B.Sc. CHEMISTRY (Hons.) CURRICULUM
(2015 batch)
SCHEME AND SYLLABUS
DEPARTMENT OF CHEMISTRY
B.Sc. CHEMISTRY (Hons.) CURRICULUM
OBJECTIVES:
The course contents have been proposed as per suggestions of the faculty members of department of Chemistry, Manipal University Jaipur. The syllabus contents are duly arranged in such a manner so that the importance is given to requisite intellectual and laboratory skills.
(i) To teach the fundamental concepts of Chemistry and their applications.
(ii) To make students aware of advantages of eco-friendly chemical processes and impact of chemistry on health and environment.
(iii) To enthuse the students for the subject and make them capable of accepting any challenges in chemistry.
(iv) To make students aware of advantages of eco-friendly chemical processes and impact of chemistry on health and environment.
(v) To motivate students to do good research work in chemistry and opt for research career.
(vi) To educate the students with respect to skills and knowledge to practice chemistry and imbibe the concept of sustainable developments.
ELIGIBILITY OF THE CANDIDATES:
Candidates who have passed (10+2) examination of any recognized Board or its equivalent examination with minimum of 45% marks with Physics, Chemistry, Mathematics or Biology as core subjects.
Course Structure of the B.Sc. (Hons) Chemistry Programme (2015-2018)
Major course: Chemistry; Subsidiary: Mathematics/Bio Science/Bio technology; Ancillary: Physics
I Semester / Exam Duration (Hrs) / Relative Weightage (%)Sr.No. / Course Code / Course Name / L / T / P / C / Theory / Practical / CWS / PRS / MTE / ETE / PRE
1 / CY1112 / Inorganic Chemistry-I / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50
2 / CY1113 / Organic chemistry –I / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50
3 / CY1114 / Physical Chemistry-1 / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
4 / CY1132 / Chemistry (Hons.) Laboratory-1 / 0 / 0 / 2 / 1 / 0 / 2 / - / 60 / - / - / 40
5 / MA 1111 / Differential Calculus and Integral Calculus / 3 / 1 / 0 / 4 / 4 / - / 10 / - / 40 / 50 / -
6 / BS1156 / Basic Biology / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
7 / BS1141 / Basic Biology Lab / 0 / 0 / 2 / 1 / - / 2 / - / 60 / - / - / 40
8 / CS 1102 / Fundamental of Computers / 2 / 0 / 0 / 2 / - / - / 10 / - / 40 / 50 / -
9 / EN 1101 / General English / 2 / 1 / 0 / 3 / 3 / 0 / 10 / - / 40 / 50 / -
10 / CS1132 / Fundamental of Computers Laboratory / 0 / 0 / 2 / 1 / - / 2 / - / 60 / - / - / 40
Total / 15 / 6 / 6 / 24
II Semester / Exam Duration (Hrs) / Relative Weightage (%)
Sr.No. / Course Code / Course Name / L / T / P / C / Theory / Practical / CWS / PRS / MTE / ETE / PRE
1. 1 / CY1212 / Inorganic Chemistry-II / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
2. 2 / CY1213 / Organic Chemistry-II / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
3. 3 / CY1214 / Physical Chemistry-II / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
4. / CY1231 / Chemistry (Hons.) Laboratory-II / 0 / 0 / 2 / 1 / 2 / - / 60 / - / - / 40
5. / MA 1211 / Algebra / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
6. 6 / VE1201 / Value Education / 2 / 0 / 0 / 2 / 3 / - / 10 / - / 40 / 50 / -
7. 7 / CY1120 / Environmental Science / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
8. / PY 1211 / Oscillations and wave Optics / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
9. 8 / PY 1231 / Optics Lab / 0 / 0 / 2 / 1 / - / 3 / - / 60 / - / - / 40
Total / 18 / 6 / 4 / 26
III Semester / Exam Duration (Hrs) / Relative Weightage (%)
Sr. No. / Course Code / Course Name / L / T / P / C / Theory / Practical / CWS / PRS / MTE / ETE / PRE
1 / CY 1313 / Inorganic Chemistry-III / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
2 / CY 1315 / Organic Chemistry-III / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
3 / CY 1316 / Physical Chemistry / 3 / 1 / 0 / 4 / 3 / 10 / 40 / 50
4 / CY1331 / Chemistry (Hons.) laboratory-III / 0 / 0 / 4 / 2 / - / 2 / - / 60 / - / - / 40
5 / CY 1332 / Computer application in Chemistry / 0 / 0 / 4 / 2 / 2 / - / 60 / - / - / 40
8 / MA 1311 / Differential Equations / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
7 / MA 1312 / Solid Geometry and Vector Calculus / 3 / 1 / 0 / 4 / 3 / 1 / 10 / - / 40 / 50 / -
Total / 15 / 5 / 8 / 24
IV Semester / Exam Duration (Hrs) / Relative Weightage (%)
Sr.No. / Course Code / Course Name / L / T / P / C / Theory / Practical / CWS / PRS / MTE / ETE / PRE
1 / CY 1413 / Inorganic Chemistry -IV / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
2 / CY 1414 / Organic Chemistry-IV / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
3 / CY 1415 / Physical Chemistry / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
4 / CY 1431 / Chemistry (Hons.) Laboratory-IV / 0 / 0 / 4 / 2 / 0 / 2 / - / 60 / - / - / 40
5 / MA 1411 / Linear Programming Problems and its application / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
5 / MA1412 / Dynamics / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
6 / ***** / Open Elective / 3 / 0 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
Total / 18 / 5 / 4 / 25
V Semester / Exam Duration (Hrs) / Relative Weightage (%)
Sr.No. / Course Code / Course Name / L / T / P / C / Theory / Practical / CWS / PRS / MTE / ETE / PRE
1 / CY 1513 / Chemistry of Biomolecules / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
2 / CY 1514 / Quantum Chemistry and its Application to Molecular Spectroscopy / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
3 / CY 1515 / Green Chemistry / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
4 / CY 1516 / Nuclear and Analytical Chemistry / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
5 / CY 1531 / Chemistry (Hons.) Laboratory-V / 0 / 0 / 4 / 2 / - / 2 / - / 60 / - / 40
6 / CY1570 / Seminar / 0 / 0 / 4 / 2 / - / - / - / 60 / - / - / 40
5 / MA 1511 / Real Analysis / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
6 / MA 1512 / Numerical Analysis and Probability Theory / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
Total / 16 / 6 / 8 / 26
VI Semester / Exam Duration (Hrs) / Relative Weightage (%)
Sr.No. / Course Code / Course Name / L / T / P / C / Theory / Practical / CWS / PRS / MTE / ETE / PRE
1 / CY 1613 / Organic Spectroscopy / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
2 / CY 1614 / Molecular Statistics and photo chemistry / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
3 / CY 1615 / Organometallic Chemistry and Industrial Chemistry / 2 / 1 / 0 / 3 / 3 / - / 10 / - / 40 / 50 / -
4 / CY 1631 / Chemistry (Hons.)Laboratory-VI / 0 / 0 / 6 / 3 / 2 / 60 / - / 40
5 / CY 1670 / Project / 0 / 0 / 6 / 3 / - / - / - / 60 / - / - / 40
6 / MA 1611 / Complex Analysis / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
7 / MA 1612 / Discrete Mathematics Structure / 3 / 1 / 0 / 4 / 3 / - / 10 / - / 40 / 50 / -
Total / 14 / 5 / 12 / 25
L = Number of Lectures hrs/week
P = Number of practical hours/week
CWS: Class Work Sessionals
MTE: Mid-Term Exam
PRE: End Term Practical Exam / T= Number of Tutorials hrs/week
C= Number of Credits.
PRS: Practical Sessionals
ETE: End Term Exam
CY1112 / Inorganic Chemistry-I / [3 1 0 4]
Atomic Structure: Schrodinger’s wave equation, significance of Ψ and Ψ2, four quantum numbers and their significance, radial and angular probability, shapes of s, p, d and f orbitals, fundamental properties of atoms such as atomic volume, the sizes of atoms, ionization energy, electron affinity and their periodic trends; Electronegativity and Polarity of bond: Electronegativity, different scales and methods of determination, dipole moments, percentage of ionic character form dipole moment and electronegativity difference; Valence Bond theory and Molecular Orbital Theory: Valence bond (VB) approach, molecular orbitals (MO) approach of bonding (LCAO Method) bonding in homo-nuclear and hetero-nuclear molecules; The Periodic Table and Chemical Periodicity: The relationship between chemical periodicity and electronic structure of the atom, the long form of the periodic table, classification of elements in s, p, d and f block of elements, diagonal behaviour between elements; Acids-bases: various definitions of acids and bases, a generalized acid-base concept, measurement of acid-base strength, Lewis interactions, Pearson’s HSAB concept.
Text Books:
1. J. D. Lee, Concise Inorganic Chemistry, Blackwell Science, 2008.
2. J. E. Huheey , E. A. Keiter and R. L. Keiter, Inorganic Chemistry: Principles of Structure and Reactivity, Pearson India, 2008.
3. D. Shriver and P. Atkins, Inorganic Chemistry, Oxford University Press, 2011.
Reference Books:
1. F. A. Cotton, G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley India, 2007.
2. C. Housecroft and A. G. Sharpe, Inorganic Chemistry, Pearson India, 2012.
CY1113 / Organic Chemistry-I / [3 1 0 4]Structure and Bonding: Hybridization, bond lengths and bond angles, bond energy, van der Waals interactions, resonance, hyperconjugation, aromaticity, inductive and field effects, hydrogen bonding; Mechanism of Organic Reactions: Curved arrow notation, drawing of electron movements with arrows, half-headed and double-headed arrows, electrophiles and nucleophiles, reactive intermediates: carbocations, carbanions, free radicals, carbenes, arynes and nitrenes, isotope effects, kinetic and stereochemical studies; Stereochemistry of Organic Compounds: Concept of isomerism, optical isomerism, molecular chirality, enantiomers, stereogenic center, relative and absolute configuration, Sequence rules, D & L and R & S systems of nomenclature, geometric isomers, E & Z system of nomenclature, Newman projection and Sawhorse formulae, Fischer and flying wedge formulae; Alkanes and Cycloalkanes: IUPAC nomenclature of branched and unbranched alkanes, methods of synthesis of alkanes, physical properties and chemical reactions of alkanes, nomenclature of cycloalkanes, methods of synthesis of cycloalkanes; Baeyer’s strain theory and its limitations; Alkenes, Cycloalkenes, Dienes and Alkynes: Nomenclature, synthesis and reactions of alkenes, cycloalkenes, dienes and alkynes.
Text Books:
1. R. T. Morrison, R. N. Boyd and S. K. Bhattacharjee, Organic Chemistry, Pearson India, 2011.
2. T. W. G. Solomons and C. B. Fryhle, Organic Chemistry, Wiley India, 2012.
3. P. Sykes, A Guidebook to Mechanism in Organic Chemistry, Pearson India, 2003.
4. I.L. Finer, Organic Chemistry, Volume I, Pearson India, 2002.
5. I.L. Finer, Organic Chemistry, Volume II, Pearson India, 2002.
Reference Books:
1. F. A. Carey andR. J. Sundberg, Advanced Organic Chemistry: Structure And Mechanisms (Part A), Springer India Private Limited, 2007.
2. F. A. Carey andR. J. Sundberg, Advanced Organic Chemistry: Reaction And Synthesis (Part B), Springer India Private Limited, 2007.
3. M. B. Smith, J. March, March's Advanced Organic Chemistry: Reactions, Mechanisms and Structure, Wiley India, 2012.
CY1114 / Physical Chemistry-I / [3 1 0 4]Equation of State: Kinetic molecular theory of gases, derivation of kinetic gas equation, imperfection in real gases, the compressibility of real gases, isotherms of real gases, equations of state, van der Waal’s equation, liquification of gases, critical phenomenon, P-V isotherms of carbon dioxide, principle of continuity of state; .Properties of Liquids: The Kinetic molecular description, intermolecular forces in liquids, density and methods for its measurements, vapour pressure and its determination, surface tension and its determination, viscosity and measurement of viscosity; The First Law of Thermodynamics: Thermodynamic terms and basic concepts, intensive and extensive properties, state functions and differentials, thermodynamic processes, reversibility, irreversibility, various statements of first law, internal energy (U) and enthalphy (H); Thermochemistry: The reaction enthalpy, standard enthalpies, Hess’s law and reaction enthalpies, Kirchoff’s equation, relation between H and U for reactions, calorimetric measurements, varieties of enthalpy changes.
Text Books:
1. P. Atkins and J. De Paula, Atkins' Physical Chemistry, Oxford University Press, 2011.
2. P. C. Rakshit, Physical Chemistry, Sarat Book Distributors, 2004.
3. T. Engel and P. Reid, Physical Chemistry, Pearson India, 2013.
Reference Book:
1. G. W. Castellan, Physical Chemistry, Narosa Publishing House, 2004.
2. G. M. Barrow, Physical Chemistry, McGraw-Hill International, 1973.
3. R. J. Silbey, R. A. Albert and M. G. Bawendi, Physical Chemistry, Wiley India, 2006.
CY1132 / Chemistry(Hons.)laboratory I / [0 0 2 1]Determination of some physical parameters: Calibration of thermometer, determination of melting points and boiling points of some organic compounds; Distillation: Simple distillation of ethanol-water mixture, distillation of nitrobenzene and aniline; Crystallization: Crystallization of some organic and inorganic compound.
Text Books:
1. A. I. Vogel, Elementary Practical Organic Chemistry: Small Scale Preparations Part 1, Pearson India, 2010.
2. A. I. Vogel, Elementary Practical Organic Chemistry: Qualitative Organic Analysis Part 2, Pearson India, 2010.