
theme / Hours / Literature
Lec / Lab / PL / OH / SSS
1 / Introduction tophysical andchemical methods of analysis / 1 / - / - / 1 / 5 / 7.1.1, 7.1.2
2 / Opticalmethods of analysis / 5 / - / 8 / 6 / 15 / 7.1.1, 7.1.2
3 / Electrochemical methods of analysis / 5 / - / 7 / 6 / 15 / 7.1.1, 7.1.2
4 / Chromatographicmethods of analysis / 4 / - / - / 2 / 10 / 7.1.1, 7.1.2
Totally / 15 / - / 15 / 15 / 45

3 GUIDELINES FOR THE STUDY OF DISCIPLINE

Laboratory studiespromotesto strengthening of theknowledge by thephysical methods ofchemical research,develops of the student’sindependence andinstillsthe skillsof the experiment.For successfully work in the laboratoryyou must firststudy the theoretical materialfrom textbooks, lecture notesand the manuals on chemicalworkshops. Thisproducesa conscious attitude tothe implementationof experimental techniques and the work will beunderstood.In thechemistry lab workers shouldstrictly follow by thesafety rules and regulationsofthe working with chemicalutensils andappliances.We must learnto usechemical agents, chemical equipment,which are listedin the guidelinesfor the workon the chemicalworkshop. Guidelinesshould not be depriveindependence,and oppositely the following by the orders speeds up the work, prevents possibledamage toequipment,glasswareand reagents.The success of theexperimental worknotdependsonly from thecorrectness of the choiceof working methods,the sequenceof measurement, weight measurements, but also from the correctsystematic recording ofresults.To theimplementation ofthe laboratory work are allowedstudents withadmissionafter verification by teacher the theoretical knowledge on the subject, knowledge by the methodicof laboratoryworkand verification of preparing lab journalto conductentries. After completingthe laboratory workthe student mustbring order toyour workplaceand deliver themon dutyortechnician. After processing theresults in thelab bookthe student mustthe report to teacher.

4 THE FORMAT OF THE COURSE

Forms of training sessions are lectures, laboratory classes. 1 hour of lecture is 50 minutes. 1hour of labs is 100 minutes. Classes are held by schedule. Also independent work of students in the audience and outside the audience are planned. Timetable of students independent work and report on them held by schedule of Chair. Monitoring by the Implementation of independent work is carried out in the forms of an oral interview, homework tasks, test papers, test tasks.

5 RATE POLICY

Administrative requirements to the students in the process of studying

- Inlate forclassare removed: 50points for thelecture
30points for the laboratory work

- Untimelyperform tasksleadsto a lowering ofthe rating10 points.

-Attendance at laboratories is permitted onlyin white coats.

-Compliance withthe safety rulesin the chemicallaboratory.

6 GRADINGPOLICY

Monitoring of students' knowledge is conducted in the forms:

- Current control (is held weekly);

- Boundary control (7 and 15 weeks);

- Final control - exam.

Current control - is the systematic examination of the student's knowledge in lectures, workshops and independent work under the guidance of a teacher. Various types of current control is provides:

- Oral questioning;

- Control of work;

- Homework;

- Tests.

In the process of studying the discipline every kind of student work is evaluated in points.

- Performance and protection of laboratory work - 210 points (7 laboratory works –by 15 points, 7 laboratory works –by 13 points, 1 laboratory works - by 14 points);

- Implementation of control work be the schedule of execution OH - 60 points (12 OH- by 5 points);

- Performance of independent work in the form of SSS - 150 points (2 works –by 45 points, 2 work –by 30 points);

- Boundary control - 120 points (1 RK - 60 points, 2 RC - 60 points).

Total - 540 points.

Distribution of points by the weeks and type of control are presented in Table

Distribution points by the discipline

«Physical methods of Chemical research»

Table 2

Week / Type of control / All points / Comment
1-7 / Seen and preparation for classroom work / 30 / Teacher notes only the absence of the student in the classroom
Execution of practical work (report, protection)
1 / Rules ofWork atfotoelektrokolorimetre / 15 / At the practical lesson
2-5 / Spectrophotometric determination ofmanganeseusinga calibration curve / 15*4 / At the practical lesson
6-7 / Photocolorimetricdeterminationof ironusinga calibration curve / 15*2 / At the practical lesson
Self-study of student
3 / Classificationof physical methods ofanalysis.Features ofphysical methods of analysisPhotometric methods. / 45 / In accordance with the schedule
6 / Visual methodsofquantitativeanalysis. Photocolorimetric methods. Bouguer-Lambert-Beerlaw. / 30 / In accordance with the schedule
Self-study of student with teacher
2-3 / Opticalmethods of analysis / 5*2 / In accordance with the schedule
4-5 / Opticalmethods of analysis / 5*2 / In accordance with the schedule
6-7 / Opticalmethods of analysis / 5*2 / In accordance with the schedule
7 / Boundary control 1-oral colloquium by the lecture materials of 1-7 weeks / 60 / In accordance with the schedule
Total scores of learning outcomes
From 1 to 7 week
8-15 / Seen and preparation for classroom work / 30 / Teacher notes only the absence of the student in the classroom
Execution of practical work (report, protection)
8 / Photocolorimetricdeterminationof ironusinga calibration curve / 13 / At the practical lesson
9-10 / Measuring thepH of thesaltextracts ofsoilsbypotentiometry / 13*2 / At the practical lesson
11-12 / Preparationand measurement ofpHbuffer solutions bypotentiometry / 13*2 / At the practical lesson
13-15 / Potentiometrictitration ofa strong acidstrong base / 13*2
14 / At the practical lesson
Self-study of student
10 / Potentiometry. Electrodesused inpotentiometry.
Types ofpotentiometricdeterminations.
Methods for determiningthe equivalence point.
Coulometric method. / 45 / In accordance with the schedule
14 / Voltammetry, polarography, amperometrictitration. Electro-gravimeter.
The bases of chromatography. The characteristics of chromatography method.
The laboratory equipment.
The Thin-layer chromatography. The gas-liquid chromatography / 30 / In accordance with the schedule
Self-study of student with teacher
9-10 / Electrochemical methods of analysis / 5*2 / In accordance with the schedule
11 / Electrochemical methods of analysis / 5 / In accordance with the schedule
12 / Chromatographicmethods of analysis / 5 / In accordance with the schedule
13-14 / Chromatographicmethods of analysis / 5*2 / In accordance with the schedule
15 / Boundary control 1-oral colloquium by the lecture materials of 8-15 weeks / 60 / In accordance with the schedule
Total scores of learning outcomes
From 8 to 15 week / 300
Total points for the exam / 400
Total points for the academic period / 1000

The examination mark of the discipline is defined as the sum of the maximum progressindicators on the modules,boundary control and final attestation (60%), exam (40%), which is 100%.

A student is admitted to the final control of the discipline, if its total per semester rating score greater than or equal to 50%.

Knowledge and skills of students are evaluated by the following system:

Point-character string ratings system of knowledge

Literal
equivalent / Points / Percent
(%) / Traditional
marking
system
А / 4,0 / 95-100 / excellent
А- / 3,67 / 90-94
В+ / 3,33 / 85-89 / good
В / 3.00 / 80-84
В- / 2,67 / 75-79
С+ / 2,33 / 70-74 / satisfactory
С / 2,00 / 65-69
С- / 1,67 / 60-64
Д+ / 1,33 / 55-59
Д / 1,00 / 50-54
F / 0,00 / 0-49 / unsatisfactory

7 LITERATURE

7.1 Basic literature:

7.1.1 В.П. Васильев. Теоретические основы физико-химических методов анализа. М.:ВШ 1979г.

7.1.2 Ляликов Ю.С. Физико-химические методы анализа М.:ВШ, 1968г.

7.1.3 Казицина А.А. , Куплетская Н.Б. Применение ИК-, УФ- и ЯМР-спектроскопии в органической химии. М.: Высшая школа, 1971, 263с.

7.1.4 Иоффе Б.В., Костиков Р.Р., Разин В.В.. Физические методы определения строения органических соединений. М.: Высшая школа, 1984, 335с.

7.1.5 Филимонов В.Д., Добычина Н.С., Тигнибидина Л.Г. Физико-химические методы исследования структуры и чистоты биологически активных соединений. Томск: 1987, 57с.

7.2 Additionalliterature:

7.2.1 Беллами Л. Инфракрасные спектры сложных молекул. М.: ИИЛ, 1963, 444с.

7.2.2 Прикладная инфракрасная спектроскопия. Под ред. Кендалла Д. М.: Мир, 1970, 376с.

7.2.3Джонстон Р. Руководство по масс-спектрометрии для химиков-органиков. М.: Мир, 1975, 236с.